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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 60,
  • Issue 9,
  • pp. 1004-1007
  • (2006)

Using the Kramers–Kronig Method to Determine Optical Constants and Evaluating Its Suitability as a Linear Transform for Near-Normal Front-Surface Reflectance Spectra

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Abstract

In this paper, the suitability of using the Kramers–Kronig transform to routinely extract optical constants from near-normal incidence reflectance spectra of solids and liquids is demonstrated. In addition, the possibility of utilizing the Kramers–Kronig transform as a linearizing transform for near-normal incidence reflectance spectra is investigated. Also, several commercial Kramers–Kronig software packages were utilized in determining the optical constants from the near-normal incidence reflectance of Plexiglas. Unexpectedly, the results produced by the various packages differed significantly. The near-normal reflectance of water was measured, the Kramers–Kronig transform was applied to extract the optical constants of water, and the result was compared to values found in the literature. Furthermore, the Kramers–Kronig transforms of near-normal incidence reflectance spectra of various concentrations of sugar in water were calculated to evaluate its use as a linearizing transform for quantitative applications.

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