Abstract
It has been determined that various similarities of some <i>f-f</i> absorption peaks observed in the spectra of <i>f</i>-transition element compounds can be used to elucidate the crystal structure of a given compound. Examples of this interpretation of spectra are presented along with some limitations of the technique. One application of this process leads to further verification of the AlCl<sub>3</sub>-type monoclinic structure of EsBr<sub>3</sub>.
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