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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 39,
  • Issue 6,
  • pp. 1056-1062
  • (1985)

High-Resolution Infrared Spectroscopy Using a Temperature-Controlled Long-Path Absorption Cell: The v3 Band of Uranium Hexafluoride at 16 μm

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Abstract

High-resolution UF<sub>6</sub> absorption spectra at 16 μm have been obtained with the use of tunable diode lasers and a long-pathlength (~10<sup>3</sup>-m) sample cell. The frequencies of the <i>v</i><sub>3</sub> Q-branch subband heads for both <sup>238</sup>UF<sub>6</sub> and <sup>235</sup>UF<sub>6</sub> have been determined, along with those for the (<i>v</i><sub>3</sub> + <i>v</i><sub>6</sub>) − <i>v</i><sub>6</sub> "hot-band" transition. Band contour studies have been carried out as a function of temperature, and comparisons are made with previous work.

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