Abstract

The Rb(5DJ)+H2 RbH+H photochemical reaction has been studied. Rb vapor mixed with H2 is irradiated in a glass cell with 778-nm pulses which populate one of the 5 2D states by two-photon absorption. Measurements for the relative intensities of the atomic fluorescence and the absorption of the RbH product near the axis of the cell yield the rate coefficients for the Rb(5D_{3/2})+H2 and Rb(5D_{5/2})+H2 reactions, which are (3.6\pm1.3)\times10^{-11} and (1.7\pm0.6)\times10^{-11} cm3/s, respectively. The relative reactivity with H2 for Rb(5D_{3/2}) is higher than that for Rb(5D_{5/2}).

© 2009 Chinese Optics Letters

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2008 (2)

J. Chen, Z. Bai, Y. Zhao, K. Dai, and Y. Shen, Chinese J. Lasers (in Chinese) 35, 907 (2008).

Q. Wang, Y. Shen, and K. Dai, Opt. Commun. 281, 2112 (2008).

2007 (1)

2004 (1)

B. C. Hattaway, S. Bililign, L. Uhl, V. Ledentu, and G. -H. Jeung, J. Chem. Phys. 120, 1739 (2004).

2002 (1)

K.-C. Lin and R. Vetter, Int. Rev. Phys. Chem. 21, 357 (2002).

2001 (1)

J.-J. Chen, Y.-M. Hung, D.-K. Liu, H.-S. Fung, and K. -C. Lin, J. Chem. Phys. 114, 9395 (2001).

1999 (1)

L.-H. Fan, J.-J. Chen, Y.-Y. Lin, and W.-T. Luh, J. Phys. Chem. A 103, 1300 (1999).

1997 (1)

M.-L. Chen, W.-C. Lin, and W.-T. Luh, J. Chem. Phys. 106, 5972 (1997).

1996 (1)

D.-K. Liu and K.-C. Lin, J. Chem. Phys. 105, 9121 (1996).

1993 (1)

P. D. Kleiber, T. H. Wong, and S. Bililign, J. Chem. Phys. 98, 1101 (1993).

1992 (2)

S. Bililign, P. D. Kleiber, W. R. Kearney, and K. M. Sando, J. Chem. Phys. 96, 218 (1992).

Y.-L. Lou, K.-C. Lin, D.-K. Liu, H.-J. Liu, and W.-T. Luh, Phys. Rev. A 46, 3834 (1992).

1991 (2)

J.-M. L'Hermite, G. Rahmat, and R. Vetter, J. Chem. Phys. 95, 3347 (1991).

W. C. Stwalley, W. T. Zemke, and S. C. Yang, J. Phys. Chem. Ref. Data 20, 153 (1991).

1984 (1)

D. von der Goltz, W. Hansen, and J. Richter, Physica Scripta 30, 244 (1984).

1983 (1)

J. P. Visticot, M. Ferray, J. Lozingot, and B. Sayer, J. Chem. Phys. 79, 2839 (1983).

1974 (1)

P. W. Pace and J. B. Atkinson, Can. J. Phys. 52, 1635 (1974).

1973 (1)

Atkinson, J. B.

P. W. Pace and J. B. Atkinson, Can. J. Phys. 52, 1635 (1974).

Bai, Z.

J. Chen, Z. Bai, Y. Zhao, K. Dai, and Y. Shen, Chinese J. Lasers (in Chinese) 35, 907 (2008).

Bililign, S.

B. C. Hattaway, S. Bililign, L. Uhl, V. Ledentu, and G. -H. Jeung, J. Chem. Phys. 120, 1739 (2004).

P. D. Kleiber, T. H. Wong, and S. Bililign, J. Chem. Phys. 98, 1101 (1993).

S. Bililign, P. D. Kleiber, W. R. Kearney, and K. M. Sando, J. Chem. Phys. 96, 218 (1992).

Chen, J.

J. Chen, Z. Bai, Y. Zhao, K. Dai, and Y. Shen, Chinese J. Lasers (in Chinese) 35, 907 (2008).

Chen, J.-J.

J.-J. Chen, Y.-M. Hung, D.-K. Liu, H.-S. Fung, and K. -C. Lin, J. Chem. Phys. 114, 9395 (2001).

L.-H. Fan, J.-J. Chen, Y.-Y. Lin, and W.-T. Luh, J. Phys. Chem. A 103, 1300 (1999).

Chen, M.-L.

M.-L. Chen, W.-C. Lin, and W.-T. Luh, J. Chem. Phys. 106, 5972 (1997).

Dai, K.

Q. Wang, Y. Shen, and K. Dai, Opt. Commun. 281, 2112 (2008).

J. Chen, Z. Bai, Y. Zhao, K. Dai, and Y. Shen, Chinese J. Lasers (in Chinese) 35, 907 (2008).

Q. Wang, K. Dai, and Y. Shen, Chin. Opt. Lett. 5, 376 (2007).

Fan, L.-H.

L.-H. Fan, J.-J. Chen, Y.-Y. Lin, and W.-T. Luh, J. Phys. Chem. A 103, 1300 (1999).

Ferray, M.

J. P. Visticot, M. Ferray, J. Lozingot, and B. Sayer, J. Chem. Phys. 79, 2839 (1983).

Fung, H.-S.

J.-J. Chen, Y.-M. Hung, D.-K. Liu, H.-S. Fung, and K. -C. Lin, J. Chem. Phys. 114, 9395 (2001).

Gallagher, A.

Goltz, D. von der

D. von der Goltz, W. Hansen, and J. Richter, Physica Scripta 30, 244 (1984).

Hansen, W.

D. von der Goltz, W. Hansen, and J. Richter, Physica Scripta 30, 244 (1984).

Hattaway, B. C.

B. C. Hattaway, S. Bililign, L. Uhl, V. Ledentu, and G. -H. Jeung, J. Chem. Phys. 120, 1739 (2004).

Hung, Y.-M.

J.-J. Chen, Y.-M. Hung, D.-K. Liu, H.-S. Fung, and K. -C. Lin, J. Chem. Phys. 114, 9395 (2001).

Jeung, G. -H.

B. C. Hattaway, S. Bililign, L. Uhl, V. Ledentu, and G. -H. Jeung, J. Chem. Phys. 120, 1739 (2004).

Kearney, W. R.

S. Bililign, P. D. Kleiber, W. R. Kearney, and K. M. Sando, J. Chem. Phys. 96, 218 (1992).

Kleiber, P. D.

P. D. Kleiber, T. H. Wong, and S. Bililign, J. Chem. Phys. 98, 1101 (1993).

S. Bililign, P. D. Kleiber, W. R. Kearney, and K. M. Sando, J. Chem. Phys. 96, 218 (1992).

Ledentu, V.

B. C. Hattaway, S. Bililign, L. Uhl, V. Ledentu, and G. -H. Jeung, J. Chem. Phys. 120, 1739 (2004).

Lewis, E. L.

L'Hermite, J.-M.

J.-M. L'Hermite, G. Rahmat, and R. Vetter, J. Chem. Phys. 95, 3347 (1991).

Lin, K. -C.

J.-J. Chen, Y.-M. Hung, D.-K. Liu, H.-S. Fung, and K. -C. Lin, J. Chem. Phys. 114, 9395 (2001).

Lin, K.-C.

K.-C. Lin and R. Vetter, Int. Rev. Phys. Chem. 21, 357 (2002).

D.-K. Liu and K.-C. Lin, J. Chem. Phys. 105, 9121 (1996).

Y.-L. Lou, K.-C. Lin, D.-K. Liu, H.-J. Liu, and W.-T. Luh, Phys. Rev. A 46, 3834 (1992).

Lin, W.-C.

M.-L. Chen, W.-C. Lin, and W.-T. Luh, J. Chem. Phys. 106, 5972 (1997).

Lin, Y.-Y.

L.-H. Fan, J.-J. Chen, Y.-Y. Lin, and W.-T. Luh, J. Phys. Chem. A 103, 1300 (1999).

Liu, D.-K.

J.-J. Chen, Y.-M. Hung, D.-K. Liu, H.-S. Fung, and K. -C. Lin, J. Chem. Phys. 114, 9395 (2001).

D.-K. Liu and K.-C. Lin, J. Chem. Phys. 105, 9121 (1996).

Y.-L. Lou, K.-C. Lin, D.-K. Liu, H.-J. Liu, and W.-T. Luh, Phys. Rev. A 46, 3834 (1992).

Liu, H.-J.

Y.-L. Lou, K.-C. Lin, D.-K. Liu, H.-J. Liu, and W.-T. Luh, Phys. Rev. A 46, 3834 (1992).

Lou, Y.-L.

Y.-L. Lou, K.-C. Lin, D.-K. Liu, H.-J. Liu, and W.-T. Luh, Phys. Rev. A 46, 3834 (1992).

Lozingot, J.

J. P. Visticot, M. Ferray, J. Lozingot, and B. Sayer, J. Chem. Phys. 79, 2839 (1983).

Luh, W.-T.

L.-H. Fan, J.-J. Chen, Y.-Y. Lin, and W.-T. Luh, J. Phys. Chem. A 103, 1300 (1999).

M.-L. Chen, W.-C. Lin, and W.-T. Luh, J. Chem. Phys. 106, 5972 (1997).

Y.-L. Lou, K.-C. Lin, D.-K. Liu, H.-J. Liu, and W.-T. Luh, Phys. Rev. A 46, 3834 (1992).

Pace, P. W.

P. W. Pace and J. B. Atkinson, Can. J. Phys. 52, 1635 (1974).

Rahmat, G.

J.-M. L'Hermite, G. Rahmat, and R. Vetter, J. Chem. Phys. 95, 3347 (1991).

Richter, J.

D. von der Goltz, W. Hansen, and J. Richter, Physica Scripta 30, 244 (1984).

Sando, K. M.

S. Bililign, P. D. Kleiber, W. R. Kearney, and K. M. Sando, J. Chem. Phys. 96, 218 (1992).

Sayer, B.

J. P. Visticot, M. Ferray, J. Lozingot, and B. Sayer, J. Chem. Phys. 79, 2839 (1983).

Shen, Y.

Q. Wang, Y. Shen, and K. Dai, Opt. Commun. 281, 2112 (2008).

J. Chen, Z. Bai, Y. Zhao, K. Dai, and Y. Shen, Chinese J. Lasers (in Chinese) 35, 907 (2008).

Q. Wang, K. Dai, and Y. Shen, Chin. Opt. Lett. 5, 376 (2007).

Stwalley, W. C.

W. C. Stwalley, W. T. Zemke, and S. C. Yang, J. Phys. Chem. Ref. Data 20, 153 (1991).

Uhl, L.

B. C. Hattaway, S. Bililign, L. Uhl, V. Ledentu, and G. -H. Jeung, J. Chem. Phys. 120, 1739 (2004).

Vetter, R.

K.-C. Lin and R. Vetter, Int. Rev. Phys. Chem. 21, 357 (2002).

J.-M. L'Hermite, G. Rahmat, and R. Vetter, J. Chem. Phys. 95, 3347 (1991).

Visticot, J. P.

J. P. Visticot, M. Ferray, J. Lozingot, and B. Sayer, J. Chem. Phys. 79, 2839 (1983).

Wang, Q.

Q. Wang, Y. Shen, and K. Dai, Opt. Commun. 281, 2112 (2008).

Q. Wang, K. Dai, and Y. Shen, Chin. Opt. Lett. 5, 376 (2007).

Wong, T. H.

P. D. Kleiber, T. H. Wong, and S. Bililign, J. Chem. Phys. 98, 1101 (1993).

Yang, S. C.

W. C. Stwalley, W. T. Zemke, and S. C. Yang, J. Phys. Chem. Ref. Data 20, 153 (1991).

Zemke, W. T.

W. C. Stwalley, W. T. Zemke, and S. C. Yang, J. Phys. Chem. Ref. Data 20, 153 (1991).

Zhao, Y.

J. Chen, Z. Bai, Y. Zhao, K. Dai, and Y. Shen, Chinese J. Lasers (in Chinese) 35, 907 (2008).

Can. J. Phys. (1)

P. W. Pace and J. B. Atkinson, Can. J. Phys. 52, 1635 (1974).

Chin. Opt. Lett. (1)

Chinese J. Lasers (in Chinese) (1)

J. Chen, Z. Bai, Y. Zhao, K. Dai, and Y. Shen, Chinese J. Lasers (in Chinese) 35, 907 (2008).

Int. Rev. Phys. Chem. (1)

K.-C. Lin and R. Vetter, Int. Rev. Phys. Chem. 21, 357 (2002).

J. Chem. Phys. (8)

M.-L. Chen, W.-C. Lin, and W.-T. Luh, J. Chem. Phys. 106, 5972 (1997).

B. C. Hattaway, S. Bililign, L. Uhl, V. Ledentu, and G. -H. Jeung, J. Chem. Phys. 120, 1739 (2004).

P. D. Kleiber, T. H. Wong, and S. Bililign, J. Chem. Phys. 98, 1101 (1993).

D.-K. Liu and K.-C. Lin, J. Chem. Phys. 105, 9121 (1996).

S. Bililign, P. D. Kleiber, W. R. Kearney, and K. M. Sando, J. Chem. Phys. 96, 218 (1992).

J.-J. Chen, Y.-M. Hung, D.-K. Liu, H.-S. Fung, and K. -C. Lin, J. Chem. Phys. 114, 9395 (2001).

J.-M. L'Hermite, G. Rahmat, and R. Vetter, J. Chem. Phys. 95, 3347 (1991).

J. P. Visticot, M. Ferray, J. Lozingot, and B. Sayer, J. Chem. Phys. 79, 2839 (1983).

J. Opt. Soc. Am. (1)

J. Phys. Chem. A (1)

L.-H. Fan, J.-J. Chen, Y.-Y. Lin, and W.-T. Luh, J. Phys. Chem. A 103, 1300 (1999).

J. Phys. Chem. Ref. Data (1)

W. C. Stwalley, W. T. Zemke, and S. C. Yang, J. Phys. Chem. Ref. Data 20, 153 (1991).

Opt. Commun. (1)

Q. Wang, Y. Shen, and K. Dai, Opt. Commun. 281, 2112 (2008).

Phys. Rev. A (1)

Y.-L. Lou, K.-C. Lin, D.-K. Liu, H.-J. Liu, and W.-T. Luh, Phys. Rev. A 46, 3834 (1992).

Physica Scripta (1)

D. von der Goltz, W. Hansen, and J. Richter, Physica Scripta 30, 244 (1984).

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