Abstract
Fluorine azide was first prepared by Haller as a reaction product of hydrogen azide and fluorine. It is described as a greenish-yellow gas at room temperature, liquefying at −82°C when diluted with nitrogen and freezing to a yellow solid at −143°C. Evaporation of this solid generally results in violent explosion. However, gaseous fluorine azide decomposes slowly at room temperature and very rapidly at 100°C without explosion. Difluorodiazene (N<sub>2</sub>F<sub>2</sub>) and nitrogen are formed.
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