Abstract

Unwanted effects can be generated in photoelectron spectra by minority emissions which commonly appear in rare gas sources of resonance line uv radiation. Such emissions probably account for certain observed states of both NO+ and Hg+. Tables of spectra from several sources are given, and useful spectral cleanup is demonstrated with zeolite gas trapping.

© 1970 Optical Society of America

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References

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  1. J. A. R. Samson, Techniques of Vacuum Ultraviolet Spectroscopy, (John Wiley & Sons, Inc., New York, 1967), p. 137.
  2. D. C. Frost, C. A. McDowell, D. A. Vroom, Chem. Phys. Lett. (Netherlands) 1, 93 (1967).
    [CrossRef]
  3. J. E. Collin, P. Natalis, Chem. Phys. Lett. (Netherlands) 2, 194 (1968).
    [CrossRef]
  4. D. C. Frost, Proc. Fifth Intern. Conf. Phys. Electronic and Atomic Collisions, Leningrad (1967). Although reference has been made to this value of 14.84 eV,3 Frost has pointed out to us in private communication that subsequent experiments in his laboratory have cast doubt upon its validity and have caused him to refrain from submitting a report of the work to a journal.
  5. Y. Tanaka, Sci. Papers Inst. Phys. Chem. Res. (Tokyo) 39, 456 (1942).
  6. K. P. Huber, Helv. Phys. Acta 34, 929 (1961).
  7. P. Mitchell, M. Wilson, Chem. Phys. Lett. (Netherlands) 3, 389 (1969).
    [CrossRef]
  8. F. Herman, S. Skillman, Atomic Structure Calculations, (Prentice Hall, Inc., Englewood Cliffs, N.J., 1963).
  9. D. W. Turner, D. P. May, J. Chem. Phys. 45, 471 (1966); see also M. I. Al-Joboury, D. P. May, D. W. Turner, J. Chem. Soc. 616 (1965).
    [CrossRef]
  10. R. I. Schoen, P. H. Doolittle, presented at The 13th Annual Conference on Mass Spectroscopy and Allied Topics, St. Louis (1965).
  11. J. A. R. Samson, Phys. Lett. 28A, 391 (1968).
  12. Sjorgren, I. Szabo, Arkiv Fysik 37, 551 (1968).
  13. K. P. Huber, Can. J. Phys. 46, 1691 (1968).
    [CrossRef]
  14. H. Sun, G. L. Weissler, J. Chem. Phys. 23, 1372 (1955).
    [CrossRef]
  15. K. Watanabe, M. Matsunaga, H. Sakai, Appl. Opt. 6, 391 (1967).
    [CrossRef] [PubMed]
  16. A. D. Baker, C. R. Brundle, D. W. Turner, J. Mass Spectrom. Ion Phys. 1, 443 (1968).
    [CrossRef]

1969 (1)

P. Mitchell, M. Wilson, Chem. Phys. Lett. (Netherlands) 3, 389 (1969).
[CrossRef]

1968 (5)

A. D. Baker, C. R. Brundle, D. W. Turner, J. Mass Spectrom. Ion Phys. 1, 443 (1968).
[CrossRef]

J. E. Collin, P. Natalis, Chem. Phys. Lett. (Netherlands) 2, 194 (1968).
[CrossRef]

J. A. R. Samson, Phys. Lett. 28A, 391 (1968).

Sjorgren, I. Szabo, Arkiv Fysik 37, 551 (1968).

K. P. Huber, Can. J. Phys. 46, 1691 (1968).
[CrossRef]

1967 (2)

D. C. Frost, C. A. McDowell, D. A. Vroom, Chem. Phys. Lett. (Netherlands) 1, 93 (1967).
[CrossRef]

K. Watanabe, M. Matsunaga, H. Sakai, Appl. Opt. 6, 391 (1967).
[CrossRef] [PubMed]

1966 (1)

D. W. Turner, D. P. May, J. Chem. Phys. 45, 471 (1966); see also M. I. Al-Joboury, D. P. May, D. W. Turner, J. Chem. Soc. 616 (1965).
[CrossRef]

1961 (1)

K. P. Huber, Helv. Phys. Acta 34, 929 (1961).

1955 (1)

H. Sun, G. L. Weissler, J. Chem. Phys. 23, 1372 (1955).
[CrossRef]

1942 (1)

Y. Tanaka, Sci. Papers Inst. Phys. Chem. Res. (Tokyo) 39, 456 (1942).

Baker, A. D.

A. D. Baker, C. R. Brundle, D. W. Turner, J. Mass Spectrom. Ion Phys. 1, 443 (1968).
[CrossRef]

Brundle, C. R.

A. D. Baker, C. R. Brundle, D. W. Turner, J. Mass Spectrom. Ion Phys. 1, 443 (1968).
[CrossRef]

Collin, J. E.

J. E. Collin, P. Natalis, Chem. Phys. Lett. (Netherlands) 2, 194 (1968).
[CrossRef]

Doolittle, P. H.

R. I. Schoen, P. H. Doolittle, presented at The 13th Annual Conference on Mass Spectroscopy and Allied Topics, St. Louis (1965).

Frost, D. C.

D. C. Frost, C. A. McDowell, D. A. Vroom, Chem. Phys. Lett. (Netherlands) 1, 93 (1967).
[CrossRef]

D. C. Frost, Proc. Fifth Intern. Conf. Phys. Electronic and Atomic Collisions, Leningrad (1967). Although reference has been made to this value of 14.84 eV,3 Frost has pointed out to us in private communication that subsequent experiments in his laboratory have cast doubt upon its validity and have caused him to refrain from submitting a report of the work to a journal.

Herman, F.

F. Herman, S. Skillman, Atomic Structure Calculations, (Prentice Hall, Inc., Englewood Cliffs, N.J., 1963).

Huber, K. P.

K. P. Huber, Can. J. Phys. 46, 1691 (1968).
[CrossRef]

K. P. Huber, Helv. Phys. Acta 34, 929 (1961).

Matsunaga, M.

May, D. P.

D. W. Turner, D. P. May, J. Chem. Phys. 45, 471 (1966); see also M. I. Al-Joboury, D. P. May, D. W. Turner, J. Chem. Soc. 616 (1965).
[CrossRef]

McDowell, C. A.

D. C. Frost, C. A. McDowell, D. A. Vroom, Chem. Phys. Lett. (Netherlands) 1, 93 (1967).
[CrossRef]

Mitchell, P.

P. Mitchell, M. Wilson, Chem. Phys. Lett. (Netherlands) 3, 389 (1969).
[CrossRef]

Natalis, P.

J. E. Collin, P. Natalis, Chem. Phys. Lett. (Netherlands) 2, 194 (1968).
[CrossRef]

Sakai, H.

Samson, J. A. R.

J. A. R. Samson, Phys. Lett. 28A, 391 (1968).

J. A. R. Samson, Techniques of Vacuum Ultraviolet Spectroscopy, (John Wiley & Sons, Inc., New York, 1967), p. 137.

Schoen, R. I.

R. I. Schoen, P. H. Doolittle, presented at The 13th Annual Conference on Mass Spectroscopy and Allied Topics, St. Louis (1965).

Sjorgren,

Sjorgren, I. Szabo, Arkiv Fysik 37, 551 (1968).

Skillman, S.

F. Herman, S. Skillman, Atomic Structure Calculations, (Prentice Hall, Inc., Englewood Cliffs, N.J., 1963).

Sun, H.

H. Sun, G. L. Weissler, J. Chem. Phys. 23, 1372 (1955).
[CrossRef]

Szabo, I.

Sjorgren, I. Szabo, Arkiv Fysik 37, 551 (1968).

Tanaka, Y.

Y. Tanaka, Sci. Papers Inst. Phys. Chem. Res. (Tokyo) 39, 456 (1942).

Turner, D. W.

A. D. Baker, C. R. Brundle, D. W. Turner, J. Mass Spectrom. Ion Phys. 1, 443 (1968).
[CrossRef]

D. W. Turner, D. P. May, J. Chem. Phys. 45, 471 (1966); see also M. I. Al-Joboury, D. P. May, D. W. Turner, J. Chem. Soc. 616 (1965).
[CrossRef]

Vroom, D. A.

D. C. Frost, C. A. McDowell, D. A. Vroom, Chem. Phys. Lett. (Netherlands) 1, 93 (1967).
[CrossRef]

Watanabe, K.

Weissler, G. L.

H. Sun, G. L. Weissler, J. Chem. Phys. 23, 1372 (1955).
[CrossRef]

Wilson, M.

P. Mitchell, M. Wilson, Chem. Phys. Lett. (Netherlands) 3, 389 (1969).
[CrossRef]

Appl. Opt. (1)

Arkiv Fysik (1)

Sjorgren, I. Szabo, Arkiv Fysik 37, 551 (1968).

Can. J. Phys. (1)

K. P. Huber, Can. J. Phys. 46, 1691 (1968).
[CrossRef]

Chem. Phys. Lett. (Netherlands) (3)

D. C. Frost, C. A. McDowell, D. A. Vroom, Chem. Phys. Lett. (Netherlands) 1, 93 (1967).
[CrossRef]

J. E. Collin, P. Natalis, Chem. Phys. Lett. (Netherlands) 2, 194 (1968).
[CrossRef]

P. Mitchell, M. Wilson, Chem. Phys. Lett. (Netherlands) 3, 389 (1969).
[CrossRef]

Helv. Phys. Acta (1)

K. P. Huber, Helv. Phys. Acta 34, 929 (1961).

J. Chem. Phys. (2)

H. Sun, G. L. Weissler, J. Chem. Phys. 23, 1372 (1955).
[CrossRef]

D. W. Turner, D. P. May, J. Chem. Phys. 45, 471 (1966); see also M. I. Al-Joboury, D. P. May, D. W. Turner, J. Chem. Soc. 616 (1965).
[CrossRef]

J. Mass Spectrom. Ion Phys. (1)

A. D. Baker, C. R. Brundle, D. W. Turner, J. Mass Spectrom. Ion Phys. 1, 443 (1968).
[CrossRef]

Phys. Lett. (1)

J. A. R. Samson, Phys. Lett. 28A, 391 (1968).

Sci. Papers Inst. Phys. Chem. Res. (Tokyo) (1)

Y. Tanaka, Sci. Papers Inst. Phys. Chem. Res. (Tokyo) 39, 456 (1942).

Other (4)

J. A. R. Samson, Techniques of Vacuum Ultraviolet Spectroscopy, (John Wiley & Sons, Inc., New York, 1967), p. 137.

D. C. Frost, Proc. Fifth Intern. Conf. Phys. Electronic and Atomic Collisions, Leningrad (1967). Although reference has been made to this value of 14.84 eV,3 Frost has pointed out to us in private communication that subsequent experiments in his laboratory have cast doubt upon its validity and have caused him to refrain from submitting a report of the work to a journal.

R. I. Schoen, P. H. Doolittle, presented at The 13th Annual Conference on Mass Spectroscopy and Allied Topics, St. Louis (1965).

F. Herman, S. Skillman, Atomic Structure Calculations, (Prentice Hall, Inc., Englewood Cliffs, N.J., 1963).

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Figures (1)

Fig. 1
Fig. 1

(a) An integrated photoelectron spectrum of nitric oxide in which only 584 Å radiation was present. (b) A synthetic curve representing the manner in which (a) would be modified by undispersed impurity emissions from a helium source. Note that (b) has an expanded ordinate scale. The abscissa unit is in terms of (21.21 eV minus the photoelectron retarding voltage V).

Tables (1)

Tables Icon

Table I Spectra of Some dc Resonace Lampsa

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