Abstract

P_(2)O_(5).BaO.Na_(2)O.K_(2)O glasses doped with various content of Eu_(2)O_(3) were prepared using high temperature melting method, and the Eu^(2+) ions in the phosphate glasses were obtained with the aid of the reductive action of silicon powder. The fabricating conditions, fluorescence, excitation spectra of the glasses were then studied. The glasses containing europium show a broad emission band at 450 nm and sharp bands from 580 to 650 nm, and the co-existence of Eu^(2+) and Eu^(3+) is identified. Also, a good glass with a dominant proportion and large quantity of Eu^(2+) ions can be obtained by the reductive action of silicon powder and proper processing.

© 2005 Chinese Optics Letters

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  1. V. P. Gapontsev, S. M. Matisin, A. A. Isineev, and V. B. Kravchenko, Opt. Laser Technol. 14, 189 (1982).
  2. K. Hirao, J. Non-Cryst. Solids 196, 16 (1996).
  3. J. R. Qiu, Y. Shimizugawa, Y. Iwabuchi, and K. Hirao, Appl. Phys. Lett. 71, 759 (1997).
  4. J. Qiu, Y. Iwabuchi, and K. Hirao, Phys. Chem. Glasses 38, 66 (1997).
  5. M. Nogami and Y. Abe, Appl. Phys. Lett. 69, 3776 (1996).
  6. R. A. Hewes and M. V. Hoffman, J. Lumin. 3, 261 (1971).
  7. M. Nogami, T. Yamazaki, and Y. Abe, J. Lumin. 78, 63 (1998).
  8. H. P. Xia, J. L. Zhang, J. H. Wang, Q. H. Nie, and H. W. Song, Mater. Lett. 53, 277 (2002).
  9. Y. Amemiya, K. Wakabayashi, H. Tanaka, Y. Ueno, and J. Miyahara, Science 237, 164 (1987).
  10. H. Burger, K. Kneipp, H. Hobert, W. Vogel, V. Kozhukharov, and S. Neov, J. Non-Cryst. Solids 151, 134 (1992).

2002

H. P. Xia, J. L. Zhang, J. H. Wang, Q. H. Nie, and H. W. Song, Mater. Lett. 53, 277 (2002).

1998

M. Nogami, T. Yamazaki, and Y. Abe, J. Lumin. 78, 63 (1998).

1997

J. R. Qiu, Y. Shimizugawa, Y. Iwabuchi, and K. Hirao, Appl. Phys. Lett. 71, 759 (1997).

J. Qiu, Y. Iwabuchi, and K. Hirao, Phys. Chem. Glasses 38, 66 (1997).

1996

M. Nogami and Y. Abe, Appl. Phys. Lett. 69, 3776 (1996).

K. Hirao, J. Non-Cryst. Solids 196, 16 (1996).

1992

H. Burger, K. Kneipp, H. Hobert, W. Vogel, V. Kozhukharov, and S. Neov, J. Non-Cryst. Solids 151, 134 (1992).

1987

Y. Amemiya, K. Wakabayashi, H. Tanaka, Y. Ueno, and J. Miyahara, Science 237, 164 (1987).

1982

V. P. Gapontsev, S. M. Matisin, A. A. Isineev, and V. B. Kravchenko, Opt. Laser Technol. 14, 189 (1982).

1971

R. A. Hewes and M. V. Hoffman, J. Lumin. 3, 261 (1971).

Abe, Y.

M. Nogami, T. Yamazaki, and Y. Abe, J. Lumin. 78, 63 (1998).

M. Nogami and Y. Abe, Appl. Phys. Lett. 69, 3776 (1996).

Amemiya, Y.

Y. Amemiya, K. Wakabayashi, H. Tanaka, Y. Ueno, and J. Miyahara, Science 237, 164 (1987).

Burger, H.

H. Burger, K. Kneipp, H. Hobert, W. Vogel, V. Kozhukharov, and S. Neov, J. Non-Cryst. Solids 151, 134 (1992).

Gapontsev, V. P.

V. P. Gapontsev, S. M. Matisin, A. A. Isineev, and V. B. Kravchenko, Opt. Laser Technol. 14, 189 (1982).

Hewes, R. A.

R. A. Hewes and M. V. Hoffman, J. Lumin. 3, 261 (1971).

Hirao, K.

J. Qiu, Y. Iwabuchi, and K. Hirao, Phys. Chem. Glasses 38, 66 (1997).

J. R. Qiu, Y. Shimizugawa, Y. Iwabuchi, and K. Hirao, Appl. Phys. Lett. 71, 759 (1997).

K. Hirao, J. Non-Cryst. Solids 196, 16 (1996).

Hobert, H.

H. Burger, K. Kneipp, H. Hobert, W. Vogel, V. Kozhukharov, and S. Neov, J. Non-Cryst. Solids 151, 134 (1992).

Hoffman, M. V.

R. A. Hewes and M. V. Hoffman, J. Lumin. 3, 261 (1971).

Isineev, A. A.

V. P. Gapontsev, S. M. Matisin, A. A. Isineev, and V. B. Kravchenko, Opt. Laser Technol. 14, 189 (1982).

Iwabuchi, Y.

J. R. Qiu, Y. Shimizugawa, Y. Iwabuchi, and K. Hirao, Appl. Phys. Lett. 71, 759 (1997).

J. Qiu, Y. Iwabuchi, and K. Hirao, Phys. Chem. Glasses 38, 66 (1997).

Kneipp, K.

H. Burger, K. Kneipp, H. Hobert, W. Vogel, V. Kozhukharov, and S. Neov, J. Non-Cryst. Solids 151, 134 (1992).

Kozhukharov, V.

H. Burger, K. Kneipp, H. Hobert, W. Vogel, V. Kozhukharov, and S. Neov, J. Non-Cryst. Solids 151, 134 (1992).

Kravchenko, V. B.

V. P. Gapontsev, S. M. Matisin, A. A. Isineev, and V. B. Kravchenko, Opt. Laser Technol. 14, 189 (1982).

Matisin, S. M.

V. P. Gapontsev, S. M. Matisin, A. A. Isineev, and V. B. Kravchenko, Opt. Laser Technol. 14, 189 (1982).

Miyahara, J.

Y. Amemiya, K. Wakabayashi, H. Tanaka, Y. Ueno, and J. Miyahara, Science 237, 164 (1987).

Neov, S.

H. Burger, K. Kneipp, H. Hobert, W. Vogel, V. Kozhukharov, and S. Neov, J. Non-Cryst. Solids 151, 134 (1992).

Nie, Q. H.

H. P. Xia, J. L. Zhang, J. H. Wang, Q. H. Nie, and H. W. Song, Mater. Lett. 53, 277 (2002).

Nogami, M.

M. Nogami, T. Yamazaki, and Y. Abe, J. Lumin. 78, 63 (1998).

M. Nogami and Y. Abe, Appl. Phys. Lett. 69, 3776 (1996).

Qiu, J.

J. Qiu, Y. Iwabuchi, and K. Hirao, Phys. Chem. Glasses 38, 66 (1997).

Qiu, J. R.

J. R. Qiu, Y. Shimizugawa, Y. Iwabuchi, and K. Hirao, Appl. Phys. Lett. 71, 759 (1997).

Shimizugawa, Y.

J. R. Qiu, Y. Shimizugawa, Y. Iwabuchi, and K. Hirao, Appl. Phys. Lett. 71, 759 (1997).

Song, H. W.

H. P. Xia, J. L. Zhang, J. H. Wang, Q. H. Nie, and H. W. Song, Mater. Lett. 53, 277 (2002).

Tanaka, H.

Y. Amemiya, K. Wakabayashi, H. Tanaka, Y. Ueno, and J. Miyahara, Science 237, 164 (1987).

Ueno, Y.

Y. Amemiya, K. Wakabayashi, H. Tanaka, Y. Ueno, and J. Miyahara, Science 237, 164 (1987).

Vogel, W.

H. Burger, K. Kneipp, H. Hobert, W. Vogel, V. Kozhukharov, and S. Neov, J. Non-Cryst. Solids 151, 134 (1992).

Wakabayashi, K.

Y. Amemiya, K. Wakabayashi, H. Tanaka, Y. Ueno, and J. Miyahara, Science 237, 164 (1987).

Wang, J. H.

H. P. Xia, J. L. Zhang, J. H. Wang, Q. H. Nie, and H. W. Song, Mater. Lett. 53, 277 (2002).

Xia, H. P.

H. P. Xia, J. L. Zhang, J. H. Wang, Q. H. Nie, and H. W. Song, Mater. Lett. 53, 277 (2002).

Yamazaki, T.

M. Nogami, T. Yamazaki, and Y. Abe, J. Lumin. 78, 63 (1998).

Zhang, J. L.

H. P. Xia, J. L. Zhang, J. H. Wang, Q. H. Nie, and H. W. Song, Mater. Lett. 53, 277 (2002).

Appl. Phys. Lett.

J. R. Qiu, Y. Shimizugawa, Y. Iwabuchi, and K. Hirao, Appl. Phys. Lett. 71, 759 (1997).

M. Nogami and Y. Abe, Appl. Phys. Lett. 69, 3776 (1996).

J. Lumin.

R. A. Hewes and M. V. Hoffman, J. Lumin. 3, 261 (1971).

M. Nogami, T. Yamazaki, and Y. Abe, J. Lumin. 78, 63 (1998).

J. Non-Cryst. Solids

K. Hirao, J. Non-Cryst. Solids 196, 16 (1996).

H. Burger, K. Kneipp, H. Hobert, W. Vogel, V. Kozhukharov, and S. Neov, J. Non-Cryst. Solids 151, 134 (1992).

Mater. Lett.

H. P. Xia, J. L. Zhang, J. H. Wang, Q. H. Nie, and H. W. Song, Mater. Lett. 53, 277 (2002).

Opt. Laser Technol.

V. P. Gapontsev, S. M. Matisin, A. A. Isineev, and V. B. Kravchenko, Opt. Laser Technol. 14, 189 (1982).

Phys. Chem. Glasses

J. Qiu, Y. Iwabuchi, and K. Hirao, Phys. Chem. Glasses 38, 66 (1997).

Science

Y. Amemiya, K. Wakabayashi, H. Tanaka, Y. Ueno, and J. Miyahara, Science 237, 164 (1987).

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