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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 27,
  • Issue 3,
  • pp. 213-217
  • (1973)

Metal Isotope Effect on Metal-Ligand Vibrations. IX. Far Infrared Spectra of Octahedral Nickel Halide Complexes of Pyridine and γ-Picoline

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Abstract

The far infrared spectra of Ni(pyridine) <sub>4</sub>X<sub>2</sub> and Ni(γ-picoline) <sub>4</sub>X<sub>2</sub> (X = Cl, Br and I) have been measured. The Ni-X and Ni-N stretching bands have been assigned based on isotopic shifts due to the <sup>58</sup>Ni-<sup>62</sup>Ni, pyridine-pyridine-d<sub>5</sub>, and Cl-<sup>37</sup>Cl substitutions.

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