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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 41,
  • Issue 4,
  • pp. 700-702
  • (1987)

Note on the Interpretation of Pt and Pd Values in Vegetation Near the Limit of Determination with a Graphite Furnace Technique

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Abstract

Platinum and palladium uptake by vegetation was reported earlier. Initially, the spectrophotometric method applied to the analysis of Pd in plant ash was affected by errors typical of values near the limit of determination. No appropriate method for Pt was available for these low values. A method published earlier for metallic alloys and ores, which is based on a double extraction of an iodide chelate of Pt and Pd from unfiltered digests into MIBK, was adapted, with some modifications, to ashed vegetation. These modifications consisted of a single extraction; the addition of benzene to the MIBK, to promote a better phase separation; and the use of a smaller volume ratio of solvent to water, to increase the sensitivity of the method. Quantitation was with a graphite furnace analyzer (GFA).

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