Abstract

Precision determinations of the origins of the fundamental and first four harmonic bands of HCl35 have been made. The rotational constants of the 2–0 and 3–0 bands as well as the origin and rotational constants of the 2–0 band of DCl35 are also reported. This work will be used in conjunction with additional measurements now in progress on the fundamental band of HCl and other bands of DCl to determine rotation-vibration constants for comparison with theoretical predictions.

© 1960 Optical Society of America

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References

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  1. H. M. Randall and E. S. Imes, Phys. Rev. 15, 152 (1920).
  2. C. F. Meyer and A. A. Levin, Phys. Rev. 34, 44 (1929).
    [Crossref]
  3. G. Herzberg and J. W. T. Spinks, Z. Physik 89, 474 (1934).
    [Crossref]
  4. E. Lindholm, Ark. Mat. Astro. Fys. 29B, No. 15 (1943).
  5. S. M. Naudé and H. Verleger, Proc. Phys. Soc. (London) A63, 470 (1950).
  6. I. M. Mills, H. W. Thompson, and R. L. Williams, Proc. Roy. Soc. (London) A218, 29 (1953).
  7. D. H. Rank, D. P. Eastman, W. B. Birtley, G. Skorinko, and T. A. Wiggins, J. Opt. Soc. Am. 50, 821 (1960).
    [Crossref]
  8. D. H. Rank, G. Skorinko, D. P. Eastman, and T. A. Wiggins, J. Mol. Spectroscopy 4, 518 (1960).
    [Crossref]
  9. D. H. Rank, J. Opt. Soc. Am. 50, 657 (1960).
    [Crossref]
  10. D. H. Rank, A. H. Guenther, J. N. Shearer, and T. A. Wiggins, J. Opt. Soc. Am. 47, 144 (1957).
    [Crossref]
  11. J. U. White, J. Opt. Soc. Am. 32, 285 (1942).
    [Crossref]
  12. D. H. Rank, A. H. Guenther, G. D. Saksena, J. N. Shearer, and T. A. Wiggins, J. Opt. Soc. Am. 47, 686 (1957).
    [Crossref]
  13. G. D. Saksena, T. A. Wiggins, and D. H. Rank, J. Chem. Phys. 31, 839 (1959).
    [Crossref]
  14. J. L. Dunham, Phys. Rev. 41, 721 (1932).
    [Crossref]
  15. B. H. Van Horne and C. D. Hause, J. Chem. Phys. 25, 56 (1956).
    [Crossref]
  16. M. Cowan and W. Gordy, Phys. Rev. 111, 209 (1958).
    [Crossref]
  17. J. Pickworth and H. W. Thompson, Proc. Roy. Soc. (London) A218, 37 (1953).

1960 (3)

1959 (1)

G. D. Saksena, T. A. Wiggins, and D. H. Rank, J. Chem. Phys. 31, 839 (1959).
[Crossref]

1958 (1)

M. Cowan and W. Gordy, Phys. Rev. 111, 209 (1958).
[Crossref]

1957 (2)

1956 (1)

B. H. Van Horne and C. D. Hause, J. Chem. Phys. 25, 56 (1956).
[Crossref]

1953 (2)

J. Pickworth and H. W. Thompson, Proc. Roy. Soc. (London) A218, 37 (1953).

I. M. Mills, H. W. Thompson, and R. L. Williams, Proc. Roy. Soc. (London) A218, 29 (1953).

1950 (1)

S. M. Naudé and H. Verleger, Proc. Phys. Soc. (London) A63, 470 (1950).

1943 (1)

E. Lindholm, Ark. Mat. Astro. Fys. 29B, No. 15 (1943).

1942 (1)

1934 (1)

G. Herzberg and J. W. T. Spinks, Z. Physik 89, 474 (1934).
[Crossref]

1932 (1)

J. L. Dunham, Phys. Rev. 41, 721 (1932).
[Crossref]

1929 (1)

C. F. Meyer and A. A. Levin, Phys. Rev. 34, 44 (1929).
[Crossref]

1920 (1)

H. M. Randall and E. S. Imes, Phys. Rev. 15, 152 (1920).

Birtley, W. B.

Cowan, M.

M. Cowan and W. Gordy, Phys. Rev. 111, 209 (1958).
[Crossref]

Dunham, J. L.

J. L. Dunham, Phys. Rev. 41, 721 (1932).
[Crossref]

Eastman, D. P.

D. H. Rank, G. Skorinko, D. P. Eastman, and T. A. Wiggins, J. Mol. Spectroscopy 4, 518 (1960).
[Crossref]

D. H. Rank, D. P. Eastman, W. B. Birtley, G. Skorinko, and T. A. Wiggins, J. Opt. Soc. Am. 50, 821 (1960).
[Crossref]

Gordy, W.

M. Cowan and W. Gordy, Phys. Rev. 111, 209 (1958).
[Crossref]

Guenther, A. H.

Hause, C. D.

B. H. Van Horne and C. D. Hause, J. Chem. Phys. 25, 56 (1956).
[Crossref]

Herzberg, G.

G. Herzberg and J. W. T. Spinks, Z. Physik 89, 474 (1934).
[Crossref]

Imes, E. S.

H. M. Randall and E. S. Imes, Phys. Rev. 15, 152 (1920).

Levin, A. A.

C. F. Meyer and A. A. Levin, Phys. Rev. 34, 44 (1929).
[Crossref]

Lindholm, E.

E. Lindholm, Ark. Mat. Astro. Fys. 29B, No. 15 (1943).

Meyer, C. F.

C. F. Meyer and A. A. Levin, Phys. Rev. 34, 44 (1929).
[Crossref]

Mills, I. M.

I. M. Mills, H. W. Thompson, and R. L. Williams, Proc. Roy. Soc. (London) A218, 29 (1953).

Naudé, S. M.

S. M. Naudé and H. Verleger, Proc. Phys. Soc. (London) A63, 470 (1950).

Pickworth, J.

J. Pickworth and H. W. Thompson, Proc. Roy. Soc. (London) A218, 37 (1953).

Randall, H. M.

H. M. Randall and E. S. Imes, Phys. Rev. 15, 152 (1920).

Rank, D. H.

Saksena, G. D.

Shearer, J. N.

Skorinko, G.

D. H. Rank, G. Skorinko, D. P. Eastman, and T. A. Wiggins, J. Mol. Spectroscopy 4, 518 (1960).
[Crossref]

D. H. Rank, D. P. Eastman, W. B. Birtley, G. Skorinko, and T. A. Wiggins, J. Opt. Soc. Am. 50, 821 (1960).
[Crossref]

Spinks, J. W. T.

G. Herzberg and J. W. T. Spinks, Z. Physik 89, 474 (1934).
[Crossref]

Thompson, H. W.

I. M. Mills, H. W. Thompson, and R. L. Williams, Proc. Roy. Soc. (London) A218, 29 (1953).

J. Pickworth and H. W. Thompson, Proc. Roy. Soc. (London) A218, 37 (1953).

Van Horne, B. H.

B. H. Van Horne and C. D. Hause, J. Chem. Phys. 25, 56 (1956).
[Crossref]

Verleger, H.

S. M. Naudé and H. Verleger, Proc. Phys. Soc. (London) A63, 470 (1950).

White, J. U.

Wiggins, T. A.

Williams, R. L.

I. M. Mills, H. W. Thompson, and R. L. Williams, Proc. Roy. Soc. (London) A218, 29 (1953).

Ark. Mat. Astro. Fys. (1)

E. Lindholm, Ark. Mat. Astro. Fys. 29B, No. 15 (1943).

J. Chem. Phys. (2)

G. D. Saksena, T. A. Wiggins, and D. H. Rank, J. Chem. Phys. 31, 839 (1959).
[Crossref]

B. H. Van Horne and C. D. Hause, J. Chem. Phys. 25, 56 (1956).
[Crossref]

J. Mol. Spectroscopy (1)

D. H. Rank, G. Skorinko, D. P. Eastman, and T. A. Wiggins, J. Mol. Spectroscopy 4, 518 (1960).
[Crossref]

J. Opt. Soc. Am. (5)

Phys. Rev. (4)

M. Cowan and W. Gordy, Phys. Rev. 111, 209 (1958).
[Crossref]

J. L. Dunham, Phys. Rev. 41, 721 (1932).
[Crossref]

H. M. Randall and E. S. Imes, Phys. Rev. 15, 152 (1920).

C. F. Meyer and A. A. Levin, Phys. Rev. 34, 44 (1929).
[Crossref]

Proc. Phys. Soc. (London) (1)

S. M. Naudé and H. Verleger, Proc. Phys. Soc. (London) A63, 470 (1950).

Proc. Roy. Soc. (London) (2)

I. M. Mills, H. W. Thompson, and R. L. Williams, Proc. Roy. Soc. (London) A218, 29 (1953).

J. Pickworth and H. W. Thompson, Proc. Roy. Soc. (London) A218, 37 (1953).

Z. Physik (1)

G. Herzberg and J. W. T. Spinks, Z. Physik 89, 474 (1934).
[Crossref]

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Figures (2)

Fig. 1
Fig. 1

Reproduction of a photograph of the R branch of the 4–0 band of HCl obtained in the 3rd order with the 10-meter spectrograph. Line positions for both Cl35 and Cl37 isotopic forms are indicated. The Hg line indicated is λ5460-A line of Hg198 which appears in the 5th order spectrum. The argon line indicated is associated with the continuum from the zirconium lamp. The paper was moved parallel to the lines in making the reproduction.

Fig. 2
Fig. 2

Reproduction of a photograph of the R branch of the 5–0 band of HCl obtained in the 4th order with the 10-meter spectrograph. Line position for both Cl35 and Cl37 isotopic forms are indicated. Several neon standard lines also appear. The paper was moved parallel to the lines in the enlarging process in making the reproduction.

Tables (6)

Tables Icon

Table I Measured and calculated frequencies in vacuum wave numbers of lines in the 2–0 band of HCl35. The standard lines and their orders used for measurement are also given.

Tables Icon

Table II Measured and calculated frequencies in vacuum wave numbers of lines in the 3–0 band of HCl35. The standard lines and their orders used for measurement are also given.

Tables Icon

Table III Measured frequencies in vacuum wave numbers of lines in the 4–0 band of HCl35.

Tables Icon

Table IV Measured frequencies in vacuum wave numbers of lines in the 5–0 band of HCl35.

Tables Icon

Table V Measured frequencies in vacuum wave numbers of lines in the 1–0 band of HCl35.

Tables Icon

Table VI Measured and calculated frequencies in vacuum wave numbers of lines in the 2–0 band of DCl35. The standard lines and their orders used for measurement are also given.

Equations (2)

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ν 0 = 5667.9834 ± 0.002 B 0 = 10.44030 6 B 2 = 9.83474 9 D 0 = 5.2900 × 10 - 4 D 2 = 5.1686 × 10 - 4 H 0 = H 2 = 1.78 2 × 10 - 8 .
ν 0 = 8346.777 ± 0.005 B 3 = 9.53519 6 D 3 = 5.1342 × 10 - 4 cm - 1 .