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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 57,
  • Issue 6,
  • pp. 655-660
  • (2003)

Silver Clusters onto Nanosized Colloidal Silica as Novel Surface-Enhanced Raman Scattering Active Substrates

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Abstract

A new method is proposed for obtaining surface-enhanced Raman scattering (SERS)-active substrates by photochemical reduction of silver nitrate onto colloidal silica. Transmission electron microscopy (TEM) and UV–visible absorption spectroscopy are employed to investigate the nanoscale structure of the materials. High quality SERS spectra are obtained from different organic ligands to check the efficiency of these substrates. A marked stability of the colloidal suspension is ensured by the scarce tendency of the Ag-doped silica particles to aggregate by either aging or adsorption of ligand.

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