Abstract

Infrared studies of hydrogen-deuterium exchange in bulk fused silica indicate that the rate of exchange steadily increases with temperature from 600 to 1000°C. The exchange takes place on isolated OH groups and occurs in either direction.

© 1960 Optical Society of America

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References

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  1. R. W. Lee, D. E. Swets, and R. C. Frank, presented at Eighth Annual Meeting ASTM Committee E-14 on Mass Spectrometry, June 26–July 1, 1960, Atlantic City, New Jersey.
  2. Adalbert Farkas and Ladislas Farkas, J. Am. Chem. Soc. 57, 821–4 (1935).
  3. R. V. Adams and R. W. Douglas, J. Soc. Glass Tech. 43, 147T–158T (1959).
  4. George C. Pimentel, Carl W. Garland, and George Jura, J. Am. Chem. Soc. 75, 803–5 (1953).
    [Crossref]
  5. R. P. Eischens and W. A. Pliskin, Advances in Catalysis 10, 1–55 (1958).
    [Crossref]
  6. E. Bartholome and K. Clusius, Naturw. 22, 420 (1934).
    [Crossref]

1959 (1)

R. V. Adams and R. W. Douglas, J. Soc. Glass Tech. 43, 147T–158T (1959).

1958 (1)

R. P. Eischens and W. A. Pliskin, Advances in Catalysis 10, 1–55 (1958).
[Crossref]

1953 (1)

George C. Pimentel, Carl W. Garland, and George Jura, J. Am. Chem. Soc. 75, 803–5 (1953).
[Crossref]

1935 (1)

Adalbert Farkas and Ladislas Farkas, J. Am. Chem. Soc. 57, 821–4 (1935).

1934 (1)

E. Bartholome and K. Clusius, Naturw. 22, 420 (1934).
[Crossref]

Adams, R. V.

R. V. Adams and R. W. Douglas, J. Soc. Glass Tech. 43, 147T–158T (1959).

Bartholome, E.

E. Bartholome and K. Clusius, Naturw. 22, 420 (1934).
[Crossref]

Clusius, K.

E. Bartholome and K. Clusius, Naturw. 22, 420 (1934).
[Crossref]

Douglas, R. W.

R. V. Adams and R. W. Douglas, J. Soc. Glass Tech. 43, 147T–158T (1959).

Eischens, R. P.

R. P. Eischens and W. A. Pliskin, Advances in Catalysis 10, 1–55 (1958).
[Crossref]

Farkas, Adalbert

Adalbert Farkas and Ladislas Farkas, J. Am. Chem. Soc. 57, 821–4 (1935).

Farkas, Ladislas

Adalbert Farkas and Ladislas Farkas, J. Am. Chem. Soc. 57, 821–4 (1935).

Frank, R. C.

R. W. Lee, D. E. Swets, and R. C. Frank, presented at Eighth Annual Meeting ASTM Committee E-14 on Mass Spectrometry, June 26–July 1, 1960, Atlantic City, New Jersey.

Garland, Carl W.

George C. Pimentel, Carl W. Garland, and George Jura, J. Am. Chem. Soc. 75, 803–5 (1953).
[Crossref]

Jura, George

George C. Pimentel, Carl W. Garland, and George Jura, J. Am. Chem. Soc. 75, 803–5 (1953).
[Crossref]

Lee, R. W.

R. W. Lee, D. E. Swets, and R. C. Frank, presented at Eighth Annual Meeting ASTM Committee E-14 on Mass Spectrometry, June 26–July 1, 1960, Atlantic City, New Jersey.

Pimentel, George C.

George C. Pimentel, Carl W. Garland, and George Jura, J. Am. Chem. Soc. 75, 803–5 (1953).
[Crossref]

Pliskin, W. A.

R. P. Eischens and W. A. Pliskin, Advances in Catalysis 10, 1–55 (1958).
[Crossref]

Swets, D. E.

R. W. Lee, D. E. Swets, and R. C. Frank, presented at Eighth Annual Meeting ASTM Committee E-14 on Mass Spectrometry, June 26–July 1, 1960, Atlantic City, New Jersey.

Advances in Catalysis (1)

R. P. Eischens and W. A. Pliskin, Advances in Catalysis 10, 1–55 (1958).
[Crossref]

J. Am. Chem. Soc. (2)

Adalbert Farkas and Ladislas Farkas, J. Am. Chem. Soc. 57, 821–4 (1935).

George C. Pimentel, Carl W. Garland, and George Jura, J. Am. Chem. Soc. 75, 803–5 (1953).
[Crossref]

J. Soc. Glass Tech. (1)

R. V. Adams and R. W. Douglas, J. Soc. Glass Tech. 43, 147T–158T (1959).

Naturw. (1)

E. Bartholome and K. Clusius, Naturw. 22, 420 (1934).
[Crossref]

Other (1)

R. W. Lee, D. E. Swets, and R. C. Frank, presented at Eighth Annual Meeting ASTM Committee E-14 on Mass Spectrometry, June 26–July 1, 1960, Atlantic City, New Jersey.

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Figures (3)

Fig. 1
Fig. 1

Typical spectra of an original sample (A) and samples exposed to 1 atm. of D2 at 1000°C (B, for 0.5 hr; C, for 5 hr; and D, for 25 hr).

Fig. 2
Fig. 2

Time and temperature dependence of OH to OD conversion at one atm.

Fig. 3
Fig. 3

Pressure dependence of OH to OD conversion under the following conditions: 22 hr at 1000°C (●), 8 hr at 1000°C (○), and 16 hr at 800°C (×).