Abstract

The Raman spectrum of gaseous 1,3-butadiene has been photographed with a three-prism glass spectrograph of linear dispersion 15 A/mm near 4358A. Polarization data have been obtained for the liquid. The observed Raman spectrum has been interpreted in some detail in terms of a planar <i>trans</i>-configuration of the molecule. Two fundamentals have been added to previous assignments, and several assignments have been made more specific. It is concluded that at room temperature a small fraction of the molecules have a <i>cis</i>-configuration.

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  1. J. G. Aston, G. Szasz, H. W. Woolley, and F. G. Brickwedde, J. Chem. Phys. 14, 67 (1946).
  2. D. C. Smith, J. Rud Nielsen and H. H. Claassen, J. Chem. Phys. 18, 326 (1950).
  3. K. W. F. Kohlrausch, Der Smekal-Ranan Effekt (Julius Springer, Berlin, 1931).
  4. K. Bradacs and L. Kahovec, Zeits. f. physik. Chemie 48, 63 (1940).
  5. A. Dadieu and K. W. F. Kohlrausch, Ber. d. d. chem. Ges. 63, 1657 (1930).
  6. E. Bartholomé and J. Karweil, Zeits. f. physik. Chemie 35, 442 (1937).
  7. R. S. Rasmussen and R. R. Brattain, J. Chem. Phys. 15, 131 (1947).
  8. E. C. Creitz and F. A. Smith, J. Research Nat. Bur. Stand. 43, 365 (1949).
  9. N. Sheppard, J. Chem. Phys. 17, 74 (1949).
  10. K. W. F. Kohlrausch, Ramnaspektren (Akademische Verlag Becker and Erler, Leipzig, 1943).
  11. C. M. Richards and J. Rud Nielsen, J. Opt. Soc. Am. 40, 442 (1950).

Aston, J. G.

J. G. Aston, G. Szasz, H. W. Woolley, and F. G. Brickwedde, J. Chem. Phys. 14, 67 (1946).

Bartholomé, E.

E. Bartholomé and J. Karweil, Zeits. f. physik. Chemie 35, 442 (1937).

Bradacs, K.

K. Bradacs and L. Kahovec, Zeits. f. physik. Chemie 48, 63 (1940).

Brattain, R. R.

R. S. Rasmussen and R. R. Brattain, J. Chem. Phys. 15, 131 (1947).

Brickwedde, F. G.

J. G. Aston, G. Szasz, H. W. Woolley, and F. G. Brickwedde, J. Chem. Phys. 14, 67 (1946).

Claassen, H. H.

D. C. Smith, J. Rud Nielsen and H. H. Claassen, J. Chem. Phys. 18, 326 (1950).

Creitz, E. C.

E. C. Creitz and F. A. Smith, J. Research Nat. Bur. Stand. 43, 365 (1949).

Dadieu, A.

A. Dadieu and K. W. F. Kohlrausch, Ber. d. d. chem. Ges. 63, 1657 (1930).

Kahovec, L.

K. Bradacs and L. Kahovec, Zeits. f. physik. Chemie 48, 63 (1940).

Karweil, J.

E. Bartholomé and J. Karweil, Zeits. f. physik. Chemie 35, 442 (1937).

Kohlrausch, K. W. F.

A. Dadieu and K. W. F. Kohlrausch, Ber. d. d. chem. Ges. 63, 1657 (1930).

K. W. F. Kohlrausch, Der Smekal-Ranan Effekt (Julius Springer, Berlin, 1931).

K. W. F. Kohlrausch, Ramnaspektren (Akademische Verlag Becker and Erler, Leipzig, 1943).

Nielsen, J. Rud

C. M. Richards and J. Rud Nielsen, J. Opt. Soc. Am. 40, 442 (1950).

D. C. Smith, J. Rud Nielsen and H. H. Claassen, J. Chem. Phys. 18, 326 (1950).

Rasmussen, R. S.

R. S. Rasmussen and R. R. Brattain, J. Chem. Phys. 15, 131 (1947).

Richards, C. M.

C. M. Richards and J. Rud Nielsen, J. Opt. Soc. Am. 40, 442 (1950).

Sheppard, N.

N. Sheppard, J. Chem. Phys. 17, 74 (1949).

Smith, D. C.

D. C. Smith, J. Rud Nielsen and H. H. Claassen, J. Chem. Phys. 18, 326 (1950).

Smith, F. A.

E. C. Creitz and F. A. Smith, J. Research Nat. Bur. Stand. 43, 365 (1949).

Szasz, G.

J. G. Aston, G. Szasz, H. W. Woolley, and F. G. Brickwedde, J. Chem. Phys. 14, 67 (1946).

Woolley, H. W.

J. G. Aston, G. Szasz, H. W. Woolley, and F. G. Brickwedde, J. Chem. Phys. 14, 67 (1946).

Other

J. G. Aston, G. Szasz, H. W. Woolley, and F. G. Brickwedde, J. Chem. Phys. 14, 67 (1946).

D. C. Smith, J. Rud Nielsen and H. H. Claassen, J. Chem. Phys. 18, 326 (1950).

K. W. F. Kohlrausch, Der Smekal-Ranan Effekt (Julius Springer, Berlin, 1931).

K. Bradacs and L. Kahovec, Zeits. f. physik. Chemie 48, 63 (1940).

A. Dadieu and K. W. F. Kohlrausch, Ber. d. d. chem. Ges. 63, 1657 (1930).

E. Bartholomé and J. Karweil, Zeits. f. physik. Chemie 35, 442 (1937).

R. S. Rasmussen and R. R. Brattain, J. Chem. Phys. 15, 131 (1947).

E. C. Creitz and F. A. Smith, J. Research Nat. Bur. Stand. 43, 365 (1949).

N. Sheppard, J. Chem. Phys. 17, 74 (1949).

K. W. F. Kohlrausch, Ramnaspektren (Akademische Verlag Becker and Erler, Leipzig, 1943).

C. M. Richards and J. Rud Nielsen, J. Opt. Soc. Am. 40, 442 (1950).

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