Abstract

The various instrumental factors which affect both peak and integrated Raman band intensities in liquids are discussed. These factors include the refractive index, color, and temperature of the sample; slit function and spectral sensitivity of the spectrophotometer; and the convergence and line width of the exciting radiation. Procedures for applying corrections for these factors relative to the 459 cm<sup>-1</sup>. band of carbon tetrachloride are presented. These considerations will allow good relative band areas to be obtained and will facilitate the interchangability of peak intensity data between different laboratories.

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  1. White, Alpert, and de Bell, J. Opt Soc. Am. 45, 154 (1955).
  2. H. H. Cary, J. Opt. Soc. Am. (to be published).
  3. H. J. Bernstein and G. Allen, J. Opt. Soc. Am. 45, 237 (1955).
  4. Long, Milner, and Thomas, Proc. Roy. Soc. (London) 237A, 197 (1956).
  5. S. R. Polo and M. K. Wilson, J. Chem. Phys. 23, 2376 (1955).
  6. W. C. Mallard and J. W. Straley, J. Chem. Phys. 27, 877 (1957).
  7. L. A. Woodward and J. H. B. George, Proc. Phys. Soc. (London) 64, 780 (1951).
  8. J. H. Jaffe and S. Kimel, J. Chem. Phys. 25, 374 (1956).
  9. R. A. Russell and H. W. Thompson, J. Chem. Soc. 479 (1955).
  10. E. E. Ferguson, J. Chem. Phys. 26, 1265 (1957).
  11. D. A. Ramsay, J. Am. Chem. Soc. 74, 72 (1952).
  12. P. C. von Planta, J. Opt. Soc. Am. 47, 629 (1957).
  13. Kh. E. Sterin, Izvest. Akad. Nauk. S.S.S.R. Ser. Fiz. 14, 411 (1950).
  14. G. Placzek, Handbuch der Radiologie VI (Leipzig, Germany, 1934), p. 2.
  15. D. H. Rank and R. E. Kagarise, J. Opt. Soc. Am. 40, 89 (1950).
  16. D. R. J. Boyd (private communication).
  17. B. P. Stoicheff, Can. J. Phys. 32, 330 (1954).
  18. Rosenbaum, Cerato, and Lauer, J. Opt. Soc. Am. 42, 670 (1952).

Allen, G.

H. J. Bernstein and G. Allen, J. Opt. Soc. Am. 45, 237 (1955).

Bernstein, H. J.

H. J. Bernstein and G. Allen, J. Opt. Soc. Am. 45, 237 (1955).

Boyd, D. R. J.

D. R. J. Boyd (private communication).

Cary, H. H.

H. H. Cary, J. Opt. Soc. Am. (to be published).

Ferguson, E. E.

E. E. Ferguson, J. Chem. Phys. 26, 1265 (1957).

George, J. H. B.

L. A. Woodward and J. H. B. George, Proc. Phys. Soc. (London) 64, 780 (1951).

Jaffe, J. H.

J. H. Jaffe and S. Kimel, J. Chem. Phys. 25, 374 (1956).

Kagarise, R. E.

D. H. Rank and R. E. Kagarise, J. Opt. Soc. Am. 40, 89 (1950).

Kimel, S.

J. H. Jaffe and S. Kimel, J. Chem. Phys. 25, 374 (1956).

Mallard, W. C.

W. C. Mallard and J. W. Straley, J. Chem. Phys. 27, 877 (1957).

Placzek, G.

G. Placzek, Handbuch der Radiologie VI (Leipzig, Germany, 1934), p. 2.

Polo, S. R.

S. R. Polo and M. K. Wilson, J. Chem. Phys. 23, 2376 (1955).

Ramsay, D. A.

D. A. Ramsay, J. Am. Chem. Soc. 74, 72 (1952).

Rank, D. H.

D. H. Rank and R. E. Kagarise, J. Opt. Soc. Am. 40, 89 (1950).

Russell, R. A.

R. A. Russell and H. W. Thompson, J. Chem. Soc. 479 (1955).

Sterin, Kh. E.

Kh. E. Sterin, Izvest. Akad. Nauk. S.S.S.R. Ser. Fiz. 14, 411 (1950).

Stoicheff, B. P.

B. P. Stoicheff, Can. J. Phys. 32, 330 (1954).

Straley, J. W.

W. C. Mallard and J. W. Straley, J. Chem. Phys. 27, 877 (1957).

Thompson, H. W.

R. A. Russell and H. W. Thompson, J. Chem. Soc. 479 (1955).

von Planta, P. C.

P. C. von Planta, J. Opt. Soc. Am. 47, 629 (1957).

Wilson, M. K.

S. R. Polo and M. K. Wilson, J. Chem. Phys. 23, 2376 (1955).

Woodward, L. A.

L. A. Woodward and J. H. B. George, Proc. Phys. Soc. (London) 64, 780 (1951).

Other

White, Alpert, and de Bell, J. Opt Soc. Am. 45, 154 (1955).

H. H. Cary, J. Opt. Soc. Am. (to be published).

H. J. Bernstein and G. Allen, J. Opt. Soc. Am. 45, 237 (1955).

Long, Milner, and Thomas, Proc. Roy. Soc. (London) 237A, 197 (1956).

S. R. Polo and M. K. Wilson, J. Chem. Phys. 23, 2376 (1955).

W. C. Mallard and J. W. Straley, J. Chem. Phys. 27, 877 (1957).

L. A. Woodward and J. H. B. George, Proc. Phys. Soc. (London) 64, 780 (1951).

J. H. Jaffe and S. Kimel, J. Chem. Phys. 25, 374 (1956).

R. A. Russell and H. W. Thompson, J. Chem. Soc. 479 (1955).

E. E. Ferguson, J. Chem. Phys. 26, 1265 (1957).

D. A. Ramsay, J. Am. Chem. Soc. 74, 72 (1952).

P. C. von Planta, J. Opt. Soc. Am. 47, 629 (1957).

Kh. E. Sterin, Izvest. Akad. Nauk. S.S.S.R. Ser. Fiz. 14, 411 (1950).

G. Placzek, Handbuch der Radiologie VI (Leipzig, Germany, 1934), p. 2.

D. H. Rank and R. E. Kagarise, J. Opt. Soc. Am. 40, 89 (1950).

D. R. J. Boyd (private communication).

B. P. Stoicheff, Can. J. Phys. 32, 330 (1954).

Rosenbaum, Cerato, and Lauer, J. Opt. Soc. Am. 42, 670 (1952).

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