Abstract

The xNb2O5-(15-x)La2O3-40B2O3-45BaO (x=5, 7.5, 12.5 mol%) glasses doped with Eu3+ ions in 1 mol% are fabricated by the melting method. The Fourier transform infrared (FTIR) spectra, phonon side-band spectra, emission and excitation spectra of the glasses are measured. The crystal field parameter and coordination number of Eu3+ ions in the glasses are obtained according to the splitting of their 5D0-7F1 levels. The intensity parameters 'Omega'2 and 'Omega'4 of Eu3+ ions for optical transition are calculated from their emission spectra in terms of reduced matrix U(t) ('lambda'=2, 4, 6) character for optical transitions. The results indicate that the intensity parameters 'Omega'2 and 'Omega'4 increase with the increase of Nb2O5 content, suggesting that the symmetry becomes lower, the band of Eu and O atoms becomes stronger and the covalence increases with the increase of Nb2O5 content.

© 2006 Chinese Optics Letters

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2005 (1)

2003 (2)

H. Xia, H. Song, Q. Nie, J. Zhang, J. Wang, J. Wang, T. Xu, and J. Zhang, Chin. Opt. Lett. 1, 296 (2003).

H.-P. Xia, H.-W. Song, J.-W. Wang, J.-L. Zhang, J.-H. Wang, J.-H. Zhang, Q.-H. Nie, and T.-F. Xu, Chin. Phys. Lett. 20, 571 (2003).

2001 (1)

B. Chen, H. Wang, S. E, and S. Huang, Chin. J. Lumin. (in Chinese) 22, 139 (2001).

2000 (1)

V. G. Plotnichenko, V. O. Sokolov, E. B. Kryukova, and E. M. Dianov, J. Non-Cryst. Solids 270, 20 (2000).

1997 (2)

M. Wachtler, A. Speghini, S. Pigorini, R. Rolli, and M. Bettinelli, J. Non-Cryst. Solids 217, 111 (1997).

M. Nogami and Y. Abe, J. Appl. Phys. 81, 6351 (1997).

1996 (1)

M. Nogami and Y. Abe, J. Non-Cryst. Solids 197, 73 (1996).

1995 (2)

A. Lu, Y. Xie, X. Zhang, and R. Lu, J. Chin. Ceram. Soc. (in Chinese) 23, 106 (1995).

X. Zou and H. Toratani, Phys. Rev. B 52, 15889 (1995).

1994 (3)

M. Tanaka and T. Kushida, Phys. Rev. B 49, 5192 (1994).

M. Tanaka, G. Nishimura, and T. Kushida, Phys. Rev. B 49, 16917 (1994).

R. C. Faria and L.-O. S. Bulhoes, J. Electrochem. Soc. 141, L29 (1994).

1983 (1)

M. J. Weber, J. E. Lynch, D. H. Blackburn, and D. J. Cronin, IEEE J. Quantum Electron. 19, 1600 (1983).

1980 (1)

C. Brecher and L. A. Riseberg, Phys. Rev. B 21, 2607 (1980).

1976 (1)

C. Brecher and L. A. Riseberg, Phys. Rev. B 13, 81 (1976).

1962 (2)

B. R. Judd, Phys. Rev. 127, 750 (1962).

G. S. Ofelt, J. Chem. Phys. 37, 511 (1962).

Abe, Y.

M. Nogami and Y. Abe, J. Appl. Phys. 81, 6351 (1997).

M. Nogami and Y. Abe, J. Non-Cryst. Solids 197, 73 (1996).

Bettinelli, M.

M. Wachtler, A. Speghini, S. Pigorini, R. Rolli, and M. Bettinelli, J. Non-Cryst. Solids 217, 111 (1997).

Blackburn, D. H.

M. J. Weber, J. E. Lynch, D. H. Blackburn, and D. J. Cronin, IEEE J. Quantum Electron. 19, 1600 (1983).

Brecher, C.

C. Brecher and L. A. Riseberg, Phys. Rev. B 21, 2607 (1980).

C. Brecher and L. A. Riseberg, Phys. Rev. B 13, 81 (1976).

Bulhoes, L.-O. S.

R. C. Faria and L.-O. S. Bulhoes, J. Electrochem. Soc. 141, L29 (1994).

Chen, B.

B. Chen, H. Wang, S. E, and S. Huang, Chin. J. Lumin. (in Chinese) 22, 139 (2001).

Cronin, D. J.

M. J. Weber, J. E. Lynch, D. H. Blackburn, and D. J. Cronin, IEEE J. Quantum Electron. 19, 1600 (1983).

Dianov, E. M.

V. G. Plotnichenko, V. O. Sokolov, E. B. Kryukova, and E. M. Dianov, J. Non-Cryst. Solids 270, 20 (2000).

E, S.

B. Chen, H. Wang, S. E, and S. Huang, Chin. J. Lumin. (in Chinese) 22, 139 (2001).

Faria, R. C.

R. C. Faria and L.-O. S. Bulhoes, J. Electrochem. Soc. 141, L29 (1994).

Huang, S.

B. Chen, H. Wang, S. E, and S. Huang, Chin. J. Lumin. (in Chinese) 22, 139 (2001).

Judd, B. R.

B. R. Judd, Phys. Rev. 127, 750 (1962).

Kryukova, E. B.

V. G. Plotnichenko, V. O. Sokolov, E. B. Kryukova, and E. M. Dianov, J. Non-Cryst. Solids 270, 20 (2000).

Kushida, T.

M. Tanaka, G. Nishimura, and T. Kushida, Phys. Rev. B 49, 16917 (1994).

M. Tanaka and T. Kushida, Phys. Rev. B 49, 5192 (1994).

Lu, A.

A. Lu, Y. Xie, X. Zhang, and R. Lu, J. Chin. Ceram. Soc. (in Chinese) 23, 106 (1995).

Lu, R.

A. Lu, Y. Xie, X. Zhang, and R. Lu, J. Chin. Ceram. Soc. (in Chinese) 23, 106 (1995).

Lynch, J. E.

M. J. Weber, J. E. Lynch, D. H. Blackburn, and D. J. Cronin, IEEE J. Quantum Electron. 19, 1600 (1983).

Ming, H.

Nie, Q.

Nie, Q.-H.

H.-P. Xia, H.-W. Song, J.-W. Wang, J.-L. Zhang, J.-H. Wang, J.-H. Zhang, Q.-H. Nie, and T.-F. Xu, Chin. Phys. Lett. 20, 571 (2003).

Nishimura, G.

M. Tanaka, G. Nishimura, and T. Kushida, Phys. Rev. B 49, 16917 (1994).

Nogami, M.

M. Nogami and Y. Abe, J. Appl. Phys. 81, 6351 (1997).

M. Nogami and Y. Abe, J. Non-Cryst. Solids 197, 73 (1996).

Ofelt, G. S.

G. S. Ofelt, J. Chem. Phys. 37, 511 (1962).

Pigorini, S.

M. Wachtler, A. Speghini, S. Pigorini, R. Rolli, and M. Bettinelli, J. Non-Cryst. Solids 217, 111 (1997).

Plotnichenko, V. G.

V. G. Plotnichenko, V. O. Sokolov, E. B. Kryukova, and E. M. Dianov, J. Non-Cryst. Solids 270, 20 (2000).

Riseberg, L. A.

C. Brecher and L. A. Riseberg, Phys. Rev. B 21, 2607 (1980).

C. Brecher and L. A. Riseberg, Phys. Rev. B 13, 81 (1976).

Rolli, R.

M. Wachtler, A. Speghini, S. Pigorini, R. Rolli, and M. Bettinelli, J. Non-Cryst. Solids 217, 111 (1997).

Sokolov, V. O.

V. G. Plotnichenko, V. O. Sokolov, E. B. Kryukova, and E. M. Dianov, J. Non-Cryst. Solids 270, 20 (2000).

Song, H.

Song, H.-W.

H.-P. Xia, H.-W. Song, J.-W. Wang, J.-L. Zhang, J.-H. Wang, J.-H. Zhang, Q.-H. Nie, and T.-F. Xu, Chin. Phys. Lett. 20, 571 (2003).

Speghini, A.

M. Wachtler, A. Speghini, S. Pigorini, R. Rolli, and M. Bettinelli, J. Non-Cryst. Solids 217, 111 (1997).

Sun, X.

Tanaka, M.

M. Tanaka and T. Kushida, Phys. Rev. B 49, 5192 (1994).

M. Tanaka, G. Nishimura, and T. Kushida, Phys. Rev. B 49, 16917 (1994).

Toratani, H.

X. Zou and H. Toratani, Phys. Rev. B 52, 15889 (1995).

Wachtler, M.

M. Wachtler, A. Speghini, S. Pigorini, R. Rolli, and M. Bettinelli, J. Non-Cryst. Solids 217, 111 (1997).

Wang, H.

B. Chen, H. Wang, S. E, and S. Huang, Chin. J. Lumin. (in Chinese) 22, 139 (2001).

Wang, J.

Wang, J.-H.

H.-P. Xia, H.-W. Song, J.-W. Wang, J.-L. Zhang, J.-H. Wang, J.-H. Zhang, Q.-H. Nie, and T.-F. Xu, Chin. Phys. Lett. 20, 571 (2003).

Wang, J.-W.

H.-P. Xia, H.-W. Song, J.-W. Wang, J.-L. Zhang, J.-H. Wang, J.-H. Zhang, Q.-H. Nie, and T.-F. Xu, Chin. Phys. Lett. 20, 571 (2003).

Weber, M. J.

M. J. Weber, J. E. Lynch, D. H. Blackburn, and D. J. Cronin, IEEE J. Quantum Electron. 19, 1600 (1983).

Xia, H.

Xia, H.-P.

H.-P. Xia, H.-W. Song, J.-W. Wang, J.-L. Zhang, J.-H. Wang, J.-H. Zhang, Q.-H. Nie, and T.-F. Xu, Chin. Phys. Lett. 20, 571 (2003).

Xie, J.

Xie, Y.

A. Lu, Y. Xie, X. Zhang, and R. Lu, J. Chin. Ceram. Soc. (in Chinese) 23, 106 (1995).

Xu, T.

Xu, T.-F.

H.-P. Xia, H.-W. Song, J.-W. Wang, J.-L. Zhang, J.-H. Wang, J.-H. Zhang, Q.-H. Nie, and T.-F. Xu, Chin. Phys. Lett. 20, 571 (2003).

Zhang, J.

Zhang, J.-H.

H.-P. Xia, H.-W. Song, J.-W. Wang, J.-L. Zhang, J.-H. Wang, J.-H. Zhang, Q.-H. Nie, and T.-F. Xu, Chin. Phys. Lett. 20, 571 (2003).

Zhang, J.-L.

H.-P. Xia, H.-W. Song, J.-W. Wang, J.-L. Zhang, J.-H. Wang, J.-H. Zhang, Q.-H. Nie, and T.-F. Xu, Chin. Phys. Lett. 20, 571 (2003).

Zhang, X.

A. Lu, Y. Xie, X. Zhang, and R. Lu, J. Chin. Ceram. Soc. (in Chinese) 23, 106 (1995).

Zheng, Z.

Zou, X.

X. Zou and H. Toratani, Phys. Rev. B 52, 15889 (1995).

Chin. J. Lumin. (in Chinese) (1)

B. Chen, H. Wang, S. E, and S. Huang, Chin. J. Lumin. (in Chinese) 22, 139 (2001).

Chin. Opt. Lett. (2)

Chin. Phys. Lett. (1)

H.-P. Xia, H.-W. Song, J.-W. Wang, J.-L. Zhang, J.-H. Wang, J.-H. Zhang, Q.-H. Nie, and T.-F. Xu, Chin. Phys. Lett. 20, 571 (2003).

IEEE J. Quantum Electron. (1)

M. J. Weber, J. E. Lynch, D. H. Blackburn, and D. J. Cronin, IEEE J. Quantum Electron. 19, 1600 (1983).

J. Appl. Phys. (1)

M. Nogami and Y. Abe, J. Appl. Phys. 81, 6351 (1997).

J. Chem. Phys. (1)

G. S. Ofelt, J. Chem. Phys. 37, 511 (1962).

J. Chin. Ceram. Soc. (in Chinese) (1)

A. Lu, Y. Xie, X. Zhang, and R. Lu, J. Chin. Ceram. Soc. (in Chinese) 23, 106 (1995).

J. Electrochem. Soc. (1)

R. C. Faria and L.-O. S. Bulhoes, J. Electrochem. Soc. 141, L29 (1994).

J. Non-Cryst. Solids (3)

V. G. Plotnichenko, V. O. Sokolov, E. B. Kryukova, and E. M. Dianov, J. Non-Cryst. Solids 270, 20 (2000).

M. Wachtler, A. Speghini, S. Pigorini, R. Rolli, and M. Bettinelli, J. Non-Cryst. Solids 217, 111 (1997).

M. Nogami and Y. Abe, J. Non-Cryst. Solids 197, 73 (1996).

Phys. Rev. (1)

B. R. Judd, Phys. Rev. 127, 750 (1962).

Phys. Rev. B (5)

X. Zou and H. Toratani, Phys. Rev. B 52, 15889 (1995).

C. Brecher and L. A. Riseberg, Phys. Rev. B 13, 81 (1976).

C. Brecher and L. A. Riseberg, Phys. Rev. B 21, 2607 (1980).

M. Tanaka and T. Kushida, Phys. Rev. B 49, 5192 (1994).

M. Tanaka, G. Nishimura, and T. Kushida, Phys. Rev. B 49, 16917 (1994).

Other (1)

F. Gan, The Physical Property Calculation and Compositional Design of Inorganic Glasses (in Chinese) (Shanghai Scientific and Technical Press, Shanghai, 1981) p.105.

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