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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 26,
  • Issue 2,
  • pp. 220-223
  • (1972)

Effects of pH on the C-13 Magnetic Resonance Spectrum of Phenol

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Abstract

The C-13 chemical shift dependences of phenol on <i>p</i>H have been investigated and the shifts interpreted in terms of the phenol–phenoxide equilibrium and hydrogen bonding. In the low and high ranges of <i>p</i>H the carbon shifts have been related to subtle changes in the characteristics of solvent properties. The spectra were obtained using the Fourier transform technique.

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