Abstract

The polyimide-silica nonlinear optical (NLO) hybrid materials with covalent links between the inorganic and the organic networks were synthesized by the sol-gel method. The prepared hybrids were characterized by IR, TGA, XRD, SEM, TEM and can be easily spin-coated, ensuring long-term alignment stability at elevated temperatures. These devices exhibit large electro-optic coefficients at 832 nm. The experimental results suggest that the hybrid thin films have potential applications as passive films for optical devices.

© 2005 Chinese Optics Letters

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2002 (2)

C. M. Chung, S. J. Lee, J. G. Kim, and D. O. Jang, J. Non-Cryst. Solids 311, 195 (2002).

J. C. Cornelius, Polym. 43, 2385 (2002).

2001 (2)

Y. G. Hsu, K. H. Lin, and I. L. Chiang, Mater. Sci. Engng. B 87, 31 (2001).

J. H. Kim and Y. M. Lee, J. Membr. Sci. 193, 209 (2001).

2000 (1)

Y. Jiang, Z. Q. Cao, Q. S. Shen, X. M. Dou, and Y. L. Chem, J. Opt. Soc. Am. B 17, 508 (2000).

1999 (1)

H. K. Kim, S. J. Kang, S. K. Choi, Y. H. Min, and C. S. Yoon, Chem. Mater. 11, 779 (1999).

1998 (1)

L. Rozes, C. Noel, I. Campistron, M. Thomas, D. Reyx, and F. Kajzar, Macromol. Chem. Phys. 199, 2553 (1998).

1997 (1)

A. Ibanez, J. P. Levy, C. Mouget, and E. Prieur, J. Solid State Chem. 129, 22 (1997).

Chem. Mater. (1)

H. K. Kim, S. J. Kang, S. K. Choi, Y. H. Min, and C. S. Yoon, Chem. Mater. 11, 779 (1999).

J. Membr. Sci. (1)

J. H. Kim and Y. M. Lee, J. Membr. Sci. 193, 209 (2001).

J. Non-Cryst. Solids (1)

C. M. Chung, S. J. Lee, J. G. Kim, and D. O. Jang, J. Non-Cryst. Solids 311, 195 (2002).

J. Opt. Soc. Am. B (1)

Y. Jiang, Z. Q. Cao, Q. S. Shen, X. M. Dou, and Y. L. Chem, J. Opt. Soc. Am. B 17, 508 (2000).

J. Solid State Chem. (1)

A. Ibanez, J. P. Levy, C. Mouget, and E. Prieur, J. Solid State Chem. 129, 22 (1997).

Macromol. Chem. Phys. (1)

L. Rozes, C. Noel, I. Campistron, M. Thomas, D. Reyx, and F. Kajzar, Macromol. Chem. Phys. 199, 2553 (1998).

Mater. Sci. Engng. B (1)

Y. G. Hsu, K. H. Lin, and I. L. Chiang, Mater. Sci. Engng. B 87, 31 (2001).

Polym. (1)

J. C. Cornelius, Polym. 43, 2385 (2002).

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