Abstract

Infrared spectra in the wavelength region 2–25µ of the series of compounds, tetramethyltin, trimethylethyltin, dimethyldiethyltin, methyltriethyltin, and tetraethyltin, have been obtained as well as Raman data for tetramethyltin and tetraethyltin. The observed spectra are interpreted on the basis of simple point group symmetry assuming that the alkyl radicals behave as “point masses.”

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  1. C. W. Young, J. S. Koehler, and D. S. McKinney, J. Am. Chem. Soc. 69, 1410 (1947).
  2. T. Schimanouchi, I. Tsuchiya, and Y. Mikawa, J. Chem. Phys. 20, 1306 (1950).
  3. H. Murata, R. Okawara, and T. Watase, J. Chem. Phys. 20, 1308 (1950).
  4. E. R. Lippincott and M. C. Tobin, J. Am. Chem. Soc. 75, 4141 (1953).
  5. W. F. Edgell and C. H. Ward, J. Am. Chem. Soc. 77, 6486 (1955).
  6. C. R. Dillard, E. H. McNeill, D. E. Simmons, and J. B. Yeldell, J. Am. Chem. Soc. 80, 3607 (1958).
  7. E. Krause and A. V. Grosse, Die Chemie der Metall-Organischen Verbindungen, (Edwards Brothers, Inc., Ann Arbor, Michigan, 1943), pp. 314 ff.
  8. A. B. F. Ducan and J. W. Murray, J. Chem. Phys. 2, 636 (1943).
  9. G. Herzberg, Infrared and Raman Spectra of Polyatomic Molecules, (D. Van Nostrand Company, Inc., Princeton, New Jersey, 1945), p. 121.

Dillard, C. R.

C. R. Dillard, E. H. McNeill, D. E. Simmons, and J. B. Yeldell, J. Am. Chem. Soc. 80, 3607 (1958).

Ducan, A. B. F.

A. B. F. Ducan and J. W. Murray, J. Chem. Phys. 2, 636 (1943).

Edgell, W. F.

W. F. Edgell and C. H. Ward, J. Am. Chem. Soc. 77, 6486 (1955).

Grosse, A. V.

E. Krause and A. V. Grosse, Die Chemie der Metall-Organischen Verbindungen, (Edwards Brothers, Inc., Ann Arbor, Michigan, 1943), pp. 314 ff.

Herzberg, G.

G. Herzberg, Infrared and Raman Spectra of Polyatomic Molecules, (D. Van Nostrand Company, Inc., Princeton, New Jersey, 1945), p. 121.

Koehler, J. S.

C. W. Young, J. S. Koehler, and D. S. McKinney, J. Am. Chem. Soc. 69, 1410 (1947).

Krause, E.

E. Krause and A. V. Grosse, Die Chemie der Metall-Organischen Verbindungen, (Edwards Brothers, Inc., Ann Arbor, Michigan, 1943), pp. 314 ff.

Lippincott, E. R.

E. R. Lippincott and M. C. Tobin, J. Am. Chem. Soc. 75, 4141 (1953).

McKinney, D. S.

C. W. Young, J. S. Koehler, and D. S. McKinney, J. Am. Chem. Soc. 69, 1410 (1947).

McNeill, E. H.

C. R. Dillard, E. H. McNeill, D. E. Simmons, and J. B. Yeldell, J. Am. Chem. Soc. 80, 3607 (1958).

Mikawa, Y.

T. Schimanouchi, I. Tsuchiya, and Y. Mikawa, J. Chem. Phys. 20, 1306 (1950).

Murata, H.

H. Murata, R. Okawara, and T. Watase, J. Chem. Phys. 20, 1308 (1950).

Murray, J. W.

A. B. F. Ducan and J. W. Murray, J. Chem. Phys. 2, 636 (1943).

Okawara, R.

H. Murata, R. Okawara, and T. Watase, J. Chem. Phys. 20, 1308 (1950).

Schimanouchi, T.

T. Schimanouchi, I. Tsuchiya, and Y. Mikawa, J. Chem. Phys. 20, 1306 (1950).

Simmons, D. E.

C. R. Dillard, E. H. McNeill, D. E. Simmons, and J. B. Yeldell, J. Am. Chem. Soc. 80, 3607 (1958).

Tobin, M. C.

E. R. Lippincott and M. C. Tobin, J. Am. Chem. Soc. 75, 4141 (1953).

Tsuchiya, I.

T. Schimanouchi, I. Tsuchiya, and Y. Mikawa, J. Chem. Phys. 20, 1306 (1950).

Ward, C. H.

W. F. Edgell and C. H. Ward, J. Am. Chem. Soc. 77, 6486 (1955).

Watase, T.

H. Murata, R. Okawara, and T. Watase, J. Chem. Phys. 20, 1308 (1950).

Yeldell, J. B.

C. R. Dillard, E. H. McNeill, D. E. Simmons, and J. B. Yeldell, J. Am. Chem. Soc. 80, 3607 (1958).

Young, C. W.

C. W. Young, J. S. Koehler, and D. S. McKinney, J. Am. Chem. Soc. 69, 1410 (1947).

Other (9)

C. W. Young, J. S. Koehler, and D. S. McKinney, J. Am. Chem. Soc. 69, 1410 (1947).

T. Schimanouchi, I. Tsuchiya, and Y. Mikawa, J. Chem. Phys. 20, 1306 (1950).

H. Murata, R. Okawara, and T. Watase, J. Chem. Phys. 20, 1308 (1950).

E. R. Lippincott and M. C. Tobin, J. Am. Chem. Soc. 75, 4141 (1953).

W. F. Edgell and C. H. Ward, J. Am. Chem. Soc. 77, 6486 (1955).

C. R. Dillard, E. H. McNeill, D. E. Simmons, and J. B. Yeldell, J. Am. Chem. Soc. 80, 3607 (1958).

E. Krause and A. V. Grosse, Die Chemie der Metall-Organischen Verbindungen, (Edwards Brothers, Inc., Ann Arbor, Michigan, 1943), pp. 314 ff.

A. B. F. Ducan and J. W. Murray, J. Chem. Phys. 2, 636 (1943).

G. Herzberg, Infrared and Raman Spectra of Polyatomic Molecules, (D. Van Nostrand Company, Inc., Princeton, New Jersey, 1945), p. 121.

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