Abstract
The interaction of O<sub>2</sub>, H<sub>2</sub>O, and SO<sub>2</sub> on silver powder prepared from the reduction of AgNO<sub>3</sub> by NaBH<sub>4</sub> was studied by surface-enhanced Raman scattering (SERS) at room temperature. The presence of H<sub>2</sub>O of about 10<sup>3</sup> Pa and O<sub>2</sub> of about 10<sup>4</sup>-10<sup>5</sup> Pa was necessary for observation of SERS peaks of SO<sub>3</sub><sup>2-</sup> and SO<sub>4</sub><sup>2-</sup>. The superoxide ion O<sub>2</sub><sup>-</sup> was observed under high partial pressure for O<sub>2</sub> conditions. SERS peaks of atomic oxygen, superoxide ion O<sub>2</sub><sup>-</sup>, SO<sub>3</sub><sup>2-</sup>, and SO<sub>4</sub><sup>2-</sup> disappeared on evacuation. SERS peaks of surface species such as Ag<sub>2</sub>O did not disappear on evacuation.
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