Abstract

Infrared (IR) and/or Nuclear Magnetic Resonance (NMR) carbon-13 data are presented for 3-<i>x</i> and 4-<i>x</i> substituted anilines. Correlations are presented for the δ<sup>13</sup>C-1 chemical shift vs. Hammett σ<i><sub>p</sub></i> and <i>σ<sub>m</sub></i> values, ν<sub>asym.</sub>NH<sub>2</sub> vs. δ<sup>13</sup>C-1, ν<sub>sym.</sub>NH<sub>2</sub> vs. δ<sup>13</sup>C-1, δ<sup>13</sup>C-1 vs. ν<sub>asym.</sub>NH<sub>2</sub>, δ<sup>13</sup>C-1 vs. the absorbance ratio A(ν<sub>asym.</sub>NH<sub>2</sub>/<i>A</i>(ν<sub>sym.</sub>NH<sub>2</sub>), and δ<sup>13</sup>C-1 vs. Taft σ<i><sub>R</sub></i>°. The IR data for these compounds are recorded in the vapor phase, and in hexane, carbon tetrachloride, and chloroform solutions. The NMR chemical shift data for these compounds in solution with chloroform were obtained with the use of tetramethylsilane as the δ<sup>13</sup>C resonance reference frequency.

PDF Article

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access OSA Member Subscription