Abstract

The ultraviolet (UV) light excited fluorescence spectra of ethanol-water mixture with different concentrations are investigated by derivative fluorimetry. It is found that there are 8 types of luminescent cluster molecules, formed by ethanol and water molecules in different ways, existing in the solution. The peak wavelengths of all these clusters' fluorescence spectra are measured and their contents are obtained by measuring the peak values in the second derivative fluorescence spectra. The spectra corresponding to the 8 types of clusters are obtained by Gaussian decomposition. It is found that two kinds of cluster molecules whose peak wavelengths are 330 and 345 nm have an optimal excitation wavelength located at (236+-3) nm. This research contributes to the study of ethanol-water cluster structures and their physical and chemical characteristics.

© 2009 Chinese Optics Letters

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  1. S. C. Upadhya, P. S. Tirumalai, M. R. Boyd, T. Mori, and V. Ravindranath, Arch. Biochem. Biophys. 373, 23 (2000).
  2. F. Castaneda and R. K. H. Kinne, J. Cancer Res. Clin. Oncol. 126, 305 (2000).
  3. S. M. de la Monte and J. R. Wands, Cell. Mol. Life Sci. 59, 882 (2002).
  4. R. Laenen and C. Rauscher, J. Chem. Phys. 107, 9759 (1997).
  5. M. E. Martín, M. L. Sánchez, F. J. O. del Valle, and M. A. Aguilar, J. Chem. Phys. 116, 1613 (2002).
  6. J. D. Weibel, C. F. Jackels, and R. L. Swofford, J. Chem. Phys. 117, 4245 (2002).
  7. R. S. Taylor and R. L. Shields, J. Chem. Phys. 119, 12569 (2003).
  8. A. Matic, C. Masciovecchio, D. Engberg, G. Monaco, L. Borjesson, S. C. Santucci, and R. Verbeni, Phys. Rev. Lett. 93, 145502 (2004).
  9. K. M. Murdoch, T. D. Ferris, J. C. Wright, and T. C. Farrar, J. Chem. Phys. 116, 5717 (2002).
  10. M. Masella and J.-P. Flament, Mol. Phys. 95, 97 (1998).
  11. Y. Liu, C. Peng, X. Lan, X. Luo, Z. Shen, J. Lu, and X. Ni, Acta Phys. Sin. (in Chinese) 54, 5455 (2005).
  12. Y. Liu, C. Liu, X. Ni, X. Luo, J. Lu, and Z. Shen, Acta Opt. Sin. (in Chinese) 26, 1580 (2006).
  13. Y. Liu, H. Shao, X. Ni, and J. Lu, Chin. Opt. Lett. (in Chinese) 6, 154 (2008).
  14. J. Xu and Z. Wang, Fluorescence Analysis (in Chinese) (Science Press, Beijing, 2006) p.299, 300.
  15. S. Dai, P. Li, X. Yang, D. Wu, R. Li, J. Yang, and H. Xiao, Acta Phys. Sin. (in Chinese) 26, 141 (2006).

2008 (1)

Y. Liu, H. Shao, X. Ni, and J. Lu, Chin. Opt. Lett. (in Chinese) 6, 154 (2008).

2006 (2)

S. Dai, P. Li, X. Yang, D. Wu, R. Li, J. Yang, and H. Xiao, Acta Phys. Sin. (in Chinese) 26, 141 (2006).

Y. Liu, C. Liu, X. Ni, X. Luo, J. Lu, and Z. Shen, Acta Opt. Sin. (in Chinese) 26, 1580 (2006).

2005 (1)

Y. Liu, C. Peng, X. Lan, X. Luo, Z. Shen, J. Lu, and X. Ni, Acta Phys. Sin. (in Chinese) 54, 5455 (2005).

2004 (1)

A. Matic, C. Masciovecchio, D. Engberg, G. Monaco, L. Borjesson, S. C. Santucci, and R. Verbeni, Phys. Rev. Lett. 93, 145502 (2004).

2003 (1)

R. S. Taylor and R. L. Shields, J. Chem. Phys. 119, 12569 (2003).

2002 (4)

K. M. Murdoch, T. D. Ferris, J. C. Wright, and T. C. Farrar, J. Chem. Phys. 116, 5717 (2002).

M. E. Martín, M. L. Sánchez, F. J. O. del Valle, and M. A. Aguilar, J. Chem. Phys. 116, 1613 (2002).

J. D. Weibel, C. F. Jackels, and R. L. Swofford, J. Chem. Phys. 117, 4245 (2002).

S. M. de la Monte and J. R. Wands, Cell. Mol. Life Sci. 59, 882 (2002).

2000 (2)

S. C. Upadhya, P. S. Tirumalai, M. R. Boyd, T. Mori, and V. Ravindranath, Arch. Biochem. Biophys. 373, 23 (2000).

F. Castaneda and R. K. H. Kinne, J. Cancer Res. Clin. Oncol. 126, 305 (2000).

1998 (1)

M. Masella and J.-P. Flament, Mol. Phys. 95, 97 (1998).

1997 (1)

R. Laenen and C. Rauscher, J. Chem. Phys. 107, 9759 (1997).

Aguilar, M. A.

M. E. Martín, M. L. Sánchez, F. J. O. del Valle, and M. A. Aguilar, J. Chem. Phys. 116, 1613 (2002).

Borjesson, L.

A. Matic, C. Masciovecchio, D. Engberg, G. Monaco, L. Borjesson, S. C. Santucci, and R. Verbeni, Phys. Rev. Lett. 93, 145502 (2004).

Boyd, M. R.

S. C. Upadhya, P. S. Tirumalai, M. R. Boyd, T. Mori, and V. Ravindranath, Arch. Biochem. Biophys. 373, 23 (2000).

Castaneda, F.

F. Castaneda and R. K. H. Kinne, J. Cancer Res. Clin. Oncol. 126, 305 (2000).

Dai, S.

S. Dai, P. Li, X. Yang, D. Wu, R. Li, J. Yang, and H. Xiao, Acta Phys. Sin. (in Chinese) 26, 141 (2006).

Engberg, D.

A. Matic, C. Masciovecchio, D. Engberg, G. Monaco, L. Borjesson, S. C. Santucci, and R. Verbeni, Phys. Rev. Lett. 93, 145502 (2004).

Farrar, T. C.

K. M. Murdoch, T. D. Ferris, J. C. Wright, and T. C. Farrar, J. Chem. Phys. 116, 5717 (2002).

Ferris, T. D.

K. M. Murdoch, T. D. Ferris, J. C. Wright, and T. C. Farrar, J. Chem. Phys. 116, 5717 (2002).

Flament, J.-P.

M. Masella and J.-P. Flament, Mol. Phys. 95, 97 (1998).

Jackels, C. F.

J. D. Weibel, C. F. Jackels, and R. L. Swofford, J. Chem. Phys. 117, 4245 (2002).

Kinne, R. K. H.

F. Castaneda and R. K. H. Kinne, J. Cancer Res. Clin. Oncol. 126, 305 (2000).

Laenen, R.

R. Laenen and C. Rauscher, J. Chem. Phys. 107, 9759 (1997).

Lan, X.

Y. Liu, C. Peng, X. Lan, X. Luo, Z. Shen, J. Lu, and X. Ni, Acta Phys. Sin. (in Chinese) 54, 5455 (2005).

Li, P.

S. Dai, P. Li, X. Yang, D. Wu, R. Li, J. Yang, and H. Xiao, Acta Phys. Sin. (in Chinese) 26, 141 (2006).

Li, R.

S. Dai, P. Li, X. Yang, D. Wu, R. Li, J. Yang, and H. Xiao, Acta Phys. Sin. (in Chinese) 26, 141 (2006).

Liu, C.

Y. Liu, C. Liu, X. Ni, X. Luo, J. Lu, and Z. Shen, Acta Opt. Sin. (in Chinese) 26, 1580 (2006).

Liu, Y.

Y. Liu, H. Shao, X. Ni, and J. Lu, Chin. Opt. Lett. (in Chinese) 6, 154 (2008).

Y. Liu, C. Liu, X. Ni, X. Luo, J. Lu, and Z. Shen, Acta Opt. Sin. (in Chinese) 26, 1580 (2006).

Y. Liu, C. Peng, X. Lan, X. Luo, Z. Shen, J. Lu, and X. Ni, Acta Phys. Sin. (in Chinese) 54, 5455 (2005).

Lu, J.

Y. Liu, H. Shao, X. Ni, and J. Lu, Chin. Opt. Lett. (in Chinese) 6, 154 (2008).

Y. Liu, C. Liu, X. Ni, X. Luo, J. Lu, and Z. Shen, Acta Opt. Sin. (in Chinese) 26, 1580 (2006).

Y. Liu, C. Peng, X. Lan, X. Luo, Z. Shen, J. Lu, and X. Ni, Acta Phys. Sin. (in Chinese) 54, 5455 (2005).

Luo, X.

Y. Liu, C. Liu, X. Ni, X. Luo, J. Lu, and Z. Shen, Acta Opt. Sin. (in Chinese) 26, 1580 (2006).

Y. Liu, C. Peng, X. Lan, X. Luo, Z. Shen, J. Lu, and X. Ni, Acta Phys. Sin. (in Chinese) 54, 5455 (2005).

Martín, M. E.

M. E. Martín, M. L. Sánchez, F. J. O. del Valle, and M. A. Aguilar, J. Chem. Phys. 116, 1613 (2002).

Masciovecchio, C.

A. Matic, C. Masciovecchio, D. Engberg, G. Monaco, L. Borjesson, S. C. Santucci, and R. Verbeni, Phys. Rev. Lett. 93, 145502 (2004).

Masella, M.

M. Masella and J.-P. Flament, Mol. Phys. 95, 97 (1998).

Matic, A.

A. Matic, C. Masciovecchio, D. Engberg, G. Monaco, L. Borjesson, S. C. Santucci, and R. Verbeni, Phys. Rev. Lett. 93, 145502 (2004).

Monaco, G.

A. Matic, C. Masciovecchio, D. Engberg, G. Monaco, L. Borjesson, S. C. Santucci, and R. Verbeni, Phys. Rev. Lett. 93, 145502 (2004).

Monte, S. M. de la

S. M. de la Monte and J. R. Wands, Cell. Mol. Life Sci. 59, 882 (2002).

Mori, T.

S. C. Upadhya, P. S. Tirumalai, M. R. Boyd, T. Mori, and V. Ravindranath, Arch. Biochem. Biophys. 373, 23 (2000).

Murdoch, K. M.

K. M. Murdoch, T. D. Ferris, J. C. Wright, and T. C. Farrar, J. Chem. Phys. 116, 5717 (2002).

Ni, X.

Y. Liu, H. Shao, X. Ni, and J. Lu, Chin. Opt. Lett. (in Chinese) 6, 154 (2008).

Y. Liu, C. Liu, X. Ni, X. Luo, J. Lu, and Z. Shen, Acta Opt. Sin. (in Chinese) 26, 1580 (2006).

Y. Liu, C. Peng, X. Lan, X. Luo, Z. Shen, J. Lu, and X. Ni, Acta Phys. Sin. (in Chinese) 54, 5455 (2005).

Peng, C.

Y. Liu, C. Peng, X. Lan, X. Luo, Z. Shen, J. Lu, and X. Ni, Acta Phys. Sin. (in Chinese) 54, 5455 (2005).

Rauscher, C.

R. Laenen and C. Rauscher, J. Chem. Phys. 107, 9759 (1997).

Ravindranath, V.

S. C. Upadhya, P. S. Tirumalai, M. R. Boyd, T. Mori, and V. Ravindranath, Arch. Biochem. Biophys. 373, 23 (2000).

Sánchez, M. L.

M. E. Martín, M. L. Sánchez, F. J. O. del Valle, and M. A. Aguilar, J. Chem. Phys. 116, 1613 (2002).

Santucci, S. C.

A. Matic, C. Masciovecchio, D. Engberg, G. Monaco, L. Borjesson, S. C. Santucci, and R. Verbeni, Phys. Rev. Lett. 93, 145502 (2004).

Shao, H.

Y. Liu, H. Shao, X. Ni, and J. Lu, Chin. Opt. Lett. (in Chinese) 6, 154 (2008).

Shen, Z.

Y. Liu, C. Liu, X. Ni, X. Luo, J. Lu, and Z. Shen, Acta Opt. Sin. (in Chinese) 26, 1580 (2006).

Y. Liu, C. Peng, X. Lan, X. Luo, Z. Shen, J. Lu, and X. Ni, Acta Phys. Sin. (in Chinese) 54, 5455 (2005).

Shields, R. L.

R. S. Taylor and R. L. Shields, J. Chem. Phys. 119, 12569 (2003).

Swofford, R. L.

J. D. Weibel, C. F. Jackels, and R. L. Swofford, J. Chem. Phys. 117, 4245 (2002).

Taylor, R. S.

R. S. Taylor and R. L. Shields, J. Chem. Phys. 119, 12569 (2003).

Tirumalai, P. S.

S. C. Upadhya, P. S. Tirumalai, M. R. Boyd, T. Mori, and V. Ravindranath, Arch. Biochem. Biophys. 373, 23 (2000).

Upadhya, S. C.

S. C. Upadhya, P. S. Tirumalai, M. R. Boyd, T. Mori, and V. Ravindranath, Arch. Biochem. Biophys. 373, 23 (2000).

Valle, F. J. O. del

M. E. Martín, M. L. Sánchez, F. J. O. del Valle, and M. A. Aguilar, J. Chem. Phys. 116, 1613 (2002).

Verbeni, R.

A. Matic, C. Masciovecchio, D. Engberg, G. Monaco, L. Borjesson, S. C. Santucci, and R. Verbeni, Phys. Rev. Lett. 93, 145502 (2004).

Wands, J. R.

S. M. de la Monte and J. R. Wands, Cell. Mol. Life Sci. 59, 882 (2002).

Weibel, J. D.

J. D. Weibel, C. F. Jackels, and R. L. Swofford, J. Chem. Phys. 117, 4245 (2002).

Wright, J. C.

K. M. Murdoch, T. D. Ferris, J. C. Wright, and T. C. Farrar, J. Chem. Phys. 116, 5717 (2002).

Wu, D.

S. Dai, P. Li, X. Yang, D. Wu, R. Li, J. Yang, and H. Xiao, Acta Phys. Sin. (in Chinese) 26, 141 (2006).

Xiao, H.

S. Dai, P. Li, X. Yang, D. Wu, R. Li, J. Yang, and H. Xiao, Acta Phys. Sin. (in Chinese) 26, 141 (2006).

Yang, J.

S. Dai, P. Li, X. Yang, D. Wu, R. Li, J. Yang, and H. Xiao, Acta Phys. Sin. (in Chinese) 26, 141 (2006).

Yang, X.

S. Dai, P. Li, X. Yang, D. Wu, R. Li, J. Yang, and H. Xiao, Acta Phys. Sin. (in Chinese) 26, 141 (2006).

Acta Opt. Sin. (in Chinese) (1)

Y. Liu, C. Liu, X. Ni, X. Luo, J. Lu, and Z. Shen, Acta Opt. Sin. (in Chinese) 26, 1580 (2006).

Acta Phys. Sin. (in Chinese) (2)

Y. Liu, C. Peng, X. Lan, X. Luo, Z. Shen, J. Lu, and X. Ni, Acta Phys. Sin. (in Chinese) 54, 5455 (2005).

S. Dai, P. Li, X. Yang, D. Wu, R. Li, J. Yang, and H. Xiao, Acta Phys. Sin. (in Chinese) 26, 141 (2006).

Arch. Biochem. Biophys. (1)

S. C. Upadhya, P. S. Tirumalai, M. R. Boyd, T. Mori, and V. Ravindranath, Arch. Biochem. Biophys. 373, 23 (2000).

Cell. Mol. Life Sci. (1)

S. M. de la Monte and J. R. Wands, Cell. Mol. Life Sci. 59, 882 (2002).

Chin. Opt. Lett. (in Chinese) (1)

Y. Liu, H. Shao, X. Ni, and J. Lu, Chin. Opt. Lett. (in Chinese) 6, 154 (2008).

J. Cancer Res. Clin. Oncol. (1)

F. Castaneda and R. K. H. Kinne, J. Cancer Res. Clin. Oncol. 126, 305 (2000).

J. Chem. Phys. (5)

K. M. Murdoch, T. D. Ferris, J. C. Wright, and T. C. Farrar, J. Chem. Phys. 116, 5717 (2002).

R. Laenen and C. Rauscher, J. Chem. Phys. 107, 9759 (1997).

M. E. Martín, M. L. Sánchez, F. J. O. del Valle, and M. A. Aguilar, J. Chem. Phys. 116, 1613 (2002).

J. D. Weibel, C. F. Jackels, and R. L. Swofford, J. Chem. Phys. 117, 4245 (2002).

R. S. Taylor and R. L. Shields, J. Chem. Phys. 119, 12569 (2003).

Mol. Phys. (1)

M. Masella and J.-P. Flament, Mol. Phys. 95, 97 (1998).

Phys. Rev. Lett. (1)

A. Matic, C. Masciovecchio, D. Engberg, G. Monaco, L. Borjesson, S. C. Santucci, and R. Verbeni, Phys. Rev. Lett. 93, 145502 (2004).

Other (1)

J. Xu and Z. Wang, Fluorescence Analysis (in Chinese) (Science Press, Beijing, 2006) p.299, 300.

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