Abstract

The effects of electrode type, are current, and the Stallwood Jet on selective distillation of impurities other than rare earths in La₂O₃ are evaluated. Selective volatilization is reduced by use of a 20-A dc arc with a ⅛-in.-diam electrode. An analytical method incorporating these operating conditions is presented for 19 impurity elements in La₂O₃ prepared from the lanthanum metal sample. The overall precision is about ±14% relative standard deviation over the concentration range of 30 to 1000 parts per million.

The Quantitative Spectrographic Analysis of the Rare Earth Elements*I. Determination of Samarium in NeodymiumII. Determination of Europium in Samarium

Velmer A. Fassel and Harley A. Wilhelm
J. Opt. Soc. Am. 38(6) 518-526 (1948)

A Method of Spectrographic Analysis of Impurities in Materials for Oxide Coating of Thermionic Cathodes*

T. J. Organ and S. L. Parsons
J. Opt. Soc. Am. 38(2) 191-195 (1948)

An Application of Spectrographic Methods to Chemical Concentrations of Trace Elements in Iron and Steel Analysis

R. A. Wolfe and R. G. Fowler
J. Opt. Soc. Am. 35(1) 86-91 (1945)

The Quantitative Spectrographic Analysis of the Rare Earth Elements* III. Determination of Major Constituents in Complex Mixtures

Velmer A. Fassel
J. Opt. Soc. Am. 39(2) 187-193 (1949)

Air-Cooled Electrodes for the Spectrochemical Analysis of Powders*†‡

B. J. Stallwood
J. Opt. Soc. Am. 44(2) 171-176 (1954)