Abstract

The infrared spectra of CF<sub>3</sub>CH<sub>2</sub>F, CF<sub>3</sub>CH<sub>2</sub>Cl, CF<sub>3</sub>CH<sub>2</sub>Br, and CF<sub>3</sub>CH<sub>2</sub>I in the vapor and solid phase have been obtained, and normal coordinate calculations on the chlorine and bromine molecules have been carried out. From this study it has been possible to correct the previous assignments of vibrational fundamentals for these molecules.

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