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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 43,
  • Issue 7,
  • pp. 1168-1172
  • (1989)

Simultaneous Detection of Optical Isomers and the Separation of Overlapping Resonances in a 1H NMR Spectrum of (+/-)-2,2-Dimethyl-1-Phenyl-1-Propanol Using an NMR Shift Reagent

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Abstract

The enantiomer separation and the spectral simplification of overlapped resonances in a high-resolution <sup>1</sup>H NMR spectrum of a model compound have been successfully accomplished with the use of paramagnetic shift reagent. Both <sup>1</sup>H and <sup>13</sup>C NMR have been applied to determine the composition of a mixture containing optically active enantiomers of (+/-)-2,2-dimethyl-1-phenyl-1-propanol.

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