Abstract

A tunable luminescence from red to blue in Eu-doped mesoporous AlPO4 glass is achieved by adjusting the annealing temperature. With increasing annealing temperature, the increased Eu3+ ions reduction changes the luminescence of the obtained glass. The abnormal reduction of Eu3+ to Eu2+ occurs in AlPO4 mesoporous glass at relative low annealed temperatures from 600 to 800 oC in air. The presence of Eu2+ ions, which are reduced from Eu3+ by hole-electron pairs, is revealed by XPS spectra. Our results indicate the mesoporous AlPO4 glass is a suitable matrix to incorporate Eu ions as the tunable luminescent light sources or LEDs.

© 2014 Chinese Optics Letters

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  2. Y. Zhang, G. Li, D. Geng, M. Shang, C. Peng, and J. Lin, Inorg. Chem. 51, 11655 (2012).
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2012 (2)

Y. Zhang, G. Li, D. Geng, M. Shang, C. Peng, and J. Lin, Inorg. Chem. 51, 11655 (2012).

Y. Xu, S. Cui, H. Fu, J. Qian, Q. Luo, X. Qiao, X. Fan, and X. Zhang, Chin. Opt. Lett. 10, 031602(2012).

2011 (2)

G. Gao, S. Reibstein, M. Peng, and L. Wondraczek, J. Mater. Chem. 21, 3156 (2011).

L. Yang, M. Yamashita, and T. Akai, J. Non-Cryst. Solids357, 2400 (2011).

2010 (2)

G. Jia, P. A. Tanner, C. K. Duan, and D. G. Jeannette, J. Phys. Chem. C 114, 17905 (2010).

Z. Y. Mao, and D. J. Wang, Inorg. Chem. 49, 4922 (2010).

2009 (2)

Y. Tian, X. Qi, X. Wu, R. Hua, and B. Chen, J. Phys. Chem. C 113, 10767 (2009).

Q. Zhang, Y. Qiao, B. Qian, G. Dong, J. Ruan, X. Liu, Q. Zhou, Q. Chen, J. Qiu, and D. Chen, J. Lumin. 129, 1393 (2009).

2007 (1)

C. Wang, M. Peng, N. Jiang, X. Jiang, C. Zhao, and J. Qiu, Mater. Lett. 61, 3608 (2007).

2005 (3)

D. Chen, H. Miyoshi, T. Akai, and T. Yazawa, Appl. Phys. Lett. 86, 231908 (2005).

L. Zhang, A. B¨ogershausen, and H. Eckert, J. Am. Ceram. Soc. 88, 897 (2005).

W. J. Yang, L. Luo, T. M. Chen, and N. S. Wang, Chem. Mater. 17, 3883 (2005).

2004 (2)

M. Peng, J. Qiu, L. Yang, and C. Zhao, Opt. Mater. 27, 591 (2004).

P. Smet, D. Poelman, and R. Van Meirhaeghe, J. Appl. Phys. 95, 184 (2004).

2003 (2)

M. Peng, Z. Pei, G. Hong, and Q. Su, Chem. Phys. Lett. 371, 1 (2003).

M. Peng, Z. Pei, G. Hong, and Q. Su, J. Mater. Chem. 13, 1202 (2003).

1999 (1)

A. Biswas, C. S. Friend, and P. N. Prasad, Mater. Lett. 39, 227 (1999).

1996 (2)

J. Duffy, J. Non-Cryst. Solids 196, 45 (1996).

M. Nogami and Y. Abe, J. Non-Cryst. Solids 197, 73 (1996).

1986 (1)

K. Arai, H. Namikawa, K. Kumata, T. Honda, Y. Ishii, and T. Handa, J. Appl. Phys. 59, 3430 (1986).

Abe, Y.

M. Nogami and Y. Abe, J. Non-Cryst. Solids 197, 73 (1996).

Akai, T.

L. Yang, M. Yamashita, and T. Akai, J. Non-Cryst. Solids357, 2400 (2011).

D. Chen, H. Miyoshi, T. Akai, and T. Yazawa, Appl. Phys. Lett. 86, 231908 (2005).

Arai, K.

K. Arai, H. Namikawa, K. Kumata, T. Honda, Y. Ishii, and T. Handa, J. Appl. Phys. 59, 3430 (1986).

B¨ogershausen, A.

L. Zhang, A. B¨ogershausen, and H. Eckert, J. Am. Ceram. Soc. 88, 897 (2005).

Biswas, A.

A. Biswas, C. S. Friend, and P. N. Prasad, Mater. Lett. 39, 227 (1999).

Chen, B.

Y. Tian, X. Qi, X. Wu, R. Hua, and B. Chen, J. Phys. Chem. C 113, 10767 (2009).

Chen, D.

Q. Zhang, Y. Qiao, B. Qian, G. Dong, J. Ruan, X. Liu, Q. Zhou, Q. Chen, J. Qiu, and D. Chen, J. Lumin. 129, 1393 (2009).

D. Chen, H. Miyoshi, T. Akai, and T. Yazawa, Appl. Phys. Lett. 86, 231908 (2005).

Chen, Q.

Q. Zhang, Y. Qiao, B. Qian, G. Dong, J. Ruan, X. Liu, Q. Zhou, Q. Chen, J. Qiu, and D. Chen, J. Lumin. 129, 1393 (2009).

Chen, T. M.

W. J. Yang, L. Luo, T. M. Chen, and N. S. Wang, Chem. Mater. 17, 3883 (2005).

Cui, S.

Dong, G.

Q. Zhang, Y. Qiao, B. Qian, G. Dong, J. Ruan, X. Liu, Q. Zhou, Q. Chen, J. Qiu, and D. Chen, J. Lumin. 129, 1393 (2009).

Duan, C. K.

G. Jia, P. A. Tanner, C. K. Duan, and D. G. Jeannette, J. Phys. Chem. C 114, 17905 (2010).

Duffy, J.

J. Duffy, J. Non-Cryst. Solids 196, 45 (1996).

Eckert, H.

L. Zhang, A. B¨ogershausen, and H. Eckert, J. Am. Ceram. Soc. 88, 897 (2005).

Fan, X.

Friend, C. S.

A. Biswas, C. S. Friend, and P. N. Prasad, Mater. Lett. 39, 227 (1999).

Fu, H.

Gao, G.

G. Gao, S. Reibstein, M. Peng, and L. Wondraczek, J. Mater. Chem. 21, 3156 (2011).

Geng, D.

Y. Zhang, G. Li, D. Geng, M. Shang, C. Peng, and J. Lin, Inorg. Chem. 51, 11655 (2012).

Handa, T.

K. Arai, H. Namikawa, K. Kumata, T. Honda, Y. Ishii, and T. Handa, J. Appl. Phys. 59, 3430 (1986).

Honda, T.

K. Arai, H. Namikawa, K. Kumata, T. Honda, Y. Ishii, and T. Handa, J. Appl. Phys. 59, 3430 (1986).

Hong, G.

M. Peng, Z. Pei, G. Hong, and Q. Su, Chem. Phys. Lett. 371, 1 (2003).

M. Peng, Z. Pei, G. Hong, and Q. Su, J. Mater. Chem. 13, 1202 (2003).

Hua, R.

Y. Tian, X. Qi, X. Wu, R. Hua, and B. Chen, J. Phys. Chem. C 113, 10767 (2009).

Ishii, Y.

K. Arai, H. Namikawa, K. Kumata, T. Honda, Y. Ishii, and T. Handa, J. Appl. Phys. 59, 3430 (1986).

Jeannette, D. G.

G. Jia, P. A. Tanner, C. K. Duan, and D. G. Jeannette, J. Phys. Chem. C 114, 17905 (2010).

Jia, G.

G. Jia, P. A. Tanner, C. K. Duan, and D. G. Jeannette, J. Phys. Chem. C 114, 17905 (2010).

Jiang, N.

C. Wang, M. Peng, N. Jiang, X. Jiang, C. Zhao, and J. Qiu, Mater. Lett. 61, 3608 (2007).

Jiang, X.

C. Wang, M. Peng, N. Jiang, X. Jiang, C. Zhao, and J. Qiu, Mater. Lett. 61, 3608 (2007).

Kumata, K.

K. Arai, H. Namikawa, K. Kumata, T. Honda, Y. Ishii, and T. Handa, J. Appl. Phys. 59, 3430 (1986).

Li, G.

Y. Zhang, G. Li, D. Geng, M. Shang, C. Peng, and J. Lin, Inorg. Chem. 51, 11655 (2012).

Lin, J.

Y. Zhang, G. Li, D. Geng, M. Shang, C. Peng, and J. Lin, Inorg. Chem. 51, 11655 (2012).

Liu, X.

Q. Zhang, Y. Qiao, B. Qian, G. Dong, J. Ruan, X. Liu, Q. Zhou, Q. Chen, J. Qiu, and D. Chen, J. Lumin. 129, 1393 (2009).

Luo, L.

W. J. Yang, L. Luo, T. M. Chen, and N. S. Wang, Chem. Mater. 17, 3883 (2005).

Luo, Q.

Mao, Z. Y.

Z. Y. Mao, and D. J. Wang, Inorg. Chem. 49, 4922 (2010).

Meirhaeghe, R. Van

P. Smet, D. Poelman, and R. Van Meirhaeghe, J. Appl. Phys. 95, 184 (2004).

Miyoshi, H.

D. Chen, H. Miyoshi, T. Akai, and T. Yazawa, Appl. Phys. Lett. 86, 231908 (2005).

Namikawa, H.

K. Arai, H. Namikawa, K. Kumata, T. Honda, Y. Ishii, and T. Handa, J. Appl. Phys. 59, 3430 (1986).

Nogami, M.

M. Nogami and Y. Abe, J. Non-Cryst. Solids 197, 73 (1996).

Pei, Z.

M. Peng, Z. Pei, G. Hong, and Q. Su, Chem. Phys. Lett. 371, 1 (2003).

M. Peng, Z. Pei, G. Hong, and Q. Su, J. Mater. Chem. 13, 1202 (2003).

Peng, C.

Y. Zhang, G. Li, D. Geng, M. Shang, C. Peng, and J. Lin, Inorg. Chem. 51, 11655 (2012).

Peng, M.

G. Gao, S. Reibstein, M. Peng, and L. Wondraczek, J. Mater. Chem. 21, 3156 (2011).

C. Wang, M. Peng, N. Jiang, X. Jiang, C. Zhao, and J. Qiu, Mater. Lett. 61, 3608 (2007).

M. Peng, J. Qiu, L. Yang, and C. Zhao, Opt. Mater. 27, 591 (2004).

M. Peng, Z. Pei, G. Hong, and Q. Su, J. Mater. Chem. 13, 1202 (2003).

M. Peng, Z. Pei, G. Hong, and Q. Su, Chem. Phys. Lett. 371, 1 (2003).

Poelman, D.

P. Smet, D. Poelman, and R. Van Meirhaeghe, J. Appl. Phys. 95, 184 (2004).

Prasad, P. N.

A. Biswas, C. S. Friend, and P. N. Prasad, Mater. Lett. 39, 227 (1999).

Qi, X.

Y. Tian, X. Qi, X. Wu, R. Hua, and B. Chen, J. Phys. Chem. C 113, 10767 (2009).

Qian, B.

Q. Zhang, Y. Qiao, B. Qian, G. Dong, J. Ruan, X. Liu, Q. Zhou, Q. Chen, J. Qiu, and D. Chen, J. Lumin. 129, 1393 (2009).

Qian, J.

Qiao, X.

Qiao, Y.

Q. Zhang, Y. Qiao, B. Qian, G. Dong, J. Ruan, X. Liu, Q. Zhou, Q. Chen, J. Qiu, and D. Chen, J. Lumin. 129, 1393 (2009).

Qiu, J.

Q. Zhang, Y. Qiao, B. Qian, G. Dong, J. Ruan, X. Liu, Q. Zhou, Q. Chen, J. Qiu, and D. Chen, J. Lumin. 129, 1393 (2009).

C. Wang, M. Peng, N. Jiang, X. Jiang, C. Zhao, and J. Qiu, Mater. Lett. 61, 3608 (2007).

M. Peng, J. Qiu, L. Yang, and C. Zhao, Opt. Mater. 27, 591 (2004).

Reibstein, S.

G. Gao, S. Reibstein, M. Peng, and L. Wondraczek, J. Mater. Chem. 21, 3156 (2011).

Ruan, J.

Q. Zhang, Y. Qiao, B. Qian, G. Dong, J. Ruan, X. Liu, Q. Zhou, Q. Chen, J. Qiu, and D. Chen, J. Lumin. 129, 1393 (2009).

Shang, M.

Y. Zhang, G. Li, D. Geng, M. Shang, C. Peng, and J. Lin, Inorg. Chem. 51, 11655 (2012).

Smet, P.

P. Smet, D. Poelman, and R. Van Meirhaeghe, J. Appl. Phys. 95, 184 (2004).

Su, Q.

M. Peng, Z. Pei, G. Hong, and Q. Su, J. Mater. Chem. 13, 1202 (2003).

M. Peng, Z. Pei, G. Hong, and Q. Su, Chem. Phys. Lett. 371, 1 (2003).

Tanner, P. A.

G. Jia, P. A. Tanner, C. K. Duan, and D. G. Jeannette, J. Phys. Chem. C 114, 17905 (2010).

Tian, Y.

Y. Tian, X. Qi, X. Wu, R. Hua, and B. Chen, J. Phys. Chem. C 113, 10767 (2009).

Wang, C.

C. Wang, M. Peng, N. Jiang, X. Jiang, C. Zhao, and J. Qiu, Mater. Lett. 61, 3608 (2007).

Wang, D. J.

Z. Y. Mao, and D. J. Wang, Inorg. Chem. 49, 4922 (2010).

Wang, N. S.

W. J. Yang, L. Luo, T. M. Chen, and N. S. Wang, Chem. Mater. 17, 3883 (2005).

Wondraczek, L.

G. Gao, S. Reibstein, M. Peng, and L. Wondraczek, J. Mater. Chem. 21, 3156 (2011).

Wu, X.

Y. Tian, X. Qi, X. Wu, R. Hua, and B. Chen, J. Phys. Chem. C 113, 10767 (2009).

Xu, Y.

Yamashita, M.

L. Yang, M. Yamashita, and T. Akai, J. Non-Cryst. Solids357, 2400 (2011).

Yang, L.

L. Yang, M. Yamashita, and T. Akai, J. Non-Cryst. Solids357, 2400 (2011).

M. Peng, J. Qiu, L. Yang, and C. Zhao, Opt. Mater. 27, 591 (2004).

Yang, W. J.

W. J. Yang, L. Luo, T. M. Chen, and N. S. Wang, Chem. Mater. 17, 3883 (2005).

Yazawa, T.

D. Chen, H. Miyoshi, T. Akai, and T. Yazawa, Appl. Phys. Lett. 86, 231908 (2005).

Zhang, L.

L. Zhang, A. B¨ogershausen, and H. Eckert, J. Am. Ceram. Soc. 88, 897 (2005).

Zhang, Q.

Q. Zhang, Y. Qiao, B. Qian, G. Dong, J. Ruan, X. Liu, Q. Zhou, Q. Chen, J. Qiu, and D. Chen, J. Lumin. 129, 1393 (2009).

Zhang, X.

Zhang, Y.

Y. Zhang, G. Li, D. Geng, M. Shang, C. Peng, and J. Lin, Inorg. Chem. 51, 11655 (2012).

Zhao, C.

C. Wang, M. Peng, N. Jiang, X. Jiang, C. Zhao, and J. Qiu, Mater. Lett. 61, 3608 (2007).

M. Peng, J. Qiu, L. Yang, and C. Zhao, Opt. Mater. 27, 591 (2004).

Zhou, Q.

Q. Zhang, Y. Qiao, B. Qian, G. Dong, J. Ruan, X. Liu, Q. Zhou, Q. Chen, J. Qiu, and D. Chen, J. Lumin. 129, 1393 (2009).

Appl. Phys. Lett. (1)

D. Chen, H. Miyoshi, T. Akai, and T. Yazawa, Appl. Phys. Lett. 86, 231908 (2005).

Chem. Mater. (1)

W. J. Yang, L. Luo, T. M. Chen, and N. S. Wang, Chem. Mater. 17, 3883 (2005).

Chem. Phys. Lett. (1)

M. Peng, Z. Pei, G. Hong, and Q. Su, Chem. Phys. Lett. 371, 1 (2003).

Chin. Opt. Lett. (1)

Inorg. Chem. (2)

Y. Zhang, G. Li, D. Geng, M. Shang, C. Peng, and J. Lin, Inorg. Chem. 51, 11655 (2012).

Z. Y. Mao, and D. J. Wang, Inorg. Chem. 49, 4922 (2010).

J. Am. Ceram. Soc. (1)

L. Zhang, A. B¨ogershausen, and H. Eckert, J. Am. Ceram. Soc. 88, 897 (2005).

J. Appl. Phys. (2)

K. Arai, H. Namikawa, K. Kumata, T. Honda, Y. Ishii, and T. Handa, J. Appl. Phys. 59, 3430 (1986).

P. Smet, D. Poelman, and R. Van Meirhaeghe, J. Appl. Phys. 95, 184 (2004).

J. Lumin. (1)

Q. Zhang, Y. Qiao, B. Qian, G. Dong, J. Ruan, X. Liu, Q. Zhou, Q. Chen, J. Qiu, and D. Chen, J. Lumin. 129, 1393 (2009).

J. Mater. Chem. (2)

M. Peng, Z. Pei, G. Hong, and Q. Su, J. Mater. Chem. 13, 1202 (2003).

G. Gao, S. Reibstein, M. Peng, and L. Wondraczek, J. Mater. Chem. 21, 3156 (2011).

J. Non-Cryst. (1)

L. Yang, M. Yamashita, and T. Akai, J. Non-Cryst. Solids357, 2400 (2011).

J. Non-Cryst. Solids (2)

M. Nogami and Y. Abe, J. Non-Cryst. Solids 197, 73 (1996).

J. Duffy, J. Non-Cryst. Solids 196, 45 (1996).

J. Phys. Chem. C (2)

G. Jia, P. A. Tanner, C. K. Duan, and D. G. Jeannette, J. Phys. Chem. C 114, 17905 (2010).

Y. Tian, X. Qi, X. Wu, R. Hua, and B. Chen, J. Phys. Chem. C 113, 10767 (2009).

Mater. Lett. (2)

C. Wang, M. Peng, N. Jiang, X. Jiang, C. Zhao, and J. Qiu, Mater. Lett. 61, 3608 (2007).

A. Biswas, C. S. Friend, and P. N. Prasad, Mater. Lett. 39, 227 (1999).

Opt. Mater. (1)

M. Peng, J. Qiu, L. Yang, and C. Zhao, Opt. Mater. 27, 591 (2004).

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