Abstract

A dissolved oxygen (DO) sensor based on U-shape plastic optical fiber (POF) and dichlorotris (1, 10-phenanthroline) ruthenium ([Ru(dpp)<sup>3</sup>]<sup>2+</sup>) as an oxygen indicator was described. Fluorescence intensity and lifetime were measured when the sensor was soaked into a water bath blasted with air with varied O<sub>2</sub>/N<sub>2</sub> ratios. The influence of Ru concentration, annealing time and U-shaped POF curve radius on the system sensitivity was also studied. A two-layer model was proposed to analyze the deviation from linear relation described by Stern-Volmer equation, and to explain the deviation and the dependence of the fluorescence on curvature of U-shape POF. By fitting the experimentally measured sub-linear relation of <i>τ</i><sub>0</sub>/<i>τ</i> ratio versus oxygen concentration, the proportion of effectively sensitive layer and the Stern-Volmer coefficient can be evaluated to be <i>f</i>=0.59 and <i>K</i><sub>SV</sub>=0.61 typically.

© 2008 Chinese Optics Letters

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2007 (3)

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 229 (2007).

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 1263 (2007).

F. Chu, H. Cai, R. Qu, and Z. Fang, Proc. SPIE 6781, 678108 (2007).

2004 (2)

D. P. O'Neal, M. A. Meledeo, J. R. Davis, B. L. Ibey, V. A. Gant, M. V. Pishko, and G. L. Coté, IEEE Sensor Journal 4, 728 (2004).

A. Campbell and D. Uttamchandani, IEE Proc.-Sci. Meas. Technol. 151, 291 (2004).

2003 (1)

D. Sheng, S. Zhao, Y. Han, F. Yue, and J. Huang, Sensor Technology (in Chinese) 23, 381 (2003).

2002 (2)

X. Chen, Z. Zhong, and Z. Li, Sensors and Actuators B 87, 233 (2002).

B. D. MacCraith and C. McDonagh, Journal of Fluorescence 12, 333 (2002).

2001 (1)

H. Hecht and M. Kolling, Sensors and Actuators B 81, 76 (2001).

1999 (1)

S. McCulloch and D. Uttamchandani, IEE Proc.-Sci. Meas. Technol. 146, 123 (1999).

1991 (1)

E. R. Carraway, J. N. Demas, and B. A. DeGraff, Analytical Chemistry 63, 337 (1991).

1976 (1)

D. Marcuse, J. Am. Soc. Opt. 66, 311 (1976).

Cai, H.

F. Chu, H. Cai, R. Qu, and Z. Fang, Proc. SPIE 6781, 678108 (2007).

Campbell, A.

A. Campbell and D. Uttamchandani, IEE Proc.-Sci. Meas. Technol. 151, 291 (2004).

Carraway, E. R.

E. R. Carraway, J. N. Demas, and B. A. DeGraff, Analytical Chemistry 63, 337 (1991).

Chen, X.

X. Chen, Z. Zhong, and Z. Li, Sensors and Actuators B 87, 233 (2002).

Chu, F.

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 1263 (2007).

F. Chu, H. Cai, R. Qu, and Z. Fang, Proc. SPIE 6781, 678108 (2007).

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 229 (2007).

Coté, G. L.

D. P. O'Neal, M. A. Meledeo, J. R. Davis, B. L. Ibey, V. A. Gant, M. V. Pishko, and G. L. Coté, IEEE Sensor Journal 4, 728 (2004).

Davis, J. R.

D. P. O'Neal, M. A. Meledeo, J. R. Davis, B. L. Ibey, V. A. Gant, M. V. Pishko, and G. L. Coté, IEEE Sensor Journal 4, 728 (2004).

DeGraff, B. A.

E. R. Carraway, J. N. Demas, and B. A. DeGraff, Analytical Chemistry 63, 337 (1991).

Demas, J. N.

E. R. Carraway, J. N. Demas, and B. A. DeGraff, Analytical Chemistry 63, 337 (1991).

Fang, Z.

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 229 (2007).

F. Chu, H. Cai, R. Qu, and Z. Fang, Proc. SPIE 6781, 678108 (2007).

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 1263 (2007).

Gant, V. A.

D. P. O'Neal, M. A. Meledeo, J. R. Davis, B. L. Ibey, V. A. Gant, M. V. Pishko, and G. L. Coté, IEEE Sensor Journal 4, 728 (2004).

Geng, J.

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 1263 (2007).

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 229 (2007).

Han, X.

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 229 (2007).

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 1263 (2007).

Han, Y.

D. Sheng, S. Zhao, Y. Han, F. Yue, and J. Huang, Sensor Technology (in Chinese) 23, 381 (2003).

Hecht, H.

H. Hecht and M. Kolling, Sensors and Actuators B 81, 76 (2001).

Huang, J.

D. Sheng, S. Zhao, Y. Han, F. Yue, and J. Huang, Sensor Technology (in Chinese) 23, 381 (2003).

Ibey, B. L.

D. P. O'Neal, M. A. Meledeo, J. R. Davis, B. L. Ibey, V. A. Gant, M. V. Pishko, and G. L. Coté, IEEE Sensor Journal 4, 728 (2004).

Kolling, M.

H. Hecht and M. Kolling, Sensors and Actuators B 81, 76 (2001).

Li, Z.

X. Chen, Z. Zhong, and Z. Li, Sensors and Actuators B 87, 233 (2002).

MacCraith, B. D.

B. D. MacCraith and C. McDonagh, Journal of Fluorescence 12, 333 (2002).

Marcuse, D.

D. Marcuse, J. Am. Soc. Opt. 66, 311 (1976).

McCulloch, S.

S. McCulloch and D. Uttamchandani, IEE Proc.-Sci. Meas. Technol. 146, 123 (1999).

McDonagh, C.

B. D. MacCraith and C. McDonagh, Journal of Fluorescence 12, 333 (2002).

Meledeo, M. A.

D. P. O'Neal, M. A. Meledeo, J. R. Davis, B. L. Ibey, V. A. Gant, M. V. Pishko, and G. L. Coté, IEEE Sensor Journal 4, 728 (2004).

O'Neal, D. P.

D. P. O'Neal, M. A. Meledeo, J. R. Davis, B. L. Ibey, V. A. Gant, M. V. Pishko, and G. L. Coté, IEEE Sensor Journal 4, 728 (2004).

Pang, F.

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 1263 (2007).

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 229 (2007).

Pishko, M. V.

D. P. O'Neal, M. A. Meledeo, J. R. Davis, B. L. Ibey, V. A. Gant, M. V. Pishko, and G. L. Coté, IEEE Sensor Journal 4, 728 (2004).

Qu, R.

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 1263 (2007).

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 229 (2007).

F. Chu, H. Cai, R. Qu, and Z. Fang, Proc. SPIE 6781, 678108 (2007).

Sheng, D.

D. Sheng, S. Zhao, Y. Han, F. Yue, and J. Huang, Sensor Technology (in Chinese) 23, 381 (2003).

Uttamchandani, D.

A. Campbell and D. Uttamchandani, IEE Proc.-Sci. Meas. Technol. 151, 291 (2004).

S. McCulloch and D. Uttamchandani, IEE Proc.-Sci. Meas. Technol. 146, 123 (1999).

Wen, H.

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 229 (2007).

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 1263 (2007).

Yue, F.

D. Sheng, S. Zhao, Y. Han, F. Yue, and J. Huang, Sensor Technology (in Chinese) 23, 381 (2003).

Zhao, S.

D. Sheng, S. Zhao, Y. Han, F. Yue, and J. Huang, Sensor Technology (in Chinese) 23, 381 (2003).

Zhong, Z.

X. Chen, Z. Zhong, and Z. Li, Sensors and Actuators B 87, 233 (2002).

Analytical Chemistry (1)

E. R. Carraway, J. N. Demas, and B. A. DeGraff, Analytical Chemistry 63, 337 (1991).

Chinese J. Lasers (in Chinese) (2)

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 229 (2007).

F. Chu, F. Pang, X. Han, J. Geng, H. Wen, R. Qu, and Z. Fang, Chinese J. Lasers (in Chinese) 34, 1263 (2007).

IEE Proc.-Sci. Meas. Technol. (2)

S. McCulloch and D. Uttamchandani, IEE Proc.-Sci. Meas. Technol. 146, 123 (1999).

A. Campbell and D. Uttamchandani, IEE Proc.-Sci. Meas. Technol. 151, 291 (2004).

IEEE Sensor Journal (1)

D. P. O'Neal, M. A. Meledeo, J. R. Davis, B. L. Ibey, V. A. Gant, M. V. Pishko, and G. L. Coté, IEEE Sensor Journal 4, 728 (2004).

J. Am. Soc. Opt. (1)

D. Marcuse, J. Am. Soc. Opt. 66, 311 (1976).

Journal of Fluorescence (1)

B. D. MacCraith and C. McDonagh, Journal of Fluorescence 12, 333 (2002).

Proc. SPIE (1)

F. Chu, H. Cai, R. Qu, and Z. Fang, Proc. SPIE 6781, 678108 (2007).

Sensor Technology (in Chinese) (1)

D. Sheng, S. Zhao, Y. Han, F. Yue, and J. Huang, Sensor Technology (in Chinese) 23, 381 (2003).

Sensors and Actuators B (2)

H. Hecht and M. Kolling, Sensors and Actuators B 81, 76 (2001).

X. Chen, Z. Zhong, and Z. Li, Sensors and Actuators B 87, 233 (2002).

Other (2)

J. R. Lakowicz, Principles of Fluorescence Spectroscopy (Academic Press, New York, 1983).

B. Zhang, An oxygen sensor based on fluorescence quenching (in Chinese) Master dissertation (Wu Han University of Technology, 2003) p.37.

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