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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 33,
  • Issue 4,
  • pp. 399-404
  • (1979)

Hydride Preconcentration for Inductively Coupled Plasma Optical Emission Spectrometry

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Abstract

Studies are presented describing an improved application of the NaBH<sub>4</sub> reduction of soluble arsenite to form arsine as a preconcentration approach for ultra-trace level arsenic determination by inductively coupled plasma optical emission spectrometry. Specialized analyte introduction techniques are described for elimination of reaction by-products that would normally extinguish a medium power plasma discharge. An approach is presented to minimize the need for background correction and facilitate a superior arsenic detection limit (≤0.03 ng/ml) in a relatively inexpensive 1.2 kW inductively coupled plasma system.

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