Table I
Wavelengths and wave numbers of germanium arc lines in the wavelength region from 11 252 A to 1546 A.
Rel. int. Shenstone’s intensitya Wavelength in air A Wave number cm−1 Combinationb WLc 0 11 252.85 8 884.21 8 −24° 1 11 144.66 8 970.45 3° −10 4 11 125.125 8 986.202 3° −11 0 11 040.20 9 055.33 4° −13 0 11 030.88 9 062.98 2° −7 4 10 947.412 9 132.078 2° −8 4 10 734.059 9 313.589 1° −7 1 10 731.80 9 315.55 8° −25.4 K 1 10 576.79 9 452.07 11 −32° 1 10 459.70 9 557.89 7° −25.6 K 10 10 404.895 9 608.228 3° −12 10 10 382.420 9 629.027 4° −14 1 10 305.24 9 701.15 6 −23° K 0 10 263.48 9 740.62 10 −33° 1 10 200.946 9 800.326 2° −9 3 10 039.427 9 957.998 3° −13 1 9 957.65 10 039.79 5° −25.5 K 0 9 844.16 10 155.52 K 0 9 731.0 10 273.6 10.1° −43 0 9 686.4 10 320.9 7° −28.9 0 9 663.1 10 345.8 8 −29° 7 9 625.658 10 386.052 2° −10 0 9 618.6 10 393.6 6° −28.5 0 9 612.1 10 500.7 6° −28.7 0 9 554.7 10 463.2 10 −36° 4 9 492.550 10 531.688 3° −14 6 9 398.862 10 636.667 1° −10 0 9 260.27 10 795.86 5° −28.5 0 9 233.28 10 827.42 11 −39° 5 9 095.953 10 990.884 4° −15 5 9 068.781 11 023.815 2° −12 1 8 930.425 11 194.602 6 −29° 0 8 895.613 11 238.411 9 −37° 0 8 879.361 11 258.980 8 −35° 1 8 789.884 11 373.591 2° −13 0 8 759.333 11 413.259 6 −30° 3 8 738.536 11 440.422 13 −49° 6 8 734.785 11 445.335 6 −31° 0 8 728.93 11 453.02 5 8 712.902 11 474.081 13 −50° 1 8 701.76 11 488.77 8° −35 9 8 700.602 11 490.301 8° −37 5 8 669.604 11 531.385 13 −52.2° 1 8 660.03 11 544.13 12 −46° 6 8 652.418 11 554.289 11 −43° 0 8 631.94 11 581.70 2 8 628.36 11 586.51 11 −44° 0 8 621.10 11 596.26 3 8 616.658 11 602.240 10 −44° 0 8 609.32 11 612.14 9 −41° 1 8 604.36 11 618.83 4 8 600.36 11 624.23 1° −13 6 8 599.271 11 625.699 10.1° −54 2 8 593.55 11 633.44 3 8 589.31 11 639.18 10 −45° 0 8 585.95 11 643.73 0 8 585.05 11 644.95 0 8 575.21 11 658.31 8 8 564.889 11 672.368 7° −38 0 8 564.08 11 673.47 13 −51.1° 3 8 561.32 11 677.24 12 −47° 1 8 549.35 11 693.58 14 −56° 4 8 541.894 11 703.790 12 −48° 4 8 532.252 11 717.016 8 −36° 5 8 507.658 11 750.888 6° −35 8 8 506.705 11 752.204 6° −36 1 8 485.76 11 781.21 13 −52° 10 8 482.214 11 786.136 7 −36° 4 8 479.30 11 790.19 12 −49° 3 8 455.15 11 823.87 12 −50° 0 8 441.35 11 843.19 5 8 429.416 11 859.959 8° −40 3 8 407.112 11 891.424 8° −41 5 8 396.355 11 906.658 8 −37° 0 8 392.31 11 912.39 7 8 391.699 11 913.264 8 −38° 4 8 387.51 11 919.22 8° −44 2 8 375.947 11 935.668 1 8 368.05 11 946.93 8 8 367.806 11 947.281 2° −14 4 8 347.908 11 975.758 7 −37° 3 8 343.296 11 982.378 7 −38° 0 8 322.06 12 012.95 0 8 320.07 12 015.82 2 8 316.04 12 021.64 9 −42° 0 8 290.70 12 058.39 10° −52 2 8 289.92 12 059.53 6 8 281.04 12 072.45 6 −34° 5 8 280.09 12 073.84 7° −42 0 8 276.58 12 078.96 0 8 268.19 12 091.23 10° −55 5 8 264.15 12 097.14 8 −39° 10 8 256.010 12 109.059 8 −40° 1 8 248.26 12 120.43 6° −39 1 8 240.70 12 131.56 7° −45 0 8 239.98 12 132.62 7° −46 7 8 226.086 12 153.109 5° −35 2 8 225.78 12 153.56 6° −41 5 8 225.22 12 154.39 5° −36 2 8 224.74 12 155.10 5° −38 3 8 221.33 12 160.14 12 −53° 0 8 217.22 12 166.22 7 −39° 0 8 209.21 12 178.09 13 −54° 4 8 206.67 12 181.86 10 −46° 1 8 199.00 12 193.26 1 8 185.64 12 213.16 6° −46 1 8 183.25 12 216.73 1 8 177.76 12 224.92 9 −45° 3 8 140.84 12 280.37 8 −41° 0 8 128.33 12 299.26 11 −47° 4 8 120.59 12 311.00 9° −51 4 8 119.37 12 312.84 8° −49 4 8 117.94 12 315.01 10 −47° 4 8 110.85 12 325.78 11 −48° 0 8 105.43 12 334.01 5 8 095.291 12 349.465 7 −41° 0 8 084.88 12 365.37 12 −53.1° 0 8 058.95 12 405.15 14 −57° 1 8 054.38 12 412.18 1 −49° 6 8 044.162 12 427.958 10 −49° 0 8 035.77 12 440.94 10.1° −56 10 8 031.037 12 448.268 11 −50.1° 1 8 001.11 12 494.83 50 −7° 0 7 985.70 12 518.93 10 −50.2° 5 7 983.327 12 522.661 5° −39 1 7 979.98 12 527.92 12 −54° 5 7 962.265 12 555.787 5° −41 1 7 955.91 12 565.81 6 −36° 2 7 951.96 12 572.05 6° −47 2 7 950.14 12 574.93 6° −48 2 7 924.68 12 615.34 5° −46 7 7 878.120 12 689.893 8 −42° 0 7 858.68 12 721.29 14 −57.2° 6 7 853.77 12 729.24 7 −41.1° 7 7 837.632 12 755.447 6 −37° 3 7 835.44 12 759.01 7 −42° 10 7 833.573 12 762.056 6 −38° 0 7 829.46 12 768.77 10 −52° 1 7 785.36 12 841.09 0 7 782.32 12 846.11 0 7 780.04 12 849.87 5 7 776.20 12 856.21 8 −44° 0 7 761.58 12 880.42 0 7 761.16 12 881.12 0 7 753.93 12 893.14 8 −45° 0 7 722.36 12 945.86 6 −39° 2 7 705.43 12 974.26 5° −47 1 7 703.72 12 977.17 5° −48 1 7 702.72 12 978.85 13 −57° 2 7 662.30 13 047.32 9 −50° 1 7 614.54 13 129.15 6 −41° 4 7 602.53 13 149.90 11 −54° 1 7 593.82 13 164.98 11 −55° 2 7 542.34 13 254.83 10 −56° 7 7 511.570 13 309.132 2° −15 2 7 440.70 13 435.89 8 −46° 6 7 402.645 13 504.965 7 −46° 2 7 400.48 13 508.91 6 −41.1° 7 7 384.208 13 538.684 6 −42° 2 7 367.72 13 568.98 8 −47° 5 7 353.332 13 595.531 8 −48° 7 7 330.380 13 638.081 7 −47° 0 7 324.08 13 649.83 9 −53.2° 1 7 306.89 13 681.95 8 −49° 2 7 275.00 13 741.93 6 −45° 2 7 184.50 13 915.02 8 −51.1° 2 7 158.07 13 966.40 10 −57° 0 7 138.89 14 003.92 7 −51.2° 6 7 130.117 14 021.149 11 −57.1° 1 7 129.31 14 022.75 8 −52° 2 7 114.52 14 051.89 8 −53° 0 6 998.591 14 284.651 6 −46° 0 6 771.48 14 763.74 6 −51.1° 1 6 702.68 14 915.29 4° −16 1 6 570.530 15 215.269 4° −17 6 6 557.488 15 245.532 4° −18 0 6 547.64 15 268.46 6 −54° 0 6 541.21 15 283.46 6 −55° 1 6 457.064 15 482.635 4° −19 0 6 202.55 16 117.93 3° −17 3 6 190.927 16 148.202 3° −18 1 6 078.379 16 447.201 4 5 998.361 16 666.606 4° −20 4 5 967.716 16 752.189 4° −21.6 4 5 906.013 16 927.205 4° −23 9 5 802.093 17 230.382 4° −25 6 5 801.032 17 233.532 2° −16 5 5 717.878 17 484.156 1° −16 6 5 701.778 17 533.524 2° −17 9 5 691.958 17 563.775 2° −18 1 5 690.17 17 569.29 3° −20 5 5 664.844 17 647.839 3° −20.5 6 5 664.227 17 649.761 3° −21 1 5 663.91 17 650.76 3° −22.4 8 5 655.962 17 675.552 4° −25.1 7 5 621.428 17 784.139 1° −17 6 5 616.137 17 800.892 2° −19 8 5 607.012 17 829.860 3° −23 8 5 564.742 17 965.297 3° −24 6 5 513.264 18 133.037 3° −25 3 5 403.852 18 500.176 4° −25.6 0 5 392.165 18 540.272 4° −26 3 5 384.601 18 566.316 4° −27 1 5 367.777 18 624.506 4° −27.5 1 5 342.398 18 712.981 4° −28 6 5 265.892 18 984.850 2° −20 0 5 242.25 19 070.47 2° −21.6 2 5 197.284 19 235.463 1° −20 3 5 194.586 19 245.451 2° −23 0 5 189.813 19 263.154 4° −28.9 0 5 158.285 19 380.889 2° −24 0 5 134.93 19 469.04 3° −27 1 5 113.97 19 548.85 2° −25 0 4 941.282 20 232.017 2 4 891.989 20 435.877 4° −34 0 4 840.68 20 652.49 4° −34.1 H 1 4 826.63 20 712.60 2° −25.2 0 4 792.864 20 858.520 2° −26 2 4 786.889 20 884.557 2° −27 0 4 753.509 21 031.211 2° −28 1 4 737.90 21 100.48 3° −30 H 0 4 735.964 21 109.120 1° −26 0 4 715.077 21 202.630 3° −32 1 4 707.50 21 236.74 3° −33 H 20 4 685.8286 21 334.972 5 −2° H 0 4 679.57 21 363.50 0 4 446.11 22 485.28 2° −29 1 4 429.14 22 571.42 2° −31 1 4 419.96 22 618.31 2° −32 1 4 380.50 22 822.03 1° −31 150 4 226.5625 23 653.228 5 −4° H 100 3 269.4889 30 577.007 4 −2° B 10 3 124.8164 31 992.605 4 −3° H 4 3 067.0214 32 595.451 5 −7° H 100 3 039.0671 32 895.262 4 −4° B 2 2 829.0076 35 337.687 5 −12° H 3 2 793.9249 35 781.393 5 −14° H 15 2 754.5878 36 292.345 3 −2° B 6 2 740.4264 36 479.879 5 −18° H 15 2 709.6237 36 894.555 2 −1° B 15 2 691.3411 37 145.171 2 −2° B 12 2 651.5683 37 702.305 1 −2° B 15 2 651.1720 37 707.941 3 −3° B 8 2 644.1836 37 807.595 5 −20° H 15 2 592.5340 38 560.768 2 −3° B 12 2 589.1878 38 610.600 3 −4° H 10 2 556.2979 39 107.341 5 −22° H 15 2 533.2305 39 463.426 2 −4° H 15 2 497.9625 40 020.561 1 −4° H 4 2 467.3681 40 516.765 3 −4.1° H 5 2 436.4120 41 031.518 5 −30° H 20 2 417.3672 41 354.753 4 −5° H 1 2 416.505 41 369.51 2 −4.1° H 6 2 397.8848 41 690.727 5 −34° H 4 2 394.0804 41 756.972 4 −6° H 5 2 389.4725 41 837.491 4 −7° H 12 2 379.1443 42 019.099 4 −8° H 4 2 359.2326 42 373.707 5 −37° H 4 2 338.6060 42 747.414 5 −41° H 15 2 327.9181 42 943.658 4 −9° H 1 2 316.44 43 156.5 5 −42° G 10 2 314.2014 43 198.171 4 −10° H 1 2 305.59 43 359.5 5 −45° G 0 2 262.71 44 181.1 5 −50° G 5 2 256.0007 44 312.503 4 −11° H 1 2 252.43 44 382.7 5 −51.1° G 2 2 247.04 44 489.1 5 −52° G 2 2 242.47 44 579.8 4 −12° G 0 50 Ha 2 232.284 44 783.2 5 −53.2° S 2 50 H 2 222.740 44 975.5 5 −56° S 4 500 2 220.3747 45 023.429 4 −14° H 2 h 2 207.253 45 291.1 S 20 1000 R 2 198.7144 45 466.925 4 −17° H 5 200 h 2 186.4508 45 721.919 4 −18° H 3 HH 2 173.68 45 990.5 S 3 HH 2 168.65 46 097.2 5 −57.4° S 10 H 2 163.377 46 209.5 5 −59° S Polar 5 H 2 161.71 46 245.1 S 3 30 2 136.711 46 786.1 4 −19° S 2h Polar 5 H 2 131.35 46 903.8 S 3h 2 128.57 46 965.1 5 500 H 2 124.7438 47 049.630 4 −20° H 3 200 2 123.825 47 070.0 3 −5° S 5 200 r 2 105.8241 47 472.294 3 −6° H 4 100 2 102.265 47 552.7 3 −7° S 25 500 R 2 094.2582 47 734.436 3 −8° H 6 2 086.0208 47 922.909 2 −5° H 2 ? 2 075.384 48 168.5 S 1 10 2 071.986 48 247.5 4 −21° S 8 1000 R 2 068.6562 48 325.130 2 −6° H 4 20 2 067.630 48 349.2 4 −22° S 8 300 R 2 065.2149 48 405.644 2 −7° H 3 100 h 2 058.586 48 561.5 4 −23° S 5 300 h 2 057.2382 48 593.309 4 −24° H 5 200 r? 2 054.4609 48 658.989 3 −9° H 8 on H 300 R 2 043.7695 48 913.499 3 −10° H 8 on H 300 R 2 041.7121 48 962.782 1 −7° H 7 on H 200 r 2 019.0684 49 511.819 2 −9° H 5 on h 200 r 2 011.293 49 703.20 4 −26° H 3 40 h 2 007.539 49 796.13 4 −27° H
Rel. int. Shenstone’s intensitya Wavelength vacuum A Wave number cm−1 Combinationb WLc 10 on H 500 R 1 998.887 50 027.84 3 −11° W 1 40 h 1 997.808 50 054.86 4 −29° W 4 40 1 989.114 50 273.64 4 −30° W 9 on H 300 r 1 988.268 50 295.03 3 −12° W 7 300 h 1 987.850 50 305.61 4 −31° W 9 on H 200 r (v) 1 970.879 50 738.78 3 −14° W 7 30 1 965.384 50 880.64 2 −11° W 5 30 h 1 963.375 50 932.71 4 −34° W 10 on H 500 r (v) 1 962.013 50 968.06 4 −35° W 8 on H 200 r 1 955.115 51 147.89 2 −12° W 2 15 s 1 953.805 51 182.18 3 −17° W 8 on h 200 r 1 944.730 51 421.02 2 −13° W 6 30 s 1 944.118 51 437.21 3 −18° W 5 on h 100 r (v) 1 938.301 51 591.57 2 −14° W 6 on h 100 r (v) 1 937.482 51 613.38 2 −15° W 1 1 937.152 51 622.2 4 −38° S 1 1 934.778 51 685.5 S 6 10 h 1 934.048 51 705.02 1 −12° W 0 1 930.278 51 806.01 4 −39° W 10 on H 500 R 1 929.828 51 818.09 4 −40° W 6 100 Hr (v)? 1 923.468 51 989.43 4 −41° W 0 1 919.634 52 093.3 S 8 on H 300 r 1 917.591 52 148.76 1 −14° W 5 30 1 912.406 52 290.15 2 −18° W 5 50 h 1 908.435 52 398.96 4 −42° W 9 on h 500 R 1 904.701 52 501.68 3 −19° W 3 5 1 903.565 52 533.01 4 −43° W 1 h 1 902.387 52 565.5 4 −44° S 1 3 1 901.069 52 601.98 4 −45° W 6 100 1 895.197 52 764.96 3 −20° W 1 2 h 1 881.682 53 143.94 4 −46° W 3 5 h 1 876.009 53 304.65 4 −48° W 8 on H 300 r 1 874.253 53 354.59 2 −19° W 1 2 h 1 872.974 53 391.02 4 −49° W 6 100 1 865.053 53 617.78 2 −20° W 2 10 h 1 861.097 53 731.75 4 −52° W 8 on HH 500 R 1 860.086 53 760.96 4 −53° W 7 on h 200 r? 1 853.132 53 962.70 3 −21° W 2 10 1 849.636 54 064.69 3 −22° W 7 100 HH 1 846.956 54 143.14 4 −55° W 7 100 h 1 845.871 54 174.97 1 −20° W 6 100 H 1 844.411 54 217.85 4 −56° W 6 200 h 1 842.408 54 276.79 3 −23° W 7 200 h 1 841.327 54 308.66 3 −24° W 0 2 h 1 838.321 54 397.46 4 −56.1° W 2 h 1 837.583 54 419.3 4 −56.2° S 2 h 1 836.649 54 447.0 4 −56.25° S 4 200 hr? 1 824.299 54 815.58 2 −21° W 1h 2 H 1 815.133 55 092.38 2 10 1 813.908 55 129.59 2 −23° W 3 on HH r 1 810.101 55 245.54 4 −57.2° W 2 2 HH 1 805.135 55 397.52 4 −58° W 4 50 h 1 804.453 55 418.46 3 −26° W 2 10 H 1 803.379 55 451.46 4 −59° W 4 30 h 1 802.626 55 474.62 1 −22° W 5 75 h 1 801.434 55 511.33 3 −27° W 5 100 h 1 793.071 55 770.24 3 −29° W 3 100 hr? 1 786.068 55 988.91 3 −30° W 5 on h 200 r 1 785.045 56 021.00 3 −31° W wide r 1 783.94 56 055.7 S 2 3 H 1 779.15 56 206.6 4 −66° S 5 on h 200 r? 1 774.175 56 364.23 2 −27° W 5 50 h 1 766.433 56 611.26 2 −28° W 4 50 h 1 766.065 56 623.06 2 −29° W 5 100 h 1 765.284 56 648.11 3 −34° W 5 100 hr? 1 764.187 56 683.33 3 −35° W 2 15 h 1 759.271 56 841.73 2 −30° W 6 on h 100 r 1 758.279 56 873.80 2 −31° W 5 on H 200 R (v) 1 750.044 57 141.42 3 −36° W on H r 1 749.796 57 149.5 S 5 H 1 749.67 57 153.6 S 2 15 1 748.859 57 180.14 1 −29° W 6 on h 50 r 1 746.064 57 271.67 2 −33° W 1 10 h 1 744.256 57 331.03 3 −37° W 1 15 h 1 744.054 57 337.67 3 −38° W 4 on h 100 r 1 742.194 57 398.89 1 −30° W 0 1 741.00 57 438.3 S 4 100 h (r?) 1 739.102 57 500.94 2 −34° W 3 100 h (r) 1 738.479 57 521.55 3 −39° W 3 50 h 1 738.119 57 533.46 3 −40° W 2 ? 1 732.974 57 704.3 3 −41° S 1 on H 20 r 1 724.308 57 994.28 2 −36° W 1 30 h 1 720.745 58 114.36 3 −42° W 1 on h r 1 718.688 58 183.92 2 −37° W 1 on h r 1 718.493 58 190.52 2 −38° W 5 on h 200 R 1 716.781 58 248.55 3 −43° W 3 on h 50 r 1 715.835 58 281.5 3 −44° W 1 h 1 714.779 58 316.6 3 −45° S 3 50 hr 1 713.080 58 374.39 2 −39° W 2 1 h 1 702.387 58 741.05 1 −37° W 2 30 h 1 696.718 58 937.31 2 −41.1° W 2 20 h 1 695.861 58 967.10 2 −42° W 3 5 h 1 694.343 59 019.93 3 −48° W 2 on h 5 r (v) 1 691.867 59 106.30 3 −49° W 2 on h 10 r (v)? 1 691.625 59 114.76 1 −41° W 6 on h 100 R 1 691.092 59 133.39 2 −44° W 2 1 690.901 59 140.07 3 −50° W 4 on h 50 r (v) 1 690.034 59 170.41 2 −45° W 1 5 h 1 685.221 59 339.40 3 −51.1° W 1 50 r 1 681.342 59 476.30 3 −53° W 0 2 1 679.987 59 524.28 1 −42° W 2 on H 50 R (v) 1 675.561 59 681.50 3 −53.1° W 2 on h 100 R (v) 1 674.272 59 727.45 1 −45° W 0 1 h 1 673.850 59 742.51 3 −53.2° W 2 5 h 1 671.011 59 844.01 3 −54° W 0 r? 1 670.954 59 846.05 2 −47° W r? 1 670.80 59 851.6 S 3 R 1 670.606 59 858.52 3 −54.5° W 4 on h r (v) 1 667.799 59 959.26 2 −49° W 3 10 h 1 665.275 60 050.14 2 −50.2° W 4 on H R 1 663.537 60 112.88 3 −56.1° W 2 on H r 1 662.986 60 132.80 3 −56.2° W 3 3 hr 1 661.344 60 192.23 2 −51.1° W 0 2 h 1 660.797 60 212.05 2 −51.2° W 2 3 h 1 658.375 60 299.99 2 −52° W 0 r 1 652.347 60 519.98 3 −56.3° W 4 on H R 1 651.953 60 534.41 2 −53.1° W 3 h 1 651.605 60 547.2 S 2 r 1 651.527 60 550.02 1 −50° W 1 on h r (v) 1 650.293 60 595.30 2 −53.2° W 2 on h r 1 647.530 60 696.92 2 −54° W 0 1 647.124 60 711.88 2 −55° W 00 1 647.165 60 710.37 0 2 h 1 645.115 60 786.02 2 −56° W r 1 644.52 60 807.9 2 −56.05° S r 1 644.123 60 822.7 S 1 on h r (v) 1 643.193 60 857.12 1 −52° W r 1 640.394 60 961.0 3 −57.2° S 4 on H R 1 639.729 60 985.69 2 −56.2° W 1 r 1 639.641 60 988.96 2 −56.23° W 2 on H r 1 638.958 61 014.38 2 −56.25° W r 1 638.138 61 044.9 3 −57.3° S r? 1 637.74 61 059.8 3 −57.4° S 3 R 1 636.312 61 113.04 3 −58° W r 1 636.062 61 122.4 3 −58.1° S 1 on H R 1 635.257 61 152.47 1 −53.2° W 1 R 1 633.470 61 219.37 3 −59.5°? W r 1 633.312 61 225.3 3 −60° S 2 on h R (v) 1 630.173 61 343.18 1 −56° W r 1 629.600 61 364.8 1 −56.05° S r 1 629.145 61 381.9 S r? 1 625.46 61 521.0 2 −57.05°? S r? 1 624.78 61 546.8 1 −56.23° S 2 on h R 1 624.126 61 571.6 1 −56.25° S r? 1 617.29 61 831.8 S r 1 616.509 61 861.7 S
r 1 615.715 61 892.1 3 −65° S 3 R 1 615.571 61 897.6 2 −57.3° S r 1 615.234 61 910.5 2 −57.4° S r 1 614.792 61 927.5 3 −67° S r 1 613.818 61 964.9 2 −58 S 1 1 613.658 61 971.0 S r 1 613.557 61 974.9 2 −58.1° S R 1 612.974 61 997.3 3 −68° S R 1 610.866 62 078.4 1 −57.05° S or 2 −60° r 1 610.774 62 082.0 2 −61° S r 1 608.500 62 169.5 S r 1 606.799 62 235.5 S r 1 604.28 62 333.3 S R 1 600.824 62 467.8 1 −57.4° S on h r 1 598.020 62 577.4 1 −59° S r 1 596.711 62 628.7 S r 1 596.443 62 639.3 1 −61° S r 1 596.229 62 647.7 S r 1 595.228 62 687.0 S r? 1 595.046 62 694.1 2 −63° S r 1 593.950 62 737.2 2 −64° S r 1 592.842 62 780.9 2 −67° S r 1 591.98 62 814.9 S r? 1 591.87 62 819.2 S r? 1 591.07 62 850.8 2 −68° S wide r 1 587.63 62 986.9 S wide r 1 582.95 63 173.2 S r 1 580.989 63 251.5 1 −63° S r? 1 579.899 63 295.2 1 −64° S r? 1 579.405 63 315.0 S r? 1 547.412 64 624.0 S r 1 547.069 64 638.4 S r? 1 546.883 64 646.1 S r 1 546.581 64 658.8 S r 1 546.234 64 673.3 S
a Shenstone used the following symbols with the meanings indicated in his characterization of the uv lines: h (slightly hazy), H (hazy), HH (very hazy, r (narrow-self reversal), R (wide-self reversal), r(v) (reversal toward violet side of emission lines), on h (reversal appearing on slightly hazy background), on H (reversal appearing on hazy background), on HH (reversal appearing on very hazy background), s (sharp), hp (hazy and polar). In the short wave end, the lines appear as reversals on a continuous or nearly continuous background and no intensity can be given.
b The numbers in this column with superscript ° refer to the odd levels as listed in
Table III and those without the superscript refer to the even levels as listed in
Table II .
c The column headed by “WL” refers to the source of the wavelength values given in this table. The letter “
B ” indicates that the values are taken from the atomic beam interferometric measurements of Deverall, Meissner and Zissis,
7 “
H ” refers to the hollow cathode interferometric measurements of Van Veld and Meissner,
5 “
W ” denotes the hollow cathode grating measurements in the vacuum region made by Meissner, Van Veld, and Wilkinson,
6 “
S ” indicates the measurements of Shenstone
† and “
K ” refers to those of Kiess.
4 No entry in this column indicates that the values are the results of those measurements by Andrew and Meissner which are discussed in Sec. II.
Table II
Even energy levels of Ge I.
Level designations given by different authors Level number Level value cm−1 Present work Moore (AEL) Kiess Rao and Gartlein 1 0.000 4p 3 P 0
same same same 2 557.134 4p 3 P 1 3 1 409.961 4p 3 P 2 4 7 125.299 4p 1 D 2 5 16 367.333 4p 1 S 0 6 45 985.602 5p 3 D 1 5p 1 P 1 7 46 765.283 5p 1 P 1 3 D 1 5p 3 D 1 8 46 834.384 5p 3 D 2 3 D 2 3 D 2 9 47 502.631 5p 3 P 0 3 P 0 3 P 0 10 48 088.356 5p 3 P 1 3 P 1 3 P 1 11 48 104.104 5p 3 D 3 3 D 3 3 D 3 12 48 726.120 5p 3 P 2 3 P 2 3 P 2 13 49 075.898 5p 3 S 1 3 S 1 3 S 1 14 49 649.588 5p 1 D 2 1 D 2 1 D 2 15 51 011.442 5p 1 S 0 1 S 0 1 S 0 16 54 935.841 6p 3 D 1 6p 1 P 1 17 55 235.829 6p 1 P 1 3 D 1 6p 3 D 1 18 55 266.092 6p 3 D 2 3 D 2 3 D 2 19 55 503.196 6p 3 P 0 3 P 0 20 56 687.165 6p 3 P 1 3 P 1 20.5 (56 765.741)a 4f 1 F 3 21 (56 767.663) 6p 3 D 3 3 D 3 21.4 (56 768.66) 4f 3 F 3 21.6 56 772.750 4f 3 F 2 23 56 947.761 6p 3 P 2 6p 3 P 2 24 57 083.196 6p 3 S 1 3 S 1 25 57 250.940 6p 1 D 2 1 D 2 6p 1 D 2 25.1 57 696.112 6p 1 S 0 1 S 0 25.2 58 414.90 7p 3 D 1 25.4 (58 459.95) 4f 3 G 4 25.5 (58 519.83) 4f 3 D 3 25.6 58 520.737 4f 3 D 2 26 58 560.819 7p 1 P 1 7p 3 D 1 27 58 586.871 7p 3 D 2 3 D 2 27.5 (58 645.067) 4f 1 D 2 28 58 733.524 7p 3 P 0 28.5 59 275.91 5f 1 F 3 28.7 (59 282.94) 5f 3 F 3 28.9 59 283.715 5f 3 F 2 29 60 187.58 7p 3 P 1 30 60 218.38 7p 3 D 3 31 60 273.72 8p 1 P 1 32 60 320.532 7p 3 P 2 33 60 354.64 7p 3 S 1 34 60 456.437 7p 1 D 2 34.1 60 673.05 7p 1 S 0 35 60 633.157 6f 1 F 3 36 60 634.467 6f 3 F 3 37 (60 634.696) 6f 3 F 4 38 60 635.152 6f 3 F 2 38.5 60 673.05 7p 1 S 0 39 61 002.709 5f 3 G 3 40 (61 004.356) 5f 3 G 4 41 61 035.830 5f 3 D 3 42 (61 036.72) 5f 3 D 2 43 (61 058.6±5.0) 5f 3 G 5 44 (61 063.62) 5f 1 G 4 45 (61 094.34) 5f 3 D 1 46 61 095.40 5f 3 D 2 47 61 454.32 7f 1 F 3 48 61457.20 7f 3 F 3 49 (61 457.24) 7f 3 F 4 50 (61 457.61) 7f 3 F 2 51 (62 379.95) 6f 3 G 3 52 (62 381.86) 6f 3 G 4 54 (62 410.7±5.0) 6f 3 G 5 55 (62 414.70) 6f 1 G 4 56 (63 225.9±5.0) 7f 3 G 5
a When a level value appears in parentheses it indicates that the level has been established by a single combination as discussed in Sec. IV,3,
f .
Table III
Odd energy levels of Ge I.
Level designations given by different authors Level number Level value cm−1 Present work Moore (AEL) Rao Gartlein 1° 37 451.689 5s 3 P 0 °
same same same 2° 37 702.305 5s 3 P 1 ° 3° 39 117.902 5s 3 P 2 ° 4° 40 020.560 5s 1 P 1 ° 4.1° 41 926.726 4s 4p 3 5 S 2 ° ⋯ ⋯ ⋯ 5° 48 480.048 4d 1 D 2 ° 4d 1 D 2 ° 4d 1 D 2 ° 4d 1 D 2 ° 6° 48 882.263 4d 3 D 2 ° 4d 3 D 2 ° 4d 3 D 2 ° 4d 3 F 2 ° 7° 48 962.783 4d 3 D 1 ° same same same 8° 49 144.397 4d 3 D 3 ° 4d 3 D 3 ° 4d 3 D 3 ° 4d 3 F 3 ° 9° 50 068.954 4d 3 F 2 ° 4d 3 F 2 ° 4d 3 F 2 ° 4d 3 D 2 ° 10° 50 323.465 4d 3 F 3 ° 4d 3 F 3 ° 4d 3 F 3 ° 4d 3 D 3 ° 10.1° 50 785±5 4d 3 F 4 ° ⋯ ⋯ ⋯ 11° 51 437.802 4d 3 P 2 ° same same same 12° 51 705.020 4d 3 P 1 ° same same same 13° 51 978.15 4d 3 P 0 ° 4d 3 P 0 ° 4d 3 P 0 ° 6s 3 P 0 ° 14° 52 148.727 6s 3 P 1 ° same same same 15° 52 170.51 6s 3 P 0 ° 6s 3 P 0 ° 6s 3 P 0 ° 4d 3 P 0 ° 17° 52 592.224 4d 1 F 3 ° same same same 18° 52 847.215 4d 1 P 1 ° same same same 19° 53 911.70 6s 3 P 2 ° same same same 20° 54 174.928 6s 1 P 1 ° same same same 21° 55 372.68 5d 1 D 2 ° 5d 3 D 2 ° 5d 3 D 2 ° ⋯ 22° 55 474.674 5d 3 D 1 ° same same same 23° 55 686.74 5d 3 D 2 ° 5d 3 D 3 ° 5d 3 D 3 ° ⋯ 24° 55 718.608 5d 3 D 3 ° 5d 1 D 2 ° 5d 1 D 2 ° 5d 3 F 3 ° 26° 56 828.32 5d 3 F 3 ° 5d 3 F 3 ° 5d 3 F 3 ° 5d 1 D 2 ° 27° 56 921.32 5d 3 F 2 ° 7s 1 P 1 ° 7s 1 P 1 ° ⋯ 28° 57 168.39 7s 3 P 0 ° same same ⋯ 29° 57 180.198 7s 3 P 1 ° 5d 3 P 2 ° 5d 3 P 2 0 ⋯ 30° 57 398.850 5d 3 P 1 ° 4s 4p 3 3 P 1 ° 4s 4p 3 3 P 1 0 7s 3 P 1 ° 31 57 430.931 5d 3 P 2 ° 5d 3 P 1 ° 5d 3 P 1 0 5d 3 D 3 ° 32° 57 556.17 5d 3 F 4 ° ⋯ ⋯ ⋯ 33° 57 828.98 5d 3 P 0 ° ⋯ ⋯ ⋯ 34° 58 058.060 5d 1 P 1 ° same same same 35° 58 093.364 5d 1 F 3 ° 4s 4p 3 1 D 2 ° 4s 4p 3 1 D 2 ° 5d 1 F 3 ° 36° 58 551.414 6d 1 D 2 ° ⋯ ⋯ 7s 1 P 1 ° 37° 58 741.040 6d 3 D 1 ° ⋯ ⋯ ⋯ 38° 58 747.654 6d 3 D 2 ° ⋯ ⋯ ⋯ 39° 58 931.49 7s 3 P 2 ° same same ⋯ 40° 58 943.443 6d 3 D 3 ° 5d 1 F 3 ° 5d 1 F 3 ° ⋯ 41° 59 114.747 7s 1 P 1 ° 7s 1 P 1 ° 7s 1 P 1 ° a P 1 °41.1° 59 494.52 8s 3 P 0 ° ⋯ ⋯ ⋯ 42° 59 524.277 8s 3 P 1 ° 1 X 1 °1 X 1 °43° 59 658.393 4s 4p 3 3 D 3 ° same same ⋯ 44° 59 690.596 4s 4p 3 3 D 2 ° same same ⋯ 45° 59 727.54 4s 4p 3 3 D 1 ° same same ⋯ 46° 60 270.248 4s 4p 3 3 S 1 ° ⋯ ⋯ ⋯ 47° 60 403.364 6d 3 F 2 ° ⋯ ⋯ ⋯ 48° 60 429.914 6d 3 F 3 ° ⋯ ⋯ ⋯ 49° 60 516.316 6d 3 P 2 ° ⋯ ⋯ ⋯ 50° 60 549.979 6d 3 P 1 ° ⋯ ⋯ ⋯ 50.1° 60 552.372 6d 3 F 4 ° ⋯ ⋯ ⋯ 50.2° 60 607.283 6d 3 P 0 ° ⋯ ⋯ ⋯ 51.1° 60 749.34 6d 1 P 1 ° ⋯ ⋯ ⋯ 51.2° 60 769.20 9s 3 P 0 ° ⋯ ⋯ ⋯ 52° 60 857.12 9s 3 P 1 ° ⋯ ⋯ ⋯ 53° 60 886.27 6d 1 F 3 ° 6d 1 D 2 ° 6d 1 D 2 ° ⋯ 53.1° 61 091.49 7d 1 D 2 ° ⋯ ⋯ ⋯ 53.2° 61 152.46 7d 3 D 1 ° ⋯ ⋯ ⋯ 54° 61 254.02 8s 3 P 2 ° 3 X 2 °3 X 2 °⋯ 54.5° 61 268.46 7d 3 D 3 ° ⋯ ⋯ ⋯ 55° 61 269.07 7d 3 D 2 ° ⋯ ⋯ ⋯ 56° 61 343.18 8s 1 P 1 ° same same ⋯ 56.05° 61 364.9 ⋯ 56.1° 61 522.78 8d 3 D 3 ° 56.2° 61 542.79 8d 1 D 2 ° 56.3° 61 546.31 10s 3 P 1 ° 56.25° 61 571.5 8d 3 D 1 ° 56.3° 61 930.06 7d 3 F 3 ° 57° 62 054.75 7d 3 P 2 ° 57.05° 62 078.4? 9d 3 D 1 ° 57.1° 62 125.253 7d 3 F 4 ° 57.2° 62 370.88 7d 1 F 3 ° 57.3° 62 454.8 10d 1 D 2 ° 57.4° 62 467.7 10d 3 D 1 ° 58° 62 522.9 10d 3 D 3 ° 58.1° 62 532.2 9s 3 P 2 ° 59° 62 577.1 9s 1 P 1 ° 59.5° 62 629.4? 11d 3 D 3 ° 60° 62 635.4? 11d 1 D 2 ° 61° 62 639.2 11d 3 D 1 ° 63° 63 251.4 8d 3 P 1 °? 64° 63 294.8 8d 1 P 1 °? 65° 63 302.1? 10s 3 P 2 ° 66° 63 332.2 10s 1 P 1 ° 67° 63 337.8 8d 3 F 2 °? 68° 63 407.4 8d 3 P 2 °?
Table IV
Predicted terms of Ge I.
Config. 1s 2 2s 2 2p 6 3s 2 3p 6 3d 10 + Predicted terms 4s 2 4p 2
3 P 1 S 1 D 4s 4p 3
5 S 0 3 S °3 P °3 D °1 P °1 D °ns (n ≥5)np (n ≥5)nd (n ≥4)nf (n ≥4)⋯ 4s 2 4p (2 P 0 )nx 3 P °3 S 3 P 3 D 3 P °3 D °3 F °3 D 3 F 3 G ⋯ 1 P °1 S 1 P 1 D 1 P °1 D °1 F °1 D 1 F 1 G ⋯ 4s 4p 2 (4 P )nx ′ 5 P 5 S °5 P °5 D °5 P 5 D 5 F 5 D °5 F °5 G °⋯ 3 P 3 S °3 P °3 D °3 P 3 D 3 F 3 D °3 F °3 G °⋯
Table VI
Series limit calculations.
Series Series limit Levels used in the calculation Constants Other level values Lower limit cm−1 Upper limit cm−1 Computed cm−1 Observed cm−1 ns 3 P 2 ° n ≧5(63 727.1) 65 494.4 T 7 T 8 T 9 3+a =0.082042 T 5 =24 673.826 376.5 α =0.001018×10−3 T 6 =11 464.511 583.1 T 10 =2 186.62 192.3 ns 1 P 1 ° n ≧5
(63 708.9) 65 476.3 T 7 , T 8 , T 9 3+a =0.152124 T 5 =23 580.525 455.6 α =0.000201×10−3 T 6 =11 028.611 301.4 T 10 =2 145.02 144.1 (63 713.0) 65 480.4 T 8 , T 9 , T 10 3+a =0.141916 T 5 22 856.725 460.2 α =0.001933T 6 =10 871.011 305.9 T 7 =6 358.76 366.0 ns 3 P 0 ° n ≧563 720.8 (65 488.2) T 7 , T 8 , T 9 3+a =0.101784 T 5 =25 760.926 269.0 α =−0.001441×10−3 T 6 =11 529.211 549.6 np 1 P 1 n ≧463 692.6 (65 459.9) T 5 , T 6 , T 7 3+a =0.658231 T 4 =71353.463 135.6 α =−0.006622×10−3 np 3 D 2 n ≧563 718.3 (65 485.6) T 5 , T 6 , T 7 3+a =0.657224 α =−0.0063855×10−3 np 3 P 2 n ≧4(63 793.6) 65 561.0 T 5 , T 6 , T 7 3+a =0.586412 T 4 =51 513.764 151.0 α =−0.0019778×10−3 nd 3 F 4 n ≧4(63 718.7) 65 486.10 T 5 , T 6 , T 7 2+a =0.708956 T 4 =14 738.714 701±5 α =0.001370×10−3