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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 33,
  • Issue 6,
  • pp. 578-581
  • (1979)

The Infrared Spectra of Some 1-(2-Thienyl)-3-and -4-Thiaalkanes

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Abstract

The infrared spectra of six 1-(2-thienyl)-3-thiaalkanes and seven 1-(2-thienyl)-4-thiaalkanes (molecular weights from 186 to 270) were obtained for the 4000 to 400 cm<sup>−1</sup> range. These spectra are compared with spectra of other thiophene ring compounds substituted in the 2-position for their characteristic absorption bands. The spectra agree with other spectra as to the major absorption band around 680 cm<sup>−1</sup> and the 2-substitution overtone pattern. A method of distinguishing between the two groups of compounds from moderate peaks in the 600 to 500 cm<sup>−1</sup> (KBr) region is shown. Interference from the 2-alkylthiophenes and the 1-(2-thienyl)-1-thiaalkanes does not occur.

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