Expand this Topic clickable element to expand a topic
Skip to content
Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 27,
  • Issue 1,
  • pp. 54-55
  • (1973)

A Method for Eliminating Resonance Fluorescence Effects in Raman Studies of Some High Temperature Vapors: Raman Spectra of BiCl3 from 450 to 800°C

Not Accessible

Your library or personal account may give you access

Abstract

The applicability of laser-Raman spectroscopy to the study of structures of gaseous inorganic species at elevated temperatures (to 1000°C) has been demonstrated. Several studies have provided information on thermodynamic quantities, chemical equilibria, and force constants for both pure materials and mixtures. In a number of cases, however, strong resonance fluorescence has obscured the vibrational Raman spectra of the species present. The source of this resonance fluorescence can be either the material under investigation or a species formed through disproportionation of the sample material. An example of the latter case is the resonance fluorescence of BiCl, which overlaps the gas phase Raman scattering of BiCl<sub>3</sub>.

PDF Article
More Like This
Fluorescence-detected Raman-optical double-resonance spectroscopy of glyoxal vapor

A. B. Duval, D. A. King, R. Haines, N. R. Isenor, and B. J. Orr
J. Opt. Soc. Am. B 2(9) 1570-1581 (1985)

On the origin of near-IR luminescence in Bi-doped materials (II). Subvalent monocation Bi+ and cluster Bi53+ luminescence in AlCl3/ZnCl2/BiCl3 chloride glass

Alexey N. Romanov, Zukhra T. Fattakhova, Alexander A. Veber, Olga V. Usovich, Elena V. Haula, Vladimir N. Korchak, Vladimir B. Tsvetkov, Lev A. Trusov, Pavel E. Kazin, and Vladimir B. Sulimov
Opt. Express 20(7) 7212-7220 (2012)

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Select as filters


Select Topics Cancel
© Copyright 2024 | Optica Publishing Group. All Rights Reserved