Ab Initio Spectroscopic Integrals for Th i*

M. Wilson

doi:10.1364/JOSA.58.001404

Journal of the Optical Society of America
Vol. 58,
Issue 10,
pp. 1404-1405
(1968)
•https://doi.org/10.1364/JOSA.58.001404

Ab Initio Spectroscopic Integrals for Th i

M. Wilson

Not Accessible

Your library or personal account may give you access

Get PDF
Email
Share
Get Citation
Copy Citation Text
M. Wilson, "Ab Initio Spectroscopic Integrals for Th i*," J. Opt. Soc. Am. 58, 1404-1405 (1968)

Export Citation
- BibTex
- Endnote (RIS)
- HTML
- Plain Text
Citation alert
Save article

Abstract

Hartree–Fock solutions have been obtained for eight configurations of Th i. Slater integrals, configuration-interaction integrals, and dipole integrals of spectroscopic interest are presented.

Full Article | PDF Article

More Like This

Present State of Analysis of the First Spectrum of Thorium (Th i)

Romuald Zalubas
J. Opt. Soc. Am. 58(9) 1195-1199 (1968)

Theoretical Study of pm–pm⁻¹l Spectra*

Robert D. Cowan
J. Opt. Soc. Am. 58(7) 924-933 (1968)

Transition Probabilities in the Spectra of Ne i, Ar i, and Kr i*

Peter W. Murphy
J. Opt. Soc. Am. 58(9) 1200-1208 (1968)

Previous Article Next Article

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Tables (3)

You do not have subscription access to this journal. Article tables are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Equations (1)

You do not have subscription access to this journal. Equations are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

	Even configurations			Odd configurations
	6d³7s	6d²7s²	5f²7s²	5f6d7s²	5f6d²7s	5f6d³	6d²7s7p	7s²6d7p
F²(6d6d)	35093.3	37482.8			32186.4	28591.0	38051.2
F⁴(6d6d)	23191.2	24974.6			21110.4	18499.0	25405.0
F²(5f5f)			66337.6
F⁴(5f5f)			42868.5
F²(5f5d)			31293.7
F²(5f6d)				27242.5	24947.0	22147.6
F⁴(5f6d)				14510.2	13132.7	11478.8
G¹(5f6d)				15661.3	14512.1	12936.1
G³(5f6d)				11756.9	10717.6	9402.4
G⁵(5f6d)				8865.1	8030.2	7002.3
F²(6d7p)							11899.1	14056.2
G¹(6d7p)							5302.9	6067.5
G³(6d7p)							4098.9	4863.8
G¹(7p7s)							21953.1	24866.7^a
G²(6d7s)	10235.1	10672.2^a		11159.2^a	10893.5		10973.1	11262.1^a
G³(5f7s)			1846.1^a	1823.9^a	1543.1
ζ_p							1532.6	2215.9
ζ_d	1652.9	1854.9		1566.2	1355.4	1134.0	1899.2	2082.4
ζ_f			1571.7	1740.3	1718.6	1703.9

Configurations		(cm⁻¹)	Cancellation factor^a
(Odd)
fs+(ds×d²)	R²(6d7s,6d6d)	−15468.9	0.81
ds+(fs×fd)	R²(5f7s,5f6d)	−2786.9	0.26
ds+(fs×fd)	R³(5f7s,6d5f)	850.5	0.16
fd+(s²×d²)	R²(7s7s,6d6d)	14172.3	0.90
fd+(ds×d²)	R²(6d7s,6d6d)	−14849.3	0.84
d²+(fs×fd)	R²(5f7s,5f6d)	−2725.0	0.29
d²+(fs×fd)	R³(5f7s,6d5f)	687.5	0.15
d²+(fd×sp)	R³(5f6d,7s7p)	−2348.2	0.74
d²+(fd×sp)	R²(5f6d,7p7s)	−1879.2	0.46
ds+(fs×dp)	R¹(5f7s,6d7p)	−10141.9	0.85
ds+(fs×dp)	R²(5f7s,7p6d)	−1316.8	0.40
ds+(dp×sp)	R¹(6d7p,7p7s)	−11255.7	0.79
ds+(dp×sp)	R²(6d7p,7s7p)	−11445.9	0.93
sp+(d²×ds)	R²(6d6d,6d7s)	−15626.3	0.74
ds+(fd×ps)	R²(5f6d,7p7s)	−2079.8	0.42
ds+(fd×ps)	R³(5f6d,7s7p)	−2681.5	0.72
s²+(fd×dp)	R¹(5f6d,6d7p)	5839.1	0.42
	R³(5f6d,6d7p)	1945.9	0.30
	R²(5f6d,7p6d)	−1248.3	0.15
	R⁴(5f6d,7p6d)	−500.7	0.10
(Even)
ds+(d²×ds)	R²(6d6d,6d7s)	−15072.2	0.77
s²+(d²×f²)	R¹(6d6d,5f5f)	20559.9	0.69
	R³(6d6d,5f5f)	15031.2	0.88
	R⁵(6d6d,5f5f)	11230.0	0.95

	5f6d7s²	5f6d²7s	6d²7s7p	7s²6d7p
6d³7s	0	+1.218(0.90)^a	+2.294(0.90)	0
6d²7s²	0	0	−5.254(0.99₉)	+2.097(0.88)
5f²7s²	+1.347(0.91)	0	0	0

	Even configurations			Odd configurations
	6d³7s	6d²7s²	5f²7s²	5f6d7s²	5f6d²7s	5f6d³	6d²7s7p	7s²6d7p
F²(6d6d)	35093.3	37482.8			32186.4	28591.0	38051.2
F⁴(6d6d)	23191.2	24974.6			21110.4	18499.0	25405.0
F²(5f5f)			66337.6
F⁴(5f5f)			42868.5
F²(5f5d)			31293.7
F²(5f6d)				27242.5	24947.0	22147.6
F⁴(5f6d)				14510.2	13132.7	11478.8
G¹(5f6d)				15661.3	14512.1	12936.1
G³(5f6d)				11756.9	10717.6	9402.4
G⁵(5f6d)				8865.1	8030.2	7002.3
F²(6d7p)							11899.1	14056.2
G¹(6d7p)							5302.9	6067.5
G³(6d7p)							4098.9	4863.8
G¹(7p7s)							21953.1	24866.7^a
G²(6d7s)	10235.1	10672.2^a		11159.2^a	10893.5		10973.1	11262.1^a
G³(5f7s)			1846.1^a	1823.9^a	1543.1
ζ_p							1532.6	2215.9
ζ_d	1652.9	1854.9		1566.2	1355.4	1134.0	1899.2	2082.4
ζ_f			1571.7	1740.3	1718.6	1703.9

Configurations		(cm⁻¹)	Cancellation factor^a
(Odd)
fs+(ds×d²)	R²(6d7s,6d6d)	−15468.9	0.81
ds+(fs×fd)	R²(5f7s,5f6d)	−2786.9	0.26
ds+(fs×fd)	R³(5f7s,6d5f)	850.5	0.16
fd+(s²×d²)	R²(7s7s,6d6d)	14172.3	0.90
fd+(ds×d²)	R²(6d7s,6d6d)	−14849.3	0.84
d²+(fs×fd)	R²(5f7s,5f6d)	−2725.0	0.29
d²+(fs×fd)	R³(5f7s,6d5f)	687.5	0.15
d²+(fd×sp)	R³(5f6d,7s7p)	−2348.2	0.74
d²+(fd×sp)	R²(5f6d,7p7s)	−1879.2	0.46
ds+(fs×dp)	R¹(5f7s,6d7p)	−10141.9	0.85
ds+(fs×dp)	R²(5f7s,7p6d)	−1316.8	0.40
ds+(dp×sp)	R¹(6d7p,7p7s)	−11255.7	0.79
ds+(dp×sp)	R²(6d7p,7s7p)	−11445.9	0.93
sp+(d²×ds)	R²(6d6d,6d7s)	−15626.3	0.74
ds+(fd×ps)	R²(5f6d,7p7s)	−2079.8	0.42
ds+(fd×ps)	R³(5f6d,7s7p)	−2681.5	0.72
s²+(fd×dp)	R¹(5f6d,6d7p)	5839.1	0.42
	R³(5f6d,6d7p)	1945.9	0.30
	R²(5f6d,7p6d)	−1248.3	0.15
	R⁴(5f6d,7p6d)	−500.7	0.10
(Even)
ds+(d²×ds)	R²(6d6d,6d7s)	−15072.2	0.77
s²+(d²×f²)	R¹(6d6d,5f5f)	20559.9	0.69
	R³(6d6d,5f5f)	15031.2	0.88
	R⁵(6d6d,5f5f)	11230.0	0.95

Abstract

Cited By

Tables (3)

Equations (1)

Journal of the Optical Society of America