Expand this Topic clickable element to expand a topic
Skip to content
Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 58,
  • Issue 11,
  • pp. 1288-1294
  • (2004)

Study of a Chemically Amplified Resist for X-ray Lithography by Fourier Transform Infrared Spectroscopy

Not Accessible

Your library or personal account may give you access

Abstract

Future applications of microelectromechanical systems (MEMS) require lithographic performance of very high aspect ratio. Chemically amplified resists (CARs) such as the negative tone commercial SU-8 provide critical advantages in sensitivity, resolution, and process efficiency in deep ultraviolet, electron-beam, and X-ray lithographies (XRLs), which result in a very high aspect ratio. In this investigation, an SU-8 resist was characterized and optimized for X-ray lithographic applications by studying the cross-linking process of the resist under different conditions of resist thickness and X-ray exposure dose. The exposure dose of soft X-ray (SXR) irradiation at the average weighted wavelength of 1.20 nm from a plasma focus device ranges from 100 to 1600 mJ/cm<sup>2</sup> on the resist surface. Resist thickness varies from 3.5 to 15 μm. The cross-linking process of the resist during post-exposure bake (PEB) was accurately monitored using Fourier transform infrared (FT-IR) spectroscopy. The infrared absorption peaks at 862, 914, 972, and 1128 cm<sup>-1</sup> in the spectrum of the SU-8 resist were found to be useful indicators for the completion of cross-linking in the resist. Results of the experiments showed that the cross-linking of SU-8 was optimized at the exposure dose of 800 mJ/cm<sup>2</sup> for resist thicknesses of 3.5, 9.5, and 15 μm. PEB temperature was set at 95°C and time at 3 min. The resist thickness was measured using interference patterns in the FT-IR spectra of the resist. Test structures with an aspect ratio 3:1 on 10 μm thick SU-8 resist film were obtained using scanning electron microscopy (SEM).

PDF Article
More Like This
Chemically amplified soft-x-ray resists: sensitivity, resolution, and molecular photodesorption

Glenn D. Kubiak, Robert Q. Hwang, Michelle T. Schulberg, Daniel A. Tichenor, and Kathleen Early
Appl. Opt. 32(34) 7036-7043 (1993)

Characterization of AZ PN114 resist for soft-x-ray projection lithography

K. Early, D. M. Tennant, D. Y. Jeon, P. P. Mulgrew, A. A. MacDowell, O. R. Wood, G. D. Kubiak, and D. A. Tichenor
Appl. Opt. 32(34) 7044-7049 (1993)

Large refractive index changes of a chemically amplified photoresist in femtosecond laser nonlinear lithography

Mizue Mizoshiri, Yoshinori Hirata, Junji Nishii, and Hiroaki Nishiyama
Opt. Express 19(8) 7673-7679 (2011)

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Select as filters


Select Topics Cancel
© Copyright 2024 | Optica Publishing Group. All rights reserved, including rights for text and data mining and training of artificial technologies or similar technologies.