Abstract

Two-photon laser-induced fluorescence spectrum (TP-LIF) of NO is obtained with a Nd:YAG pumped optical parametric generator and amplifier as radiation source. Spectral intensity distribution shows that the electronic transition moment for NO (A^(2)? ? X^(2)?) transition varies significantly with inter-nuclear distance. The variation relationship of the electronic transition moment versus inter-nuclear distance is deduced with polyminal fit procedure. The spontaneous radiative coefficients for NO (A^(2)? ? X^(2)?) transition from ?' = 0, 1 are obtained by combing this transition moment variation with the measurements of spontaneous radiative lifetime.

© 2005 Chinese Optics Letters

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  1. E. Klisch, S. P. Belov, R. Schieder, G. Winnewisser, and E. Herbst, Mole. Phys. 97, 65 (1999).
  2. C. Chackerian, Jr., R. S. Freedman, L. P. Giver, and L. R. Brown, J. Mole. Spectrosc. 192, 215 (1998).
  3. M. Khalil and A. Tokmakoff, Chem. Phys. 266, 213 (2001).
  4. L. G. Piper and L. M. Cowles, J. Chem. Phys. 85, 2419 (1986).
  5. M. Jeunehomme, J. Chem. Phys. 45, 4433 (1966).
  6. H. P. Broida and T. Carrington, J. Chem. Phys. 38, 136 (1963).
  7. J. Luque and D. R. Crosley, J. Quantum Spectrosc. Radiat. Transfer 53, 189 (1995).
  8. T. D. Varberg, F. Stroh, and K. M. Evenson, J. Mole. Spectrosc. 196, 5 (1999).
  9. M. Salzmann, M. Muller, N. Bowering, and U. Heinzmann, J. Phys. B 32, 2517 (1999).
  10. R. L. Pastel and R. C. Sausa, Appl. Opt. 39, 2487 (2000).
  11. G. Herzberg, Molecular Spectra and Molecular Structure Vol. 1 Spectra of Diatomic Molecules (Van Nostrand Reinhold Company, 1986).
  12. R. N. Zare, J. Chem. Phys. 40, 1934 (1964).

2001 (1)

M. Khalil and A. Tokmakoff, Chem. Phys. 266, 213 (2001).

2000 (1)

1999 (3)

E. Klisch, S. P. Belov, R. Schieder, G. Winnewisser, and E. Herbst, Mole. Phys. 97, 65 (1999).

T. D. Varberg, F. Stroh, and K. M. Evenson, J. Mole. Spectrosc. 196, 5 (1999).

M. Salzmann, M. Muller, N. Bowering, and U. Heinzmann, J. Phys. B 32, 2517 (1999).

1998 (1)

C. Chackerian, Jr., R. S. Freedman, L. P. Giver, and L. R. Brown, J. Mole. Spectrosc. 192, 215 (1998).

1995 (1)

J. Luque and D. R. Crosley, J. Quantum Spectrosc. Radiat. Transfer 53, 189 (1995).

1986 (1)

L. G. Piper and L. M. Cowles, J. Chem. Phys. 85, 2419 (1986).

1966 (1)

M. Jeunehomme, J. Chem. Phys. 45, 4433 (1966).

1964 (1)

R. N. Zare, J. Chem. Phys. 40, 1934 (1964).

1963 (1)

H. P. Broida and T. Carrington, J. Chem. Phys. 38, 136 (1963).

Belov, S. P.

E. Klisch, S. P. Belov, R. Schieder, G. Winnewisser, and E. Herbst, Mole. Phys. 97, 65 (1999).

Bowering, N.

M. Salzmann, M. Muller, N. Bowering, and U. Heinzmann, J. Phys. B 32, 2517 (1999).

Broida, H. P.

H. P. Broida and T. Carrington, J. Chem. Phys. 38, 136 (1963).

Brown, L. R.

C. Chackerian, Jr., R. S. Freedman, L. P. Giver, and L. R. Brown, J. Mole. Spectrosc. 192, 215 (1998).

Carrington, T.

H. P. Broida and T. Carrington, J. Chem. Phys. 38, 136 (1963).

Chackerian, C.

C. Chackerian, Jr., R. S. Freedman, L. P. Giver, and L. R. Brown, J. Mole. Spectrosc. 192, 215 (1998).

Cowles, L. M.

L. G. Piper and L. M. Cowles, J. Chem. Phys. 85, 2419 (1986).

Crosley, D. R.

J. Luque and D. R. Crosley, J. Quantum Spectrosc. Radiat. Transfer 53, 189 (1995).

Evenson, K. M.

T. D. Varberg, F. Stroh, and K. M. Evenson, J. Mole. Spectrosc. 196, 5 (1999).

Freedman, R. S.

C. Chackerian, Jr., R. S. Freedman, L. P. Giver, and L. R. Brown, J. Mole. Spectrosc. 192, 215 (1998).

Giver, L. P.

C. Chackerian, Jr., R. S. Freedman, L. P. Giver, and L. R. Brown, J. Mole. Spectrosc. 192, 215 (1998).

Heinzmann, U.

M. Salzmann, M. Muller, N. Bowering, and U. Heinzmann, J. Phys. B 32, 2517 (1999).

Herbst, E.

E. Klisch, S. P. Belov, R. Schieder, G. Winnewisser, and E. Herbst, Mole. Phys. 97, 65 (1999).

Jeunehomme, M.

M. Jeunehomme, J. Chem. Phys. 45, 4433 (1966).

Khalil, M.

M. Khalil and A. Tokmakoff, Chem. Phys. 266, 213 (2001).

Klisch, E.

E. Klisch, S. P. Belov, R. Schieder, G. Winnewisser, and E. Herbst, Mole. Phys. 97, 65 (1999).

Luque, J.

J. Luque and D. R. Crosley, J. Quantum Spectrosc. Radiat. Transfer 53, 189 (1995).

Muller, M.

M. Salzmann, M. Muller, N. Bowering, and U. Heinzmann, J. Phys. B 32, 2517 (1999).

Pastel, R. L.

Piper, L. G.

L. G. Piper and L. M. Cowles, J. Chem. Phys. 85, 2419 (1986).

Salzmann, M.

M. Salzmann, M. Muller, N. Bowering, and U. Heinzmann, J. Phys. B 32, 2517 (1999).

Sausa, R. C.

Schieder, R.

E. Klisch, S. P. Belov, R. Schieder, G. Winnewisser, and E. Herbst, Mole. Phys. 97, 65 (1999).

Stroh, F.

T. D. Varberg, F. Stroh, and K. M. Evenson, J. Mole. Spectrosc. 196, 5 (1999).

Tokmakoff, A.

M. Khalil and A. Tokmakoff, Chem. Phys. 266, 213 (2001).

Varberg, T. D.

T. D. Varberg, F. Stroh, and K. M. Evenson, J. Mole. Spectrosc. 196, 5 (1999).

Winnewisser, G.

E. Klisch, S. P. Belov, R. Schieder, G. Winnewisser, and E. Herbst, Mole. Phys. 97, 65 (1999).

Zare, R. N.

R. N. Zare, J. Chem. Phys. 40, 1934 (1964).

Appl. Opt. (1)

Chem. Phys. (1)

M. Khalil and A. Tokmakoff, Chem. Phys. 266, 213 (2001).

J. Chem. Phys. (4)

L. G. Piper and L. M. Cowles, J. Chem. Phys. 85, 2419 (1986).

M. Jeunehomme, J. Chem. Phys. 45, 4433 (1966).

H. P. Broida and T. Carrington, J. Chem. Phys. 38, 136 (1963).

R. N. Zare, J. Chem. Phys. 40, 1934 (1964).

J. Mole. Spectrosc. (2)

C. Chackerian, Jr., R. S. Freedman, L. P. Giver, and L. R. Brown, J. Mole. Spectrosc. 192, 215 (1998).

T. D. Varberg, F. Stroh, and K. M. Evenson, J. Mole. Spectrosc. 196, 5 (1999).

J. Phys. B (1)

M. Salzmann, M. Muller, N. Bowering, and U. Heinzmann, J. Phys. B 32, 2517 (1999).

J. Quantum Spectrosc. Radiat. Transfer (1)

J. Luque and D. R. Crosley, J. Quantum Spectrosc. Radiat. Transfer 53, 189 (1995).

Mole. Phys. (1)

E. Klisch, S. P. Belov, R. Schieder, G. Winnewisser, and E. Herbst, Mole. Phys. 97, 65 (1999).

Other (1)

G. Herzberg, Molecular Spectra and Molecular Structure Vol. 1 Spectra of Diatomic Molecules (Van Nostrand Reinhold Company, 1986).

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