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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 36,
  • Issue 5,
  • pp. 533-535
  • (1982)

Infrared Group Frequency Data for Diphenoquinones

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Abstract

The 3,3',5,5'-tetraalkyl-4,4'-diphenoquinones exhibit their most intense IR band near 1600 cm<sup>−1</sup>, and is assigned to a complex mode involving out-of-phase (C==O)<sub>2</sub> stretching. A combination tone assigned as in-phase (C==O)<sub>2</sub> stretching and out-of-phase stretching suggests that the frequency separation between the two (C==O)<sub>2</sub> stretching modes is small. Other characteristic group frequencies are also discussed.

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