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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 48,
  • Issue 12,
  • pp. 1472-1476
  • (1994)

Examining the Decomposition of Ethylene-Vinyl Acetate Copolymers Using TG/GC/IR

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Abstract

With a combination of information from TG/IR and GC/IR measurements of the trapped gases, characterization of complex polymer decompositions can be made. In this paper, the thermally induced breakdown of ethylene-vinyl acetate (EVA) copolymers was studied. Results show that EVA undergoes a two-step decomposition: an acetate pyrolysis of the copolymer leaving a polyunsaturated linear hydrocarbon, followed by the breakdown of the hydrocarbon backbone to produce a large number of straight-chain hydrocarbon products.

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