Abstract
The infrared spectra of CH<sub>3</sub>OPF<sub>2</sub> and CD<sub>3</sub>OPF<sub>2</sub> in the gaseous and solid states and the Raman spectra of the gaseous, liquid, and solid states have been recorded from 3200 to 40 cm<sup>-1</sup>. Seventeen of the 18 normal modes have been assigned through the use of group frequencies, depolarization values, band contours, and frequency shifts with isotopic substitution. The V<sub>3</sub> term of the asymmetric potential function was calculated to have a value of 3.41 kcal/mol from the fundamental and first overtone of the methoxy torsion. The vibrational spectra support a <i>trans</i> conformation for this molecule.
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