Abstract
The first demonstration of lifetime resolution in fluorescence-detected circular dichroism (FDCD) is described, performed on a modified phase-modulation spectrofluorometer in which a Babinet-Soleil compensator is used to generate the circularly polarized excitation. Measurements of optically inactive solutions indicate the absence of significant instrumental or optical artifacts for steady-state and lifetime-resolved FDCD. Advantages of the instrumental approach are discussed and early results are presented for a system of benzo(a)pyrene and benzo(k)fluoranthene in γ-cyclodextrin, demonstrating the accuracy of the lifetime determinations with circularly polarized excitation as well as the applicability of lifetime-resolved FDCD for studies of induced chirality in asymmetric microenvironments.
PDF Article
More Like This
Cited By
You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.
Contact your librarian or system administrator
or
Login to access Optica Member Subscription