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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 28,
  • Issue 3,
  • pp. 277-278
  • (1974)

Ligand-Field Transitions in Tetrahedral Tetrabromo-Iron(III) Complex Ions in Molten tetra-n-Butylphosphonium Bromide

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Abstract

The spectrum of iron (III) chloride has been measured in molten metal chlorides and nitrate eutectics. Gruen has suggested a strong absorption band below 25,000 cm<sup>−1</sup> in the latter. In the case of chloride eutectic a strongly absorbing shoulder has been found below 25,000 cm<sup>−1</sup>. These results appear to be inconclusive with regard to the iron-chloride configuration.

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