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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 46,
  • Issue 1,
  • pp. 126-130
  • (1992)

New Fiber-Optic-Based Instrumentation for the Measurement of Low-Temperature Phosphorescence Intensities and Lifetimes

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Abstract

New fiber-optic instrumentation for phosphorescence-lifetime determinations and for steady-state phosphorescence measurements is shown to perform comparably to conventional instrumentation. The importance of optimal glass formation in the fiber-optic sample cell is considered in some detail. Detection limits for acetophenone, benzophenone, and <i>p</i>-nitrophenol are reported, and phosphorescence lifetimes are measured for several compounds, with values ranging from 2.5 ms to 4.7 s.

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