The Influence of Varying Amounts of Elements in Steel and Cast Irons on Spectral Intensity

Lillian J. Canody; T. Harris; J. F. Woodruff

doi:10.1364/JOSA.43.000145

Journal of the Optical Society of America
Vol. 43,
Issue 2,
pp. 145-148
(1953)
•https://doi.org/10.1364/JOSA.43.000145

The Influence of Varying Amounts of Elements in Steel and Cast Irons on Spectral Intensity

Lillian J. Canody, T. Harris, and J. F. Woodruff

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Lillian J. Canody, T. Harris, and J. F. Woodruff, "The Influence of Varying Amounts of Elements in Steel and Cast Irons on Spectral Intensity," J. Opt. Soc. Am. 43, 145-148 (1953)

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Abstract

The effect upon spectral intensity of varying amounts of elements in approximately sixty Bureau of Standards steel samples have been investigated. Samples used in the study included cast iron, low and high carbon steels, and low and high alloy steels. Of all the certified analyses, only varying amounts of carbon, chromium, and phosphorous appeared to affect spectral intensity. Experimental data and spectrochemical techniques are discussed.

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No.	% Transmission of 3173A Fe	Averaged analyses reported in supplement to NBS circular C 398
No.	% Transmission of 3173A Fe	% C	% Mn	% P	% S	% Si	% Cu	% Ni	% Cr	% V	% Mo	% Ti	% As
4g	14.	2.47	0.843	0.122	0.071	1.33	0.24	0.065	0.118	0.011	0.017	0.024	0.012
5g	16.	2.86	0.610	0.261	0.122	1.84	1.44	0.128	0.018	0.021	0.001	0.066	0.32
5h	18.	2.91	0.603	0.263	0.120	1.85	1.45	0.124	0.020	0.019	⋯	⋯	⋯
5i	17.	2.52	0.696	0.241	0.101	2.44	1.00	0.016	0.020	0.015	0.005	0.044	0.025
7C	24.	2.33	0.564	0.778	0.064	1.79	0.039	0.010	0.019	0.042	0.002	0.067	0.071
7d	19.	2.41	0.563	0.77	0.066	1.81	0.042	0.010	0.020	0.038	0.003	0.07	⋯
122	14.	3.06	0.511	0.31	0.034	0.585	0.043	0.023	0.032	0.016	0.002.	0.009	0.019
107	15.	2.57	0.706	0.197	0.090	2.34	0.074	0.807	0.455	0.015	0.687	0.037	0.01
82	9.5	2.78	0.722	0.102	0.033	2.09	0.020	1.00	0.245	0.011	0.004	0.048	0.009
6e	14.	2.61	1.36	0.431	0.079	2.33	0.254	0.062	0.074	0.024	0.016	0.025	⋯

No.	% Transmission of 3173A Fe	Averaged analyses reported in supplement to NBS circular C 398
No.	% Transmission of 3173A Fe	% C	% Mn	% P	% S	% Si	% Cu	% Ni	% Cr	% V	% Mo	% Other elements
11e	22.	0.18	0.451	0.015	0.028	0.316	0.105	0.045	0.036	0.002	0.007	N—0.004
12d	22.	0.418	0.344	0.013	0.036	0.016	0.015	0.007	0.015	0.002	0.016	⋯
12e	24.	0.371	.0.706	0.014	0.026	0.278	0.142	0.058	0.050	0.002	0.016	⋯
13d	14.	0.576	0.924	0.016	0.025	0.265	0.022	0.010	0.023	0.002	0.002	⋯
14c	9.	0.791	0.462	0.012	0.030	0.058	0.025	0.010	0.025	0.003	0.002	Al—0.025
15d	27.	0.100	0.393	0.018	0.033	0.079	0.054	0.024	0.060	0.001	0.007	⋯
19c	25.	0.214	0.630	0.049	0.040	0.201	0.161	0.179	0.063	⋯	⋯	⋯
152	13.	0.466	0.782	0.020	0.027	0.244	0.127	0.062	0.050	0.002	0.002	N—0.004; Sn—0.036
16c	5.	1.01	0.385	0.032	0.044	0.168	0.060	0.023	0.045	0.003	0.001	As—0.007
19d	27.	0.205	0.450	0.034	0.041	0.173	0.158	0.163	0.039	0.005	0.017	N—0.004
21c	7.5	0.574	0.630	0.062	0.030	0.107	0.050	0.152	0.166	0.007	0.005	As—0.008
34a	10.	0.762	0.501	0.028	0.026	0.276	0.222	0.232	0.275	0.007	0.003	As—0.009
35a	10.5	1.03	0.345	0.037	0.037	0.387	0.267	0.254	0.264	0.011	0.004	As—0.009; Al—0.002
20d	10.	0.411	0.916	0.048	0.098	0.254	0.164	0.227	0.283	0.049	0.062	⋯
55a	33.	0.014	0.022	0.004	0.020	0.001	0.046	0.019	0.006	0.0005	0.004	N—0.004; Al—0.002
55b	30.	0.012	0.015	0.003	0.019	0.001	0.042	0.016	0.002	0.001	0.004	Sn—0.005; Al—0.002
8g	21.	0.069	0.427	0.093	0.026	0.013	0.019	0.011	0.009	0.002	0.003	N—0.021; Sn—0.002
9c	16.	0.202	0.068	0.096	0.036	0.047	0.020	0.003	0.007	0.006	0.003	As—0.009; Sn—0.002
9d	21.	0.204	0.620	0.096	0.036	0.032	0.009	0.004	0.004	0.005	0.002	N—0.017
10e	21.	0.406	0.634	0.083	0.047	0.067	0.032	0.020	0.023	0.004	0.010	As—0.004; N—0.010
22c	16.	0.482	0.746	0.083	0.080	0.098	0.011	0.004	0.007	0.006	0.001	Al—0.116; N—0.010
22b	8.	0.674	0.935	0.084	0.041	0.123	0.009	0.003	0.003	0.005	0.002	As—0.004; Sn—0.0004
65b	16.	0.294	0.725	0.031	0.012	0.341	0.205	0.052	0.042	0.004	0.006	⋯
65c	16.	0.339	0.878	0.023	0.031	0.440	0.050	0.040	0.025	0.002	0.007	Sn—0.008
51a	4.7	1.27	0.233	0.010	0.010	0.308	0.082	0.063	0.056	0.002	0.002	Sn—0.011
129	20.	0.131	0.855	0.109	0.260	0.014	0.166	0.061	0.049	0.004	0.007	As—0.007
130	16.	0.454	0.688	0.025	0.021	0.237	0.017	0.009	0.029	⋯	0.003	Pb—0.204

No.	% Transmission of 3173A Fe	Averaged analyses reported in supplement to NBS circular C 398
No.	% Transmission of 3173A Fe	% C	% Mn	% P	% S	% Si	% Cu	% Ni	% Cr	% V	% Mo	% Other elements
101c	69.	0.069	0.597	0.018	0.025	0.480	0.168	8.97	18.50	0.049	0.078	N—0.035; Co—0.079; Cb—0.106
50a	17.	0.66	.287	0.020	0.007	0.480	0.047	0.045	3.52	0.970	0.009	As—0.042; W—18.25
50b	21.	0.728	0.325	0.029	0.007	0.294	0.110	0.089	4.08	1.02	0.401	Sn—0.025; W—18.05; As—0.041
153	16.	0.864	0.219	0.025	0.008	0.187	0.099	0.107	4.14	2.04	8.38	W—1.58; Co—8.45
73a	47.	0.349	0.249	0.015	0.030	0.311	0.080	0.159	14.09	0.028	0.069	W—0.091; N—0.036
121a	55.	0.073	1.28	0.023	0.010	0.52	0.085	10.58	18.69	0.035	0.020	Ti—0.36; Co—0.09; N—0.014
132	19.	0.803	0.252	0.027	0.004	0.239	0.149	0.094	4.11	1.64	7.07	W—6.29
133	53.	0.118	0.799	0.022	0.355	0.433	0.061	0.286	13.59	0.020	0.56	N—0.046
134	14.	0.810	0.155	0.016	0.006	0.323	0.114	0.077	3.73	1.13	8.68	W—1.82
33b	8.5	0.366	0.700	0.037	0.032	0.233	0.114	3.48	0.029	0.005	0.003	As—0.016
33c	14.	0.368	0.733	0.017	0.030	0.283	0.031	3.28	0.052	0.002	0.032	N—0.003; Al—0.032; Sn—0.003
30d	10.	0.363	0.786	0.031	0.031	0.286	0.092	0.150	1.15	⋯	0.034	⋯
32c	12.	0.429	0.752	0.010	0.018	0.281	0.099	1.20	0.654	0.003	0.063	N—0.006
36	13.	0.129	0.390	0.018	0.021	0.309	0.112	0.128	2.31	0.006	1.01	N—0.013
100	14.	0.617	1.38	0.023	0.022	0.191	0.124	0.151	0.180	0.011	0.005	⋯
100a	13.	0.447	1.66	0.020	0.027	0.243	0.050	0.032	0.051	0.003	0.008	⋯
139	7.	0.394	0.867	0.019	0.024	0.292	0.089	0.563	0.549	0.002	0.178	⋯
156	13.	0.515	1.40	0.032	0.017	0.226	0.053	0.475	0.429	0.002	0.138	⋯
125	16.	0.058	0.103	0.008	0.005	4.97	0.066	0.047	0.017	0.001	0.003	Ti—0.006; Al—0.26; Sn—0.007
135	22.	0.094	0.458	0.017	0.010	0.383	0.076	0.083	5.15	0.010	0.575	N—0.024
155	11.	0.905	1.24	0.015	0.010	0.322	0.082	0.10	0.485	0.014	0.040	W—0.515
72c	12.	0.329	0.539	0.015	0.019	0.286	⋯	⋯	0.967	⋯	0.216	⋯
106a	8.	0.355	0.546	0.016	0.018	0.254	0.156	0.277	1.15	0.002	0.203	⋯
111a	14.	0.203	0.743	0.017	0.017	0.270	0.079	1.75	0.242	0.002	0.002	N—0.009

No.	% Transmission of 3173A Fe	Averaged analyses reported in supplement to NBS circular C 398
No.	% Transmission of 3173A Fe	% C	% Mn	% P	% S	% Si	% Cu	% Ni	% Cr	% V	% Mo	% Ti	% As
4g	14.	2.47	0.843	0.122	0.071	1.33	0.24	0.065	0.118	0.011	0.017	0.024	0.012
5g	16.	2.86	0.610	0.261	0.122	1.84	1.44	0.128	0.018	0.021	0.001	0.066	0.32
5h	18.	2.91	0.603	0.263	0.120	1.85	1.45	0.124	0.020	0.019	⋯	⋯	⋯
5i	17.	2.52	0.696	0.241	0.101	2.44	1.00	0.016	0.020	0.015	0.005	0.044	0.025
7C	24.	2.33	0.564	0.778	0.064	1.79	0.039	0.010	0.019	0.042	0.002	0.067	0.071
7d	19.	2.41	0.563	0.77	0.066	1.81	0.042	0.010	0.020	0.038	0.003	0.07	⋯
122	14.	3.06	0.511	0.31	0.034	0.585	0.043	0.023	0.032	0.016	0.002.	0.009	0.019
107	15.	2.57	0.706	0.197	0.090	2.34	0.074	0.807	0.455	0.015	0.687	0.037	0.01
82	9.5	2.78	0.722	0.102	0.033	2.09	0.020	1.00	0.245	0.011	0.004	0.048	0.009
6e	14.	2.61	1.36	0.431	0.079	2.33	0.254	0.062	0.074	0.024	0.016	0.025	⋯

No.	% Transmission of 3173A Fe	Averaged analyses reported in supplement to NBS circular C 398
No.	% Transmission of 3173A Fe	% C	% Mn	% P	% S	% Si	% Cu	% Ni	% Cr	% V	% Mo	% Other elements
11e	22.	0.18	0.451	0.015	0.028	0.316	0.105	0.045	0.036	0.002	0.007	N—0.004
12d	22.	0.418	0.344	0.013	0.036	0.016	0.015	0.007	0.015	0.002	0.016	⋯
12e	24.	0.371	.0.706	0.014	0.026	0.278	0.142	0.058	0.050	0.002	0.016	⋯
13d	14.	0.576	0.924	0.016	0.025	0.265	0.022	0.010	0.023	0.002	0.002	⋯
14c	9.	0.791	0.462	0.012	0.030	0.058	0.025	0.010	0.025	0.003	0.002	Al—0.025
15d	27.	0.100	0.393	0.018	0.033	0.079	0.054	0.024	0.060	0.001	0.007	⋯
19c	25.	0.214	0.630	0.049	0.040	0.201	0.161	0.179	0.063	⋯	⋯	⋯
152	13.	0.466	0.782	0.020	0.027	0.244	0.127	0.062	0.050	0.002	0.002	N—0.004; Sn—0.036
16c	5.	1.01	0.385	0.032	0.044	0.168	0.060	0.023	0.045	0.003	0.001	As—0.007
19d	27.	0.205	0.450	0.034	0.041	0.173	0.158	0.163	0.039	0.005	0.017	N—0.004
21c	7.5	0.574	0.630	0.062	0.030	0.107	0.050	0.152	0.166	0.007	0.005	As—0.008
34a	10.	0.762	0.501	0.028	0.026	0.276	0.222	0.232	0.275	0.007	0.003	As—0.009
35a	10.5	1.03	0.345	0.037	0.037	0.387	0.267	0.254	0.264	0.011	0.004	As—0.009; Al—0.002
20d	10.	0.411	0.916	0.048	0.098	0.254	0.164	0.227	0.283	0.049	0.062	⋯
55a	33.	0.014	0.022	0.004	0.020	0.001	0.046	0.019	0.006	0.0005	0.004	N—0.004; Al—0.002
55b	30.	0.012	0.015	0.003	0.019	0.001	0.042	0.016	0.002	0.001	0.004	Sn—0.005; Al—0.002
8g	21.	0.069	0.427	0.093	0.026	0.013	0.019	0.011	0.009	0.002	0.003	N—0.021; Sn—0.002
9c	16.	0.202	0.068	0.096	0.036	0.047	0.020	0.003	0.007	0.006	0.003	As—0.009; Sn—0.002
9d	21.	0.204	0.620	0.096	0.036	0.032	0.009	0.004	0.004	0.005	0.002	N—0.017
10e	21.	0.406	0.634	0.083	0.047	0.067	0.032	0.020	0.023	0.004	0.010	As—0.004; N—0.010
22c	16.	0.482	0.746	0.083	0.080	0.098	0.011	0.004	0.007	0.006	0.001	Al—0.116; N—0.010
22b	8.	0.674	0.935	0.084	0.041	0.123	0.009	0.003	0.003	0.005	0.002	As—0.004; Sn—0.0004
65b	16.	0.294	0.725	0.031	0.012	0.341	0.205	0.052	0.042	0.004	0.006	⋯
65c	16.	0.339	0.878	0.023	0.031	0.440	0.050	0.040	0.025	0.002	0.007	Sn—0.008
51a	4.7	1.27	0.233	0.010	0.010	0.308	0.082	0.063	0.056	0.002	0.002	Sn—0.011
129	20.	0.131	0.855	0.109	0.260	0.014	0.166	0.061	0.049	0.004	0.007	As—0.007
130	16.	0.454	0.688	0.025	0.021	0.237	0.017	0.009	0.029	⋯	0.003	Pb—0.204

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Journal of the Optical Society of America