Abstract

Infrared specular reflection spectra of Z-Tetraol on a gold substrate was simulated and studied experimentally. The simulated spectra were obtained using a classical dispersion analysis coupled with solutions of Maxwell's equations for transmission and reflection of electromagnetic radiation. The simulated spectra, which are based on a randomly oriented sample, provide excellent fits for Z-Tetraol over a wide film thickness range. Spectroscopic data are provided for the Z-Tetraol -(CF<sub>2</sub>O)<sub>p</sub>-(CF<sub>2</sub>CF<sub>2</sub>O)<sub>q</sub>- main chain. The differences in the transverse and longitudinal optical infrared spectra are discussed for off-normal reflection spectra in the thin film limit. Corrections to the infrared reflection spectra for sub-monolayer coverage using effective medium theory are also discussed.

PDF Article

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access OSA Member Subscription