Abstract

Hydrogen bonding, dielectric effects, and steric effects are all factors which determine the carbonyl stretching frequency, <i>v</i>C=O, of ketones in solution. The <i>v</i>C=O frequency for ketones shifts continuously at constant concentration in solutions of CHCl<sub>3</sub>/CCl<sub>4</sub> with change in the mole ratio of the two solvents. The <i>v</i>C=O frequency is also affected by change in concentration in either CCl<sub>4</sub> or CHCl<sub>3</sub> solution.

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