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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 47,
  • Issue 12,
  • pp. 2052-2057
  • (1993)

Theoretical Studies in EDXRF on a New Linear Relation: ln(Fluorescent Intensity Ratio of Analyte to Pure Analyte/Concentration of Analyte) Versus ln(Fluorescent Energy)

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Abstract

The inaccuracies and validity of the approximate linear relation between ln(fluorescent intensity/concentration) and ln(fluorescent energy) are presented and discussed. We then present the derivation of a new linear relation between ln(fluorescent intensity ratio of analyte to pure analyte/ concentration of analyte) and ln(fluorescent energy) which is valid for all elements that can be excited by radiation sources, whether by tube x-ray or by radioisotope sources.

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