Abstract

The dispersion of carbon tetrachloride, carbon disulfide, chloroform, cyclohexane, tetrachloroethylene, methylene iodide, acetone, and perfluoro 1,3,5-trimethylcyclohexane has been measured in the 2–15 μ region using an interferometric method. The problem of assigning the proper orders of interference to the observed fringe system has been solved by studying the compounds of interest dissolved in carbon disulfide and carbon tetrachloride. Since the orders of interference can be reliably determined for these two solvents one can follow the shift in order as the concentration of the solute is increased in a stepwise fashion from 0 to 100%.

© 1960 Optical Society of America

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References

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  1. A. Wada and Y. Morino, J. Chem. Phys. 22, 1276 (1954).
    [Crossref]
  2. S. R. Polo and M. K. Wilson, J. Chem. Phys. 23, 2376 (1955).
    [Crossref]
  3. E. E. Ferguson, Spectrochim. Acta 10, 123 (1958).
    [Crossref]
  4. L. J. Bellamy and H. E. Hallam, Trans. Faraday Soc. 55, 220 (1959).
    [Crossref]
  5. P. N. Schatz, J. Chem. Phys. 29, 959 (1958).
    [Crossref]
  6. E. E. Ferguson and R. E. Kagarise, J. Chem. Phys. (to be published).
  7. R. E. Kagarise and J. W. Mayfield, J. Opt. Soc. Am. 48, 430 (1958).
    [Crossref]
  8. J. Vincent-Geisse and J. Lecomte, Compt. rend. 244, 577 (1957).
  9. A. Pfund, J. Opt. Soc. Am. 29, 358 (1939).
    [Crossref]

1959 (1)

L. J. Bellamy and H. E. Hallam, Trans. Faraday Soc. 55, 220 (1959).
[Crossref]

1958 (3)

P. N. Schatz, J. Chem. Phys. 29, 959 (1958).
[Crossref]

E. E. Ferguson, Spectrochim. Acta 10, 123 (1958).
[Crossref]

R. E. Kagarise and J. W. Mayfield, J. Opt. Soc. Am. 48, 430 (1958).
[Crossref]

1957 (1)

J. Vincent-Geisse and J. Lecomte, Compt. rend. 244, 577 (1957).

1955 (1)

S. R. Polo and M. K. Wilson, J. Chem. Phys. 23, 2376 (1955).
[Crossref]

1954 (1)

A. Wada and Y. Morino, J. Chem. Phys. 22, 1276 (1954).
[Crossref]

1939 (1)

Bellamy, L. J.

L. J. Bellamy and H. E. Hallam, Trans. Faraday Soc. 55, 220 (1959).
[Crossref]

Ferguson, E. E.

E. E. Ferguson, Spectrochim. Acta 10, 123 (1958).
[Crossref]

E. E. Ferguson and R. E. Kagarise, J. Chem. Phys. (to be published).

Hallam, H. E.

L. J. Bellamy and H. E. Hallam, Trans. Faraday Soc. 55, 220 (1959).
[Crossref]

Kagarise, R. E.

R. E. Kagarise and J. W. Mayfield, J. Opt. Soc. Am. 48, 430 (1958).
[Crossref]

E. E. Ferguson and R. E. Kagarise, J. Chem. Phys. (to be published).

Lecomte, J.

J. Vincent-Geisse and J. Lecomte, Compt. rend. 244, 577 (1957).

Mayfield, J. W.

Morino, Y.

A. Wada and Y. Morino, J. Chem. Phys. 22, 1276 (1954).
[Crossref]

Pfund, A.

Polo, S. R.

S. R. Polo and M. K. Wilson, J. Chem. Phys. 23, 2376 (1955).
[Crossref]

Schatz, P. N.

P. N. Schatz, J. Chem. Phys. 29, 959 (1958).
[Crossref]

Vincent-Geisse, J.

J. Vincent-Geisse and J. Lecomte, Compt. rend. 244, 577 (1957).

Wada, A.

A. Wada and Y. Morino, J. Chem. Phys. 22, 1276 (1954).
[Crossref]

Wilson, M. K.

S. R. Polo and M. K. Wilson, J. Chem. Phys. 23, 2376 (1955).
[Crossref]

Compt. rend. (1)

J. Vincent-Geisse and J. Lecomte, Compt. rend. 244, 577 (1957).

J. Chem. Phys. (3)

P. N. Schatz, J. Chem. Phys. 29, 959 (1958).
[Crossref]

A. Wada and Y. Morino, J. Chem. Phys. 22, 1276 (1954).
[Crossref]

S. R. Polo and M. K. Wilson, J. Chem. Phys. 23, 2376 (1955).
[Crossref]

J. Opt. Soc. Am. (2)

Spectrochim. Acta (1)

E. E. Ferguson, Spectrochim. Acta 10, 123 (1958).
[Crossref]

Trans. Faraday Soc. (1)

L. J. Bellamy and H. E. Hallam, Trans. Faraday Soc. 55, 220 (1959).
[Crossref]

Other (1)

E. E. Ferguson and R. E. Kagarise, J. Chem. Phys. (to be published).

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Figures (9)

Fig. 1
Fig. 1

Infrared dispersion of carbon disulfide corrected to 20°C.

Fig. 2
Fig. 2

Infrared dispersion of carbon tetrachloride corrected to 20°C.

Fig. 3
Fig. 3

Interference patterns of solutions of tetrachloroethylene in carbon disulfide.

Fig. 4
Fig. 4

Infrared dispersion of chloroform corrected to 20°C.

Fig. 5
Fig. 5

Infrared dispersion of cyclohexane corrected to 21.5°C.

Fig. 6
Fig. 6

Infrared dispersion of tetrachloroethylene at 31.2°C.

Fig. 7
Fig. 7

Infrared dispersion of methylene iodide at 31.2°C.

Fig. 8
Fig. 8

Infrared dispersion of acetone at 31.2°C.

Fig. 9
Fig. 9

Infrared dispersion of perfluoro-1,3,5-trimethyl cyclohexane at 31.2°C.

Tables (2)

Tables Icon

Table I Indexes of refraction of CS2 at 20°C.

Tables Icon

Table II Refractive index of CCl4 corrected to 20°C.