Abstract

Data are presented from Hartree-Fock calculations and from empirical level fitting showing a linear decrease with energy in the various radial integrals which describe Coulomb repulsion and spin-orbit interaction of atomic electrons.

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  1. E. U. Condon and G. H. Shortley, The Theory of Atomic Spectra (Cambridge University Press, Cambridge, 1935), Ch. IV.
  2. J. C. Slater, Quantum Theory of Atomic Structure (McGraw-Hill Book Co., New York, 1960).
  3. C. Froese, J. Chem. Phys. 45, 1417 (1966).
  4. M. Blume and R. E. Watson, Proc. Roy. Soc. (London) A270, 127 (1962); M. Wilson, J. Opt. Soc. Am. 58, 855 (1968).
  5. B. G. Wybourne, Spectroscopic Properties of Rare Earths (John Wiley & Sons, Inc., New York, 1965), p. 82.
  6. M. G. Mayer, Phys. Rev. 60, 184 (1941). Cf. Ref. 2, Vol. I, p. 225 for the change of the d well in the transition elements.

Blume, M.

M. Blume and R. E. Watson, Proc. Roy. Soc. (London) A270, 127 (1962); M. Wilson, J. Opt. Soc. Am. 58, 855 (1968).

Condon, E. U.

E. U. Condon and G. H. Shortley, The Theory of Atomic Spectra (Cambridge University Press, Cambridge, 1935), Ch. IV.

Froese, C.

C. Froese, J. Chem. Phys. 45, 1417 (1966).

Mayer, M. G.

M. G. Mayer, Phys. Rev. 60, 184 (1941). Cf. Ref. 2, Vol. I, p. 225 for the change of the d well in the transition elements.

Shortley, G. H.

E. U. Condon and G. H. Shortley, The Theory of Atomic Spectra (Cambridge University Press, Cambridge, 1935), Ch. IV.

Slater, J. C.

J. C. Slater, Quantum Theory of Atomic Structure (McGraw-Hill Book Co., New York, 1960).

Watson, R. E.

M. Blume and R. E. Watson, Proc. Roy. Soc. (London) A270, 127 (1962); M. Wilson, J. Opt. Soc. Am. 58, 855 (1968).

Wybourne, B. G.

B. G. Wybourne, Spectroscopic Properties of Rare Earths (John Wiley & Sons, Inc., New York, 1965), p. 82.

Other (6)

E. U. Condon and G. H. Shortley, The Theory of Atomic Spectra (Cambridge University Press, Cambridge, 1935), Ch. IV.

J. C. Slater, Quantum Theory of Atomic Structure (McGraw-Hill Book Co., New York, 1960).

C. Froese, J. Chem. Phys. 45, 1417 (1966).

M. Blume and R. E. Watson, Proc. Roy. Soc. (London) A270, 127 (1962); M. Wilson, J. Opt. Soc. Am. 58, 855 (1968).

B. G. Wybourne, Spectroscopic Properties of Rare Earths (John Wiley & Sons, Inc., New York, 1965), p. 82.

M. G. Mayer, Phys. Rev. 60, 184 (1941). Cf. Ref. 2, Vol. I, p. 225 for the change of the d well in the transition elements.

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