Abstract

The infrared lattice spectra from 700 to 50 cm−1 of eight cubic rare earth oxides are reported. It is evident from these data that the crystal structure determines the frequency position, and clearly shows the effect of the lanthanide contraction in this series of compounds.

© 1966 Optical Society of America

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References

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  1. N. T. McDevitt and W. L. Baun, Spectrochim. Acta 20, 799 (1964).
    [Crossref]
  2. C. D. Helms, H. W. Jones, A. J. Russo, and E. H. Siegler, Spectrochim. Acta 19, 819 (1963).
    [Crossref]
  3. K. A. Gschneider, Rare Earth Alloys (D. Van Nostrand Co., Inc., Princeton, N. J., 1961), p. 242.

1964 (1)

N. T. McDevitt and W. L. Baun, Spectrochim. Acta 20, 799 (1964).
[Crossref]

1963 (1)

C. D. Helms, H. W. Jones, A. J. Russo, and E. H. Siegler, Spectrochim. Acta 19, 819 (1963).
[Crossref]

Baun, W. L.

N. T. McDevitt and W. L. Baun, Spectrochim. Acta 20, 799 (1964).
[Crossref]

Gschneider, K. A.

K. A. Gschneider, Rare Earth Alloys (D. Van Nostrand Co., Inc., Princeton, N. J., 1961), p. 242.

Helms, C. D.

C. D. Helms, H. W. Jones, A. J. Russo, and E. H. Siegler, Spectrochim. Acta 19, 819 (1963).
[Crossref]

Jones, H. W.

C. D. Helms, H. W. Jones, A. J. Russo, and E. H. Siegler, Spectrochim. Acta 19, 819 (1963).
[Crossref]

McDevitt, N. T.

N. T. McDevitt and W. L. Baun, Spectrochim. Acta 20, 799 (1964).
[Crossref]

Russo, A. J.

C. D. Helms, H. W. Jones, A. J. Russo, and E. H. Siegler, Spectrochim. Acta 19, 819 (1963).
[Crossref]

Siegler, E. H.

C. D. Helms, H. W. Jones, A. J. Russo, and E. H. Siegler, Spectrochim. Acta 19, 819 (1963).
[Crossref]

Spectrochim. Acta (2)

N. T. McDevitt and W. L. Baun, Spectrochim. Acta 20, 799 (1964).
[Crossref]

C. D. Helms, H. W. Jones, A. J. Russo, and E. H. Siegler, Spectrochim. Acta 19, 819 (1963).
[Crossref]

Other (1)

K. A. Gschneider, Rare Earth Alloys (D. Van Nostrand Co., Inc., Princeton, N. J., 1961), p. 242.

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Figures (9)

Fig. 1
Fig. 1

Transmission spectrum of Gd2O3.

Fig. 2
Fig. 2

Transmission spectrum of Dy2O3.

Fig. 3
Fig. 3

Transmission spectrum of Ho2O3.

Fig. 4
Fig. 4

Transmission spectrum of Er2O3.

Fig. 5
Fig. 5

Transmission spectrum of Tm2O3.

Fig. 6
Fig. 6

Transmission spectrum of Lu2O3.

Fig. 7
Fig. 7

Transmission spectrum of Y2O3.

Fig. 8
Fig. 8

Transmission spectrum of Yb2O3.

Fig. 9
Fig. 9

Frequency versus cell volume.

Tables (1)

Tables Icon

Table I Lattice absorptions in cubic rare earth oxides.