Abstract

The Lorentz parameter Δν has been obtained by the equivalent-width method for the pressure-broadened spectral lines of low-<i>J</i> value in the HF fundamental. These values have been compared with values obtained directly from the line shapes after correction for the effect of instrumental broadening. From the line intensities <i>I</i><sub>0</sub><sup>1</sup>(<i>m</i>), the square of the matrix element of the electric dipole moment for a nonrotating anharmonic oscillator |<i>R</i><sub>0</sub><sup>1</sup>|<sup>2</sup>, and a set of rotational-correction factors <i>F</i><sub>0</sub><sup>1</sup>(<i>m</i>) have been calculated. The effective charge <i>M</i><sub>1</sub> and the vibration-rotation interaction constant θ have been calculated. Experimental and theoretical values of the <i>F</i><sub>0</sub><sup>1</sup>(<i>m</i>) have been compared.

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  1. J. A. Herndon, W. E. Deeds, N. M. Gailar, W. F. Herget, R. J. Lovell, and A. H. Nielsen, J. Opt. Soc. Am. 52, 1108 (1962).
  2. D. F. Smith, J. Mol. Spectroscopy 3, 473 (1959).
  3. W. F. Herget, W. E. Deeds, N. M. Gailar, R. J. Lovell, and A. H. Nielsen, J. Opt. Soc. Am. 52, 1113 (1962).
  4. R. Herman, R. W. Rothery, and R. J. Rubin, J. Mol. Spectroscopy 2, 369 (1958).
  5. W. S. Benedict, R. Herman, G. E. Moore, and S. Silverman, Can. J. Phys. 34, 830 (1956).
  6. L. D. Kaplan and D. F. Eggers, J. Chem. Phys. 25, 876 (1956).
  7. R. Herman and R. J. Rubin, Astrophys. J. 121, 533 (1955).
  8. Private communication from Rainer Weiss of Massachusetts Institute of Technology.
  9. G. A. Kuipers, J. Mol. Spectroscopy 2, 75 (1958).

Benedict, W. S.

W. S. Benedict, R. Herman, G. E. Moore, and S. Silverman, Can. J. Phys. 34, 830 (1956).

Deeds, W. E.

W. F. Herget, W. E. Deeds, N. M. Gailar, R. J. Lovell, and A. H. Nielsen, J. Opt. Soc. Am. 52, 1113 (1962).

J. A. Herndon, W. E. Deeds, N. M. Gailar, W. F. Herget, R. J. Lovell, and A. H. Nielsen, J. Opt. Soc. Am. 52, 1108 (1962).

Eggers, D. F.

L. D. Kaplan and D. F. Eggers, J. Chem. Phys. 25, 876 (1956).

Gailar, N. M.

J. A. Herndon, W. E. Deeds, N. M. Gailar, W. F. Herget, R. J. Lovell, and A. H. Nielsen, J. Opt. Soc. Am. 52, 1108 (1962).

W. F. Herget, W. E. Deeds, N. M. Gailar, R. J. Lovell, and A. H. Nielsen, J. Opt. Soc. Am. 52, 1113 (1962).

Herget, W. F.

W. F. Herget, W. E. Deeds, N. M. Gailar, R. J. Lovell, and A. H. Nielsen, J. Opt. Soc. Am. 52, 1113 (1962).

J. A. Herndon, W. E. Deeds, N. M. Gailar, W. F. Herget, R. J. Lovell, and A. H. Nielsen, J. Opt. Soc. Am. 52, 1108 (1962).

Herman, R.

R. Herman and R. J. Rubin, Astrophys. J. 121, 533 (1955).

W. S. Benedict, R. Herman, G. E. Moore, and S. Silverman, Can. J. Phys. 34, 830 (1956).

R. Herman, R. W. Rothery, and R. J. Rubin, J. Mol. Spectroscopy 2, 369 (1958).

Herndon, J. A.

J. A. Herndon, W. E. Deeds, N. M. Gailar, W. F. Herget, R. J. Lovell, and A. H. Nielsen, J. Opt. Soc. Am. 52, 1108 (1962).

Kaplan, L. D.

L. D. Kaplan and D. F. Eggers, J. Chem. Phys. 25, 876 (1956).

Kuipers, G. A.

G. A. Kuipers, J. Mol. Spectroscopy 2, 75 (1958).

Lovell, R. J.

J. A. Herndon, W. E. Deeds, N. M. Gailar, W. F. Herget, R. J. Lovell, and A. H. Nielsen, J. Opt. Soc. Am. 52, 1108 (1962).

W. F. Herget, W. E. Deeds, N. M. Gailar, R. J. Lovell, and A. H. Nielsen, J. Opt. Soc. Am. 52, 1113 (1962).

Moore, G. E.

W. S. Benedict, R. Herman, G. E. Moore, and S. Silverman, Can. J. Phys. 34, 830 (1956).

Nielsen, A. H.

W. F. Herget, W. E. Deeds, N. M. Gailar, R. J. Lovell, and A. H. Nielsen, J. Opt. Soc. Am. 52, 1113 (1962).

J. A. Herndon, W. E. Deeds, N. M. Gailar, W. F. Herget, R. J. Lovell, and A. H. Nielsen, J. Opt. Soc. Am. 52, 1108 (1962).

Rothery, R. W.

R. Herman, R. W. Rothery, and R. J. Rubin, J. Mol. Spectroscopy 2, 369 (1958).

Rubin, R. J.

R. Herman, R. W. Rothery, and R. J. Rubin, J. Mol. Spectroscopy 2, 369 (1958).

R. Herman and R. J. Rubin, Astrophys. J. 121, 533 (1955).

Silverman, S.

W. S. Benedict, R. Herman, G. E. Moore, and S. Silverman, Can. J. Phys. 34, 830 (1956).

Smith, D. F.

D. F. Smith, J. Mol. Spectroscopy 3, 473 (1959).

Other

J. A. Herndon, W. E. Deeds, N. M. Gailar, W. F. Herget, R. J. Lovell, and A. H. Nielsen, J. Opt. Soc. Am. 52, 1108 (1962).

D. F. Smith, J. Mol. Spectroscopy 3, 473 (1959).

W. F. Herget, W. E. Deeds, N. M. Gailar, R. J. Lovell, and A. H. Nielsen, J. Opt. Soc. Am. 52, 1113 (1962).

R. Herman, R. W. Rothery, and R. J. Rubin, J. Mol. Spectroscopy 2, 369 (1958).

W. S. Benedict, R. Herman, G. E. Moore, and S. Silverman, Can. J. Phys. 34, 830 (1956).

L. D. Kaplan and D. F. Eggers, J. Chem. Phys. 25, 876 (1956).

R. Herman and R. J. Rubin, Astrophys. J. 121, 533 (1955).

Private communication from Rainer Weiss of Massachusetts Institute of Technology.

G. A. Kuipers, J. Mol. Spectroscopy 2, 75 (1958).

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