Expand this Topic clickable element to expand a topic
Skip to content
Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 24,
  • Issue 3,
  • pp. 382-383
  • (1970)

An Inert Infrared Cell for Measuring Quantitative Solution Spectra of Carbonium Ions and Other Reactive Species

Not Accessible

Your library or personal account may give you access

Abstract

During a study of the integrated intensity of the 1600 cm<sup>−1</sup> band of substituted benzenes, we wished to measure solution spectra of some aryl carbonium ions. These ions reacted rapidly with the usual cell window materials so it was necessary to develop an inert cell of uniform and constant path length which allowed accurate and reproducible intensity measurements to be made. We succeeded in this aim with a cell utilizing conventional NaCl windows covered with polytetrafluoroethylene (Teflon) sheeting and separated by a Teflon spacer, with stainless steel injection ports, so that the reactive solution was in contact with only Teflon and stainless steel.

PDF Article
More Like This
Pseudo actinometry for the measurement of reactive species density

Minwook Kang, Yunhyeok Ko, Il-yong Jang, Junhwa Jung, and Jae W. Hahn
Opt. Lett. 42(7) 1420-1423 (2017)

A Vacuum-Tight Infrared Cell for Reactive Liquids

J. L. Mack
Appl. Opt. 5(7) 1235-1236 (1966)

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Select as filters


Select Topics Cancel
© Copyright 2024 | Optica Publishing Group. All Rights Reserved