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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 46,
  • Issue 12,
  • pp. 1780-1784
  • (1992)

Comparison of Different Calibration Methods Suited for Calibration Problems with Many Variables

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Abstract

This paper describes and compares different kinds of statistical methods proposed in the literature as suited for solving calibration problems with many variables. These are: principal component regression, partial least-squares, and ridge regression. The statistical techniques themselves do not provide robust results in the spirit of calibration equations which can last for long periods. A way of obtaining this property is by smoothing and differentiating the data. These techniques are considered, and it is shown how they fit into the treated description.

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