Abstract

Three novel binary Tb(III) complexes (TbL2, TbL, and Tb2L; L=3,3,4,4-biphenyl tetracarboxylic ligand) were synthesized by changing the molar ratio of Tb(III) to 3,3,4,4-biphthalic anhydride (BPDA) (12, 11, and 21, respectively). IR spectra indicate that there are two coordination modes of the carboxylate ligands with Tb3+ ions in the complexes. Most of them are in bridging mode; the others are in chelating mode. These complexes all have good thermal stability. The photophysical properties of these complexes are studied in detail using UV absorption spectra, fluorescence spectra, and transient fluorescence spectra. The results indicate that the photoluminescence properties of the complexes depend strongly on the molar ratio of Tb(III) to BPDA. When the molar ratio of Tb(III) to BPDA is 11, complex TbL exhibits the strongest yellow light emission among the three Tb(III) complexes. However, complex Tb2L exhibits a weaker yellowish-green light emission when the molar ratio of Tb(III) to BPDA is 21. The phenomenon of the yellow emission from terbium complexes is rarely reported.

© 2014 Optical Society of America

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  2. H. A. Azab, S. A. El-Korashy, Z. M. Anwar, B. H. Hussein, and G. M. Khairy, “Synthesis and fluorescence properties of Eu-anthracene-9-carboxylic acid towards N-acetyl amino acids and nucleotides in different solvents,” Spectrochim. Acta A 75, 21–27 (2010).
    [CrossRef]
  3. S. G. Gouin, M. Roger, N. Leygue, D. Deniaud, K. Julienne, E. Benoist, C. Picard, J. Kovensky, and C. Galaup, “Lanthanide(III) complexes of pyridine-tetraacetic acid-glycoconjugates: synthesis and luminescence studies of mono and divalent derivatives,” Bioorg. Med. Chem. Lett. 22, 2684–2688 (2012).
    [CrossRef]
  4. C. Marchal, Y. Filinchuk, X. Y. Chen, D. Imbert, and M. Mazzanti, “Lanthanide-based coordination polymers assembled by a flexible multidentate linker: design, structure, photophysical properties, and dynamic solid-state behavior,” Chemistry 15, 5273–5288 (2009).
    [CrossRef]
  5. E. S. Andreiadis, R. Demadrille, D. Imbert, J. Pecaut, and M. Mazzanti, “Remarkable tuning of the coordination and photophysical properties of lanthanide ions in a series of tetrazole-based complexes,” Chem. Eur. J. 15, 9458–9476 (2009).
    [CrossRef]
  6. B. J. Gao, W. Zhang, Z. G. Zhang, and Q. J. Lei, “Preparation of polymer–rare earth complex using salicylic acid-containing polystyrene and its fluorescence emission property,” J. Lumin. 132, 2005–2011 (2012).
    [CrossRef]
  7. T. Wu, J. Gao, J. Wang, S. Wang, Y. Bai, Y. Li, K. Li, and X. Zhang, “Synthesis, structural determination and spectroscopic analysis of a novel 2D terbium coordination network with ethyleneglycol-bis-(2-aminoethylether)-N,N,N′,N′-tetraacetic acid,” Spectrochim. Acta A 86, 1–7 (2012).
    [CrossRef]
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    [CrossRef]
  9. H. G. Yan, H. H. Wang, P. He, J. X. Shi, and M. L. Gong, “An efficient bonding-type Eu- containing copolymer as red phosphor applied in LED,” Inorg. Chem. Commun. 14, 1065–1068 (2011).
    [CrossRef]
  10. L. M. Zhang, B. Li, S. M. Yue, M. T. Li, Z. R. Hong, and W. L. Li, “A terbium (III) complex with triphenylamine-functionalized ligand for organic electroluminescent device,” J. Lumin. 128, 620–624 (2008).
    [CrossRef]
  11. X. L. Wang, L. C. Li, and D. Z. Liao, “Slow magnetic relaxation in lanthanide complexes with chelating nitronyl nitroxide radical,” Inorg. Chem. 49, 4735–4737 (2010).
    [CrossRef]
  12. B. Yan, C. Sheng, and L. Guo, “Lanthanide (Eu3+, Tb3+, Gd3+) hybrid system with functionalized diethylenetriamine pentaacetic acid: coordination bonding assembly, luminescence and MRI contrast agent property,” Inorg. Chem. Commun. 18, 43–46 (2012).
    [CrossRef]
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    [CrossRef]
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    [CrossRef]
  16. Y. X. Zhou, X. Q. Shen, C. X. Du, B. L. Wu, and H. Y. Zhang, “1d, 2d and 3d coordination polymers of aromatic carboxylate TbIII: structure, thermolysis kinetics and fluorescence,” Eur. J. Inorg. Chem. 2008, 4280–4289 (2008).
    [CrossRef]
  17. M. Tabatabaee, M. A. Sharif, F. Vakili, and S. Saheli, “Hydrothermal synthesis and structural studies of a new coordination polymer of lanthanum(III) with benzene-1,2,4,5-tetracarboxylic acid and 4,4′-bipyridine,” J. Rare Earths 27, 356–361 (2009).
    [CrossRef]
  18. X. Zhao, X. Y. Yu, T. L. Chen, Y. H. Luo, J. J. Yang, and H. Zhang, “A series of lanthanide compounds based on mixed aromatic carboxylate ligands: syntheses, crystal structures and luminescent properties,” Inorg. Chem. Commun. 20, 247–251 (2012).
    [CrossRef]
  19. J. Jia, M. Shao, T. T. Jia, S. R. Zhu, Y. M. Zhao, F. F. Xing, and M. X. Li, “Coordination polymers of biphenyl-2,4,2′,4′-tetracarboxylic acid—synthesis, structures and adsorption properties,” CrystEngComm. 12, 1548–1561 (2010).
    [CrossRef]
  20. L. Ma, Y. C. Qiu, G. Peng, J. B. Cai, H. Deng, and M. Zeller, “Self-assembly of d–f coordination frameworks based on 1H-benzimidazole-5-carboxylic acid: synthesis, structure and luminescence,” CrystEngComm. 13, 3852–3861 (2011).
    [CrossRef]
  21. P. Mahata, K. V. Ramya, and S. Natarajan, “Synthesis, structure and optical properties of rare-earth benzene carboxylates,” Dalton Trans. 36, 4017–4026 (2007).
    [CrossRef]
  22. R. Koner and I. Goldberg, “The first coordination polymer of lanthanum(III) with a naphthalene -1,4,5,8-tetracarboxylic 1,8-anhydride derivative,” Acta Crystallogr. Sect. C 64, m264–m266 (2008).
    [CrossRef]

2012 (7)

S. G. Gouin, M. Roger, N. Leygue, D. Deniaud, K. Julienne, E. Benoist, C. Picard, J. Kovensky, and C. Galaup, “Lanthanide(III) complexes of pyridine-tetraacetic acid-glycoconjugates: synthesis and luminescence studies of mono and divalent derivatives,” Bioorg. Med. Chem. Lett. 22, 2684–2688 (2012).
[CrossRef]

B. J. Gao, W. Zhang, Z. G. Zhang, and Q. J. Lei, “Preparation of polymer–rare earth complex using salicylic acid-containing polystyrene and its fluorescence emission property,” J. Lumin. 132, 2005–2011 (2012).
[CrossRef]

T. Wu, J. Gao, J. Wang, S. Wang, Y. Bai, Y. Li, K. Li, and X. Zhang, “Synthesis, structural determination and spectroscopic analysis of a novel 2D terbium coordination network with ethyleneglycol-bis-(2-aminoethylether)-N,N,N′,N′-tetraacetic acid,” Spectrochim. Acta A 86, 1–7 (2012).
[CrossRef]

M. Pietraszkiewicz, S. Mal, and O. Pietraszkiewicz, “Novel, highly photoluminescent Eu(III) and Tb(III) tetrazolate-2-pyridine-1-oxide complexes,” Opt. Mater. 34, 1507–1512 (2012).
[CrossRef]

B. Yan, C. Sheng, and L. Guo, “Lanthanide (Eu3+, Tb3+, Gd3+) hybrid system with functionalized diethylenetriamine pentaacetic acid: coordination bonding assembly, luminescence and MRI contrast agent property,” Inorg. Chem. Commun. 18, 43–46 (2012).
[CrossRef]

M. Xu, Y. C. Zhang, Z. H. Xu, and Z. Z. Zeng, “Crystal structure, biological studies of water-soluble rare earth metal complexes with an ofloxacin derivative,” Inorg. Chem. Commun. 384, 324–332 (2012).
[CrossRef]

X. Zhao, X. Y. Yu, T. L. Chen, Y. H. Luo, J. J. Yang, and H. Zhang, “A series of lanthanide compounds based on mixed aromatic carboxylate ligands: syntheses, crystal structures and luminescent properties,” Inorg. Chem. Commun. 20, 247–251 (2012).
[CrossRef]

2011 (3)

M. Hilder, M. Lezhnina, M. L. Cole, C. M. Forsyth, P. C. Junk, and U. H. Kynast, “Spectroscopic properties of lanthanoid benzene carboxylates in the solid state: part 2. polar substituted benzoates,” J. Photochem. Photobiol., A 217, 76–86 (2011).
[CrossRef]

H. G. Yan, H. H. Wang, P. He, J. X. Shi, and M. L. Gong, “An efficient bonding-type Eu- containing copolymer as red phosphor applied in LED,” Inorg. Chem. Commun. 14, 1065–1068 (2011).
[CrossRef]

L. Ma, Y. C. Qiu, G. Peng, J. B. Cai, H. Deng, and M. Zeller, “Self-assembly of d–f coordination frameworks based on 1H-benzimidazole-5-carboxylic acid: synthesis, structure and luminescence,” CrystEngComm. 13, 3852–3861 (2011).
[CrossRef]

2010 (3)

H. A. Azab, S. A. El-Korashy, Z. M. Anwar, B. H. Hussein, and G. M. Khairy, “Synthesis and fluorescence properties of Eu-anthracene-9-carboxylic acid towards N-acetyl amino acids and nucleotides in different solvents,” Spectrochim. Acta A 75, 21–27 (2010).
[CrossRef]

J. Jia, M. Shao, T. T. Jia, S. R. Zhu, Y. M. Zhao, F. F. Xing, and M. X. Li, “Coordination polymers of biphenyl-2,4,2′,4′-tetracarboxylic acid—synthesis, structures and adsorption properties,” CrystEngComm. 12, 1548–1561 (2010).
[CrossRef]

X. L. Wang, L. C. Li, and D. Z. Liao, “Slow magnetic relaxation in lanthanide complexes with chelating nitronyl nitroxide radical,” Inorg. Chem. 49, 4735–4737 (2010).
[CrossRef]

2009 (3)

C. Marchal, Y. Filinchuk, X. Y. Chen, D. Imbert, and M. Mazzanti, “Lanthanide-based coordination polymers assembled by a flexible multidentate linker: design, structure, photophysical properties, and dynamic solid-state behavior,” Chemistry 15, 5273–5288 (2009).
[CrossRef]

E. S. Andreiadis, R. Demadrille, D. Imbert, J. Pecaut, and M. Mazzanti, “Remarkable tuning of the coordination and photophysical properties of lanthanide ions in a series of tetrazole-based complexes,” Chem. Eur. J. 15, 9458–9476 (2009).
[CrossRef]

M. Tabatabaee, M. A. Sharif, F. Vakili, and S. Saheli, “Hydrothermal synthesis and structural studies of a new coordination polymer of lanthanum(III) with benzene-1,2,4,5-tetracarboxylic acid and 4,4′-bipyridine,” J. Rare Earths 27, 356–361 (2009).
[CrossRef]

2008 (3)

R. Koner and I. Goldberg, “The first coordination polymer of lanthanum(III) with a naphthalene -1,4,5,8-tetracarboxylic 1,8-anhydride derivative,” Acta Crystallogr. Sect. C 64, m264–m266 (2008).
[CrossRef]

L. M. Zhang, B. Li, S. M. Yue, M. T. Li, Z. R. Hong, and W. L. Li, “A terbium (III) complex with triphenylamine-functionalized ligand for organic electroluminescent device,” J. Lumin. 128, 620–624 (2008).
[CrossRef]

Y. X. Zhou, X. Q. Shen, C. X. Du, B. L. Wu, and H. Y. Zhang, “1d, 2d and 3d coordination polymers of aromatic carboxylate TbIII: structure, thermolysis kinetics and fluorescence,” Eur. J. Inorg. Chem. 2008, 4280–4289 (2008).
[CrossRef]

2007 (2)

B. Yan, W. Wang, and Y. Song, “Photophysical properties of praseodymium complexes with aromatic carboxylic acids: double light conversion both in ultraviolet and visible region,” Spectrochim. Acta A 66, 1115–1121 (2007).
[CrossRef]

P. Mahata, K. V. Ramya, and S. Natarajan, “Synthesis, structure and optical properties of rare-earth benzene carboxylates,” Dalton Trans. 36, 4017–4026 (2007).
[CrossRef]

1942 (1)

S. I. Weissman, “Intramolecular energy transfer the fluorescence of complexes of europium,” J. Chem. Phys. 10, 214–217 (1942).
[CrossRef]

Andreiadis, E. S.

E. S. Andreiadis, R. Demadrille, D. Imbert, J. Pecaut, and M. Mazzanti, “Remarkable tuning of the coordination and photophysical properties of lanthanide ions in a series of tetrazole-based complexes,” Chem. Eur. J. 15, 9458–9476 (2009).
[CrossRef]

Anwar, Z. M.

H. A. Azab, S. A. El-Korashy, Z. M. Anwar, B. H. Hussein, and G. M. Khairy, “Synthesis and fluorescence properties of Eu-anthracene-9-carboxylic acid towards N-acetyl amino acids and nucleotides in different solvents,” Spectrochim. Acta A 75, 21–27 (2010).
[CrossRef]

Azab, H. A.

H. A. Azab, S. A. El-Korashy, Z. M. Anwar, B. H. Hussein, and G. M. Khairy, “Synthesis and fluorescence properties of Eu-anthracene-9-carboxylic acid towards N-acetyl amino acids and nucleotides in different solvents,” Spectrochim. Acta A 75, 21–27 (2010).
[CrossRef]

Bai, Y.

T. Wu, J. Gao, J. Wang, S. Wang, Y. Bai, Y. Li, K. Li, and X. Zhang, “Synthesis, structural determination and spectroscopic analysis of a novel 2D terbium coordination network with ethyleneglycol-bis-(2-aminoethylether)-N,N,N′,N′-tetraacetic acid,” Spectrochim. Acta A 86, 1–7 (2012).
[CrossRef]

Benoist, E.

S. G. Gouin, M. Roger, N. Leygue, D. Deniaud, K. Julienne, E. Benoist, C. Picard, J. Kovensky, and C. Galaup, “Lanthanide(III) complexes of pyridine-tetraacetic acid-glycoconjugates: synthesis and luminescence studies of mono and divalent derivatives,” Bioorg. Med. Chem. Lett. 22, 2684–2688 (2012).
[CrossRef]

Cai, J. B.

L. Ma, Y. C. Qiu, G. Peng, J. B. Cai, H. Deng, and M. Zeller, “Self-assembly of d–f coordination frameworks based on 1H-benzimidazole-5-carboxylic acid: synthesis, structure and luminescence,” CrystEngComm. 13, 3852–3861 (2011).
[CrossRef]

Chen, T. L.

X. Zhao, X. Y. Yu, T. L. Chen, Y. H. Luo, J. J. Yang, and H. Zhang, “A series of lanthanide compounds based on mixed aromatic carboxylate ligands: syntheses, crystal structures and luminescent properties,” Inorg. Chem. Commun. 20, 247–251 (2012).
[CrossRef]

Chen, X. Y.

C. Marchal, Y. Filinchuk, X. Y. Chen, D. Imbert, and M. Mazzanti, “Lanthanide-based coordination polymers assembled by a flexible multidentate linker: design, structure, photophysical properties, and dynamic solid-state behavior,” Chemistry 15, 5273–5288 (2009).
[CrossRef]

Cole, M. L.

M. Hilder, M. Lezhnina, M. L. Cole, C. M. Forsyth, P. C. Junk, and U. H. Kynast, “Spectroscopic properties of lanthanoid benzene carboxylates in the solid state: part 2. polar substituted benzoates,” J. Photochem. Photobiol., A 217, 76–86 (2011).
[CrossRef]

Demadrille, R.

E. S. Andreiadis, R. Demadrille, D. Imbert, J. Pecaut, and M. Mazzanti, “Remarkable tuning of the coordination and photophysical properties of lanthanide ions in a series of tetrazole-based complexes,” Chem. Eur. J. 15, 9458–9476 (2009).
[CrossRef]

Deng, H.

L. Ma, Y. C. Qiu, G. Peng, J. B. Cai, H. Deng, and M. Zeller, “Self-assembly of d–f coordination frameworks based on 1H-benzimidazole-5-carboxylic acid: synthesis, structure and luminescence,” CrystEngComm. 13, 3852–3861 (2011).
[CrossRef]

Deniaud, D.

S. G. Gouin, M. Roger, N. Leygue, D. Deniaud, K. Julienne, E. Benoist, C. Picard, J. Kovensky, and C. Galaup, “Lanthanide(III) complexes of pyridine-tetraacetic acid-glycoconjugates: synthesis and luminescence studies of mono and divalent derivatives,” Bioorg. Med. Chem. Lett. 22, 2684–2688 (2012).
[CrossRef]

Du, C. X.

Y. X. Zhou, X. Q. Shen, C. X. Du, B. L. Wu, and H. Y. Zhang, “1d, 2d and 3d coordination polymers of aromatic carboxylate TbIII: structure, thermolysis kinetics and fluorescence,” Eur. J. Inorg. Chem. 2008, 4280–4289 (2008).
[CrossRef]

El-Korashy, S. A.

H. A. Azab, S. A. El-Korashy, Z. M. Anwar, B. H. Hussein, and G. M. Khairy, “Synthesis and fluorescence properties of Eu-anthracene-9-carboxylic acid towards N-acetyl amino acids and nucleotides in different solvents,” Spectrochim. Acta A 75, 21–27 (2010).
[CrossRef]

Filinchuk, Y.

C. Marchal, Y. Filinchuk, X. Y. Chen, D. Imbert, and M. Mazzanti, “Lanthanide-based coordination polymers assembled by a flexible multidentate linker: design, structure, photophysical properties, and dynamic solid-state behavior,” Chemistry 15, 5273–5288 (2009).
[CrossRef]

Forsyth, C. M.

M. Hilder, M. Lezhnina, M. L. Cole, C. M. Forsyth, P. C. Junk, and U. H. Kynast, “Spectroscopic properties of lanthanoid benzene carboxylates in the solid state: part 2. polar substituted benzoates,” J. Photochem. Photobiol., A 217, 76–86 (2011).
[CrossRef]

Galaup, C.

S. G. Gouin, M. Roger, N. Leygue, D. Deniaud, K. Julienne, E. Benoist, C. Picard, J. Kovensky, and C. Galaup, “Lanthanide(III) complexes of pyridine-tetraacetic acid-glycoconjugates: synthesis and luminescence studies of mono and divalent derivatives,” Bioorg. Med. Chem. Lett. 22, 2684–2688 (2012).
[CrossRef]

Gao, B. J.

B. J. Gao, W. Zhang, Z. G. Zhang, and Q. J. Lei, “Preparation of polymer–rare earth complex using salicylic acid-containing polystyrene and its fluorescence emission property,” J. Lumin. 132, 2005–2011 (2012).
[CrossRef]

Gao, J.

T. Wu, J. Gao, J. Wang, S. Wang, Y. Bai, Y. Li, K. Li, and X. Zhang, “Synthesis, structural determination and spectroscopic analysis of a novel 2D terbium coordination network with ethyleneglycol-bis-(2-aminoethylether)-N,N,N′,N′-tetraacetic acid,” Spectrochim. Acta A 86, 1–7 (2012).
[CrossRef]

Goldberg, I.

R. Koner and I. Goldberg, “The first coordination polymer of lanthanum(III) with a naphthalene -1,4,5,8-tetracarboxylic 1,8-anhydride derivative,” Acta Crystallogr. Sect. C 64, m264–m266 (2008).
[CrossRef]

Gong, M. L.

H. G. Yan, H. H. Wang, P. He, J. X. Shi, and M. L. Gong, “An efficient bonding-type Eu- containing copolymer as red phosphor applied in LED,” Inorg. Chem. Commun. 14, 1065–1068 (2011).
[CrossRef]

Gouin, S. G.

S. G. Gouin, M. Roger, N. Leygue, D. Deniaud, K. Julienne, E. Benoist, C. Picard, J. Kovensky, and C. Galaup, “Lanthanide(III) complexes of pyridine-tetraacetic acid-glycoconjugates: synthesis and luminescence studies of mono and divalent derivatives,” Bioorg. Med. Chem. Lett. 22, 2684–2688 (2012).
[CrossRef]

Guo, L.

B. Yan, C. Sheng, and L. Guo, “Lanthanide (Eu3+, Tb3+, Gd3+) hybrid system with functionalized diethylenetriamine pentaacetic acid: coordination bonding assembly, luminescence and MRI contrast agent property,” Inorg. Chem. Commun. 18, 43–46 (2012).
[CrossRef]

He, P.

H. G. Yan, H. H. Wang, P. He, J. X. Shi, and M. L. Gong, “An efficient bonding-type Eu- containing copolymer as red phosphor applied in LED,” Inorg. Chem. Commun. 14, 1065–1068 (2011).
[CrossRef]

Hilder, M.

M. Hilder, M. Lezhnina, M. L. Cole, C. M. Forsyth, P. C. Junk, and U. H. Kynast, “Spectroscopic properties of lanthanoid benzene carboxylates in the solid state: part 2. polar substituted benzoates,” J. Photochem. Photobiol., A 217, 76–86 (2011).
[CrossRef]

Hong, Z. R.

L. M. Zhang, B. Li, S. M. Yue, M. T. Li, Z. R. Hong, and W. L. Li, “A terbium (III) complex with triphenylamine-functionalized ligand for organic electroluminescent device,” J. Lumin. 128, 620–624 (2008).
[CrossRef]

Hussein, B. H.

H. A. Azab, S. A. El-Korashy, Z. M. Anwar, B. H. Hussein, and G. M. Khairy, “Synthesis and fluorescence properties of Eu-anthracene-9-carboxylic acid towards N-acetyl amino acids and nucleotides in different solvents,” Spectrochim. Acta A 75, 21–27 (2010).
[CrossRef]

Imbert, D.

C. Marchal, Y. Filinchuk, X. Y. Chen, D. Imbert, and M. Mazzanti, “Lanthanide-based coordination polymers assembled by a flexible multidentate linker: design, structure, photophysical properties, and dynamic solid-state behavior,” Chemistry 15, 5273–5288 (2009).
[CrossRef]

E. S. Andreiadis, R. Demadrille, D. Imbert, J. Pecaut, and M. Mazzanti, “Remarkable tuning of the coordination and photophysical properties of lanthanide ions in a series of tetrazole-based complexes,” Chem. Eur. J. 15, 9458–9476 (2009).
[CrossRef]

Jia, J.

J. Jia, M. Shao, T. T. Jia, S. R. Zhu, Y. M. Zhao, F. F. Xing, and M. X. Li, “Coordination polymers of biphenyl-2,4,2′,4′-tetracarboxylic acid—synthesis, structures and adsorption properties,” CrystEngComm. 12, 1548–1561 (2010).
[CrossRef]

Jia, T. T.

J. Jia, M. Shao, T. T. Jia, S. R. Zhu, Y. M. Zhao, F. F. Xing, and M. X. Li, “Coordination polymers of biphenyl-2,4,2′,4′-tetracarboxylic acid—synthesis, structures and adsorption properties,” CrystEngComm. 12, 1548–1561 (2010).
[CrossRef]

Julienne, K.

S. G. Gouin, M. Roger, N. Leygue, D. Deniaud, K. Julienne, E. Benoist, C. Picard, J. Kovensky, and C. Galaup, “Lanthanide(III) complexes of pyridine-tetraacetic acid-glycoconjugates: synthesis and luminescence studies of mono and divalent derivatives,” Bioorg. Med. Chem. Lett. 22, 2684–2688 (2012).
[CrossRef]

Junk, P. C.

M. Hilder, M. Lezhnina, M. L. Cole, C. M. Forsyth, P. C. Junk, and U. H. Kynast, “Spectroscopic properties of lanthanoid benzene carboxylates in the solid state: part 2. polar substituted benzoates,” J. Photochem. Photobiol., A 217, 76–86 (2011).
[CrossRef]

Khairy, G. M.

H. A. Azab, S. A. El-Korashy, Z. M. Anwar, B. H. Hussein, and G. M. Khairy, “Synthesis and fluorescence properties of Eu-anthracene-9-carboxylic acid towards N-acetyl amino acids and nucleotides in different solvents,” Spectrochim. Acta A 75, 21–27 (2010).
[CrossRef]

Koner, R.

R. Koner and I. Goldberg, “The first coordination polymer of lanthanum(III) with a naphthalene -1,4,5,8-tetracarboxylic 1,8-anhydride derivative,” Acta Crystallogr. Sect. C 64, m264–m266 (2008).
[CrossRef]

Kovensky, J.

S. G. Gouin, M. Roger, N. Leygue, D. Deniaud, K. Julienne, E. Benoist, C. Picard, J. Kovensky, and C. Galaup, “Lanthanide(III) complexes of pyridine-tetraacetic acid-glycoconjugates: synthesis and luminescence studies of mono and divalent derivatives,” Bioorg. Med. Chem. Lett. 22, 2684–2688 (2012).
[CrossRef]

Kynast, U. H.

M. Hilder, M. Lezhnina, M. L. Cole, C. M. Forsyth, P. C. Junk, and U. H. Kynast, “Spectroscopic properties of lanthanoid benzene carboxylates in the solid state: part 2. polar substituted benzoates,” J. Photochem. Photobiol., A 217, 76–86 (2011).
[CrossRef]

Lei, Q. J.

B. J. Gao, W. Zhang, Z. G. Zhang, and Q. J. Lei, “Preparation of polymer–rare earth complex using salicylic acid-containing polystyrene and its fluorescence emission property,” J. Lumin. 132, 2005–2011 (2012).
[CrossRef]

Leygue, N.

S. G. Gouin, M. Roger, N. Leygue, D. Deniaud, K. Julienne, E. Benoist, C. Picard, J. Kovensky, and C. Galaup, “Lanthanide(III) complexes of pyridine-tetraacetic acid-glycoconjugates: synthesis and luminescence studies of mono and divalent derivatives,” Bioorg. Med. Chem. Lett. 22, 2684–2688 (2012).
[CrossRef]

Lezhnina, M.

M. Hilder, M. Lezhnina, M. L. Cole, C. M. Forsyth, P. C. Junk, and U. H. Kynast, “Spectroscopic properties of lanthanoid benzene carboxylates in the solid state: part 2. polar substituted benzoates,” J. Photochem. Photobiol., A 217, 76–86 (2011).
[CrossRef]

Li, B.

L. M. Zhang, B. Li, S. M. Yue, M. T. Li, Z. R. Hong, and W. L. Li, “A terbium (III) complex with triphenylamine-functionalized ligand for organic electroluminescent device,” J. Lumin. 128, 620–624 (2008).
[CrossRef]

Li, K.

T. Wu, J. Gao, J. Wang, S. Wang, Y. Bai, Y. Li, K. Li, and X. Zhang, “Synthesis, structural determination and spectroscopic analysis of a novel 2D terbium coordination network with ethyleneglycol-bis-(2-aminoethylether)-N,N,N′,N′-tetraacetic acid,” Spectrochim. Acta A 86, 1–7 (2012).
[CrossRef]

Li, L. C.

X. L. Wang, L. C. Li, and D. Z. Liao, “Slow magnetic relaxation in lanthanide complexes with chelating nitronyl nitroxide radical,” Inorg. Chem. 49, 4735–4737 (2010).
[CrossRef]

Li, M. T.

L. M. Zhang, B. Li, S. M. Yue, M. T. Li, Z. R. Hong, and W. L. Li, “A terbium (III) complex with triphenylamine-functionalized ligand for organic electroluminescent device,” J. Lumin. 128, 620–624 (2008).
[CrossRef]

Li, M. X.

J. Jia, M. Shao, T. T. Jia, S. R. Zhu, Y. M. Zhao, F. F. Xing, and M. X. Li, “Coordination polymers of biphenyl-2,4,2′,4′-tetracarboxylic acid—synthesis, structures and adsorption properties,” CrystEngComm. 12, 1548–1561 (2010).
[CrossRef]

Li, W. L.

L. M. Zhang, B. Li, S. M. Yue, M. T. Li, Z. R. Hong, and W. L. Li, “A terbium (III) complex with triphenylamine-functionalized ligand for organic electroluminescent device,” J. Lumin. 128, 620–624 (2008).
[CrossRef]

Li, Y.

T. Wu, J. Gao, J. Wang, S. Wang, Y. Bai, Y. Li, K. Li, and X. Zhang, “Synthesis, structural determination and spectroscopic analysis of a novel 2D terbium coordination network with ethyleneglycol-bis-(2-aminoethylether)-N,N,N′,N′-tetraacetic acid,” Spectrochim. Acta A 86, 1–7 (2012).
[CrossRef]

Liao, D. Z.

X. L. Wang, L. C. Li, and D. Z. Liao, “Slow magnetic relaxation in lanthanide complexes with chelating nitronyl nitroxide radical,” Inorg. Chem. 49, 4735–4737 (2010).
[CrossRef]

Luo, Y. H.

X. Zhao, X. Y. Yu, T. L. Chen, Y. H. Luo, J. J. Yang, and H. Zhang, “A series of lanthanide compounds based on mixed aromatic carboxylate ligands: syntheses, crystal structures and luminescent properties,” Inorg. Chem. Commun. 20, 247–251 (2012).
[CrossRef]

Ma, L.

L. Ma, Y. C. Qiu, G. Peng, J. B. Cai, H. Deng, and M. Zeller, “Self-assembly of d–f coordination frameworks based on 1H-benzimidazole-5-carboxylic acid: synthesis, structure and luminescence,” CrystEngComm. 13, 3852–3861 (2011).
[CrossRef]

Mahata, P.

P. Mahata, K. V. Ramya, and S. Natarajan, “Synthesis, structure and optical properties of rare-earth benzene carboxylates,” Dalton Trans. 36, 4017–4026 (2007).
[CrossRef]

Mal, S.

M. Pietraszkiewicz, S. Mal, and O. Pietraszkiewicz, “Novel, highly photoluminescent Eu(III) and Tb(III) tetrazolate-2-pyridine-1-oxide complexes,” Opt. Mater. 34, 1507–1512 (2012).
[CrossRef]

Marchal, C.

C. Marchal, Y. Filinchuk, X. Y. Chen, D. Imbert, and M. Mazzanti, “Lanthanide-based coordination polymers assembled by a flexible multidentate linker: design, structure, photophysical properties, and dynamic solid-state behavior,” Chemistry 15, 5273–5288 (2009).
[CrossRef]

Mazzanti, M.

C. Marchal, Y. Filinchuk, X. Y. Chen, D. Imbert, and M. Mazzanti, “Lanthanide-based coordination polymers assembled by a flexible multidentate linker: design, structure, photophysical properties, and dynamic solid-state behavior,” Chemistry 15, 5273–5288 (2009).
[CrossRef]

E. S. Andreiadis, R. Demadrille, D. Imbert, J. Pecaut, and M. Mazzanti, “Remarkable tuning of the coordination and photophysical properties of lanthanide ions in a series of tetrazole-based complexes,” Chem. Eur. J. 15, 9458–9476 (2009).
[CrossRef]

Natarajan, S.

P. Mahata, K. V. Ramya, and S. Natarajan, “Synthesis, structure and optical properties of rare-earth benzene carboxylates,” Dalton Trans. 36, 4017–4026 (2007).
[CrossRef]

Pecaut, J.

E. S. Andreiadis, R. Demadrille, D. Imbert, J. Pecaut, and M. Mazzanti, “Remarkable tuning of the coordination and photophysical properties of lanthanide ions in a series of tetrazole-based complexes,” Chem. Eur. J. 15, 9458–9476 (2009).
[CrossRef]

Peng, G.

L. Ma, Y. C. Qiu, G. Peng, J. B. Cai, H. Deng, and M. Zeller, “Self-assembly of d–f coordination frameworks based on 1H-benzimidazole-5-carboxylic acid: synthesis, structure and luminescence,” CrystEngComm. 13, 3852–3861 (2011).
[CrossRef]

Picard, C.

S. G. Gouin, M. Roger, N. Leygue, D. Deniaud, K. Julienne, E. Benoist, C. Picard, J. Kovensky, and C. Galaup, “Lanthanide(III) complexes of pyridine-tetraacetic acid-glycoconjugates: synthesis and luminescence studies of mono and divalent derivatives,” Bioorg. Med. Chem. Lett. 22, 2684–2688 (2012).
[CrossRef]

Pietraszkiewicz, M.

M. Pietraszkiewicz, S. Mal, and O. Pietraszkiewicz, “Novel, highly photoluminescent Eu(III) and Tb(III) tetrazolate-2-pyridine-1-oxide complexes,” Opt. Mater. 34, 1507–1512 (2012).
[CrossRef]

Pietraszkiewicz, O.

M. Pietraszkiewicz, S. Mal, and O. Pietraszkiewicz, “Novel, highly photoluminescent Eu(III) and Tb(III) tetrazolate-2-pyridine-1-oxide complexes,” Opt. Mater. 34, 1507–1512 (2012).
[CrossRef]

Qiu, Y. C.

L. Ma, Y. C. Qiu, G. Peng, J. B. Cai, H. Deng, and M. Zeller, “Self-assembly of d–f coordination frameworks based on 1H-benzimidazole-5-carboxylic acid: synthesis, structure and luminescence,” CrystEngComm. 13, 3852–3861 (2011).
[CrossRef]

Ramya, K. V.

P. Mahata, K. V. Ramya, and S. Natarajan, “Synthesis, structure and optical properties of rare-earth benzene carboxylates,” Dalton Trans. 36, 4017–4026 (2007).
[CrossRef]

Roger, M.

S. G. Gouin, M. Roger, N. Leygue, D. Deniaud, K. Julienne, E. Benoist, C. Picard, J. Kovensky, and C. Galaup, “Lanthanide(III) complexes of pyridine-tetraacetic acid-glycoconjugates: synthesis and luminescence studies of mono and divalent derivatives,” Bioorg. Med. Chem. Lett. 22, 2684–2688 (2012).
[CrossRef]

Saheli, S.

M. Tabatabaee, M. A. Sharif, F. Vakili, and S. Saheli, “Hydrothermal synthesis and structural studies of a new coordination polymer of lanthanum(III) with benzene-1,2,4,5-tetracarboxylic acid and 4,4′-bipyridine,” J. Rare Earths 27, 356–361 (2009).
[CrossRef]

Shao, M.

J. Jia, M. Shao, T. T. Jia, S. R. Zhu, Y. M. Zhao, F. F. Xing, and M. X. Li, “Coordination polymers of biphenyl-2,4,2′,4′-tetracarboxylic acid—synthesis, structures and adsorption properties,” CrystEngComm. 12, 1548–1561 (2010).
[CrossRef]

Sharif, M. A.

M. Tabatabaee, M. A. Sharif, F. Vakili, and S. Saheli, “Hydrothermal synthesis and structural studies of a new coordination polymer of lanthanum(III) with benzene-1,2,4,5-tetracarboxylic acid and 4,4′-bipyridine,” J. Rare Earths 27, 356–361 (2009).
[CrossRef]

Shen, X. Q.

Y. X. Zhou, X. Q. Shen, C. X. Du, B. L. Wu, and H. Y. Zhang, “1d, 2d and 3d coordination polymers of aromatic carboxylate TbIII: structure, thermolysis kinetics and fluorescence,” Eur. J. Inorg. Chem. 2008, 4280–4289 (2008).
[CrossRef]

Sheng, C.

B. Yan, C. Sheng, and L. Guo, “Lanthanide (Eu3+, Tb3+, Gd3+) hybrid system with functionalized diethylenetriamine pentaacetic acid: coordination bonding assembly, luminescence and MRI contrast agent property,” Inorg. Chem. Commun. 18, 43–46 (2012).
[CrossRef]

Shi, J. X.

H. G. Yan, H. H. Wang, P. He, J. X. Shi, and M. L. Gong, “An efficient bonding-type Eu- containing copolymer as red phosphor applied in LED,” Inorg. Chem. Commun. 14, 1065–1068 (2011).
[CrossRef]

Song, Y.

B. Yan, W. Wang, and Y. Song, “Photophysical properties of praseodymium complexes with aromatic carboxylic acids: double light conversion both in ultraviolet and visible region,” Spectrochim. Acta A 66, 1115–1121 (2007).
[CrossRef]

Tabatabaee, M.

M. Tabatabaee, M. A. Sharif, F. Vakili, and S. Saheli, “Hydrothermal synthesis and structural studies of a new coordination polymer of lanthanum(III) with benzene-1,2,4,5-tetracarboxylic acid and 4,4′-bipyridine,” J. Rare Earths 27, 356–361 (2009).
[CrossRef]

Vakili, F.

M. Tabatabaee, M. A. Sharif, F. Vakili, and S. Saheli, “Hydrothermal synthesis and structural studies of a new coordination polymer of lanthanum(III) with benzene-1,2,4,5-tetracarboxylic acid and 4,4′-bipyridine,” J. Rare Earths 27, 356–361 (2009).
[CrossRef]

Wang, H. H.

H. G. Yan, H. H. Wang, P. He, J. X. Shi, and M. L. Gong, “An efficient bonding-type Eu- containing copolymer as red phosphor applied in LED,” Inorg. Chem. Commun. 14, 1065–1068 (2011).
[CrossRef]

Wang, J.

T. Wu, J. Gao, J. Wang, S. Wang, Y. Bai, Y. Li, K. Li, and X. Zhang, “Synthesis, structural determination and spectroscopic analysis of a novel 2D terbium coordination network with ethyleneglycol-bis-(2-aminoethylether)-N,N,N′,N′-tetraacetic acid,” Spectrochim. Acta A 86, 1–7 (2012).
[CrossRef]

Wang, S.

T. Wu, J. Gao, J. Wang, S. Wang, Y. Bai, Y. Li, K. Li, and X. Zhang, “Synthesis, structural determination and spectroscopic analysis of a novel 2D terbium coordination network with ethyleneglycol-bis-(2-aminoethylether)-N,N,N′,N′-tetraacetic acid,” Spectrochim. Acta A 86, 1–7 (2012).
[CrossRef]

Wang, W.

B. Yan, W. Wang, and Y. Song, “Photophysical properties of praseodymium complexes with aromatic carboxylic acids: double light conversion both in ultraviolet and visible region,” Spectrochim. Acta A 66, 1115–1121 (2007).
[CrossRef]

Wang, X. L.

X. L. Wang, L. C. Li, and D. Z. Liao, “Slow magnetic relaxation in lanthanide complexes with chelating nitronyl nitroxide radical,” Inorg. Chem. 49, 4735–4737 (2010).
[CrossRef]

Weissman, S. I.

S. I. Weissman, “Intramolecular energy transfer the fluorescence of complexes of europium,” J. Chem. Phys. 10, 214–217 (1942).
[CrossRef]

Wu, B. L.

Y. X. Zhou, X. Q. Shen, C. X. Du, B. L. Wu, and H. Y. Zhang, “1d, 2d and 3d coordination polymers of aromatic carboxylate TbIII: structure, thermolysis kinetics and fluorescence,” Eur. J. Inorg. Chem. 2008, 4280–4289 (2008).
[CrossRef]

Wu, T.

T. Wu, J. Gao, J. Wang, S. Wang, Y. Bai, Y. Li, K. Li, and X. Zhang, “Synthesis, structural determination and spectroscopic analysis of a novel 2D terbium coordination network with ethyleneglycol-bis-(2-aminoethylether)-N,N,N′,N′-tetraacetic acid,” Spectrochim. Acta A 86, 1–7 (2012).
[CrossRef]

Xing, F. F.

J. Jia, M. Shao, T. T. Jia, S. R. Zhu, Y. M. Zhao, F. F. Xing, and M. X. Li, “Coordination polymers of biphenyl-2,4,2′,4′-tetracarboxylic acid—synthesis, structures and adsorption properties,” CrystEngComm. 12, 1548–1561 (2010).
[CrossRef]

Xu, M.

M. Xu, Y. C. Zhang, Z. H. Xu, and Z. Z. Zeng, “Crystal structure, biological studies of water-soluble rare earth metal complexes with an ofloxacin derivative,” Inorg. Chem. Commun. 384, 324–332 (2012).
[CrossRef]

Xu, Z. H.

M. Xu, Y. C. Zhang, Z. H. Xu, and Z. Z. Zeng, “Crystal structure, biological studies of water-soluble rare earth metal complexes with an ofloxacin derivative,” Inorg. Chem. Commun. 384, 324–332 (2012).
[CrossRef]

Yan, B.

B. Yan, C. Sheng, and L. Guo, “Lanthanide (Eu3+, Tb3+, Gd3+) hybrid system with functionalized diethylenetriamine pentaacetic acid: coordination bonding assembly, luminescence and MRI contrast agent property,” Inorg. Chem. Commun. 18, 43–46 (2012).
[CrossRef]

B. Yan, W. Wang, and Y. Song, “Photophysical properties of praseodymium complexes with aromatic carboxylic acids: double light conversion both in ultraviolet and visible region,” Spectrochim. Acta A 66, 1115–1121 (2007).
[CrossRef]

Yan, H. G.

H. G. Yan, H. H. Wang, P. He, J. X. Shi, and M. L. Gong, “An efficient bonding-type Eu- containing copolymer as red phosphor applied in LED,” Inorg. Chem. Commun. 14, 1065–1068 (2011).
[CrossRef]

Yang, J. J.

X. Zhao, X. Y. Yu, T. L. Chen, Y. H. Luo, J. J. Yang, and H. Zhang, “A series of lanthanide compounds based on mixed aromatic carboxylate ligands: syntheses, crystal structures and luminescent properties,” Inorg. Chem. Commun. 20, 247–251 (2012).
[CrossRef]

Yu, X. Y.

X. Zhao, X. Y. Yu, T. L. Chen, Y. H. Luo, J. J. Yang, and H. Zhang, “A series of lanthanide compounds based on mixed aromatic carboxylate ligands: syntheses, crystal structures and luminescent properties,” Inorg. Chem. Commun. 20, 247–251 (2012).
[CrossRef]

Yue, S. M.

L. M. Zhang, B. Li, S. M. Yue, M. T. Li, Z. R. Hong, and W. L. Li, “A terbium (III) complex with triphenylamine-functionalized ligand for organic electroluminescent device,” J. Lumin. 128, 620–624 (2008).
[CrossRef]

Zeller, M.

L. Ma, Y. C. Qiu, G. Peng, J. B. Cai, H. Deng, and M. Zeller, “Self-assembly of d–f coordination frameworks based on 1H-benzimidazole-5-carboxylic acid: synthesis, structure and luminescence,” CrystEngComm. 13, 3852–3861 (2011).
[CrossRef]

Zeng, Z. Z.

M. Xu, Y. C. Zhang, Z. H. Xu, and Z. Z. Zeng, “Crystal structure, biological studies of water-soluble rare earth metal complexes with an ofloxacin derivative,” Inorg. Chem. Commun. 384, 324–332 (2012).
[CrossRef]

Zhang, H.

X. Zhao, X. Y. Yu, T. L. Chen, Y. H. Luo, J. J. Yang, and H. Zhang, “A series of lanthanide compounds based on mixed aromatic carboxylate ligands: syntheses, crystal structures and luminescent properties,” Inorg. Chem. Commun. 20, 247–251 (2012).
[CrossRef]

Zhang, H. Y.

Y. X. Zhou, X. Q. Shen, C. X. Du, B. L. Wu, and H. Y. Zhang, “1d, 2d and 3d coordination polymers of aromatic carboxylate TbIII: structure, thermolysis kinetics and fluorescence,” Eur. J. Inorg. Chem. 2008, 4280–4289 (2008).
[CrossRef]

Zhang, L. M.

L. M. Zhang, B. Li, S. M. Yue, M. T. Li, Z. R. Hong, and W. L. Li, “A terbium (III) complex with triphenylamine-functionalized ligand for organic electroluminescent device,” J. Lumin. 128, 620–624 (2008).
[CrossRef]

Zhang, W.

B. J. Gao, W. Zhang, Z. G. Zhang, and Q. J. Lei, “Preparation of polymer–rare earth complex using salicylic acid-containing polystyrene and its fluorescence emission property,” J. Lumin. 132, 2005–2011 (2012).
[CrossRef]

Zhang, X.

T. Wu, J. Gao, J. Wang, S. Wang, Y. Bai, Y. Li, K. Li, and X. Zhang, “Synthesis, structural determination and spectroscopic analysis of a novel 2D terbium coordination network with ethyleneglycol-bis-(2-aminoethylether)-N,N,N′,N′-tetraacetic acid,” Spectrochim. Acta A 86, 1–7 (2012).
[CrossRef]

Zhang, Y. C.

M. Xu, Y. C. Zhang, Z. H. Xu, and Z. Z. Zeng, “Crystal structure, biological studies of water-soluble rare earth metal complexes with an ofloxacin derivative,” Inorg. Chem. Commun. 384, 324–332 (2012).
[CrossRef]

Zhang, Z. G.

B. J. Gao, W. Zhang, Z. G. Zhang, and Q. J. Lei, “Preparation of polymer–rare earth complex using salicylic acid-containing polystyrene and its fluorescence emission property,” J. Lumin. 132, 2005–2011 (2012).
[CrossRef]

Zhao, X.

X. Zhao, X. Y. Yu, T. L. Chen, Y. H. Luo, J. J. Yang, and H. Zhang, “A series of lanthanide compounds based on mixed aromatic carboxylate ligands: syntheses, crystal structures and luminescent properties,” Inorg. Chem. Commun. 20, 247–251 (2012).
[CrossRef]

Zhao, Y. M.

J. Jia, M. Shao, T. T. Jia, S. R. Zhu, Y. M. Zhao, F. F. Xing, and M. X. Li, “Coordination polymers of biphenyl-2,4,2′,4′-tetracarboxylic acid—synthesis, structures and adsorption properties,” CrystEngComm. 12, 1548–1561 (2010).
[CrossRef]

Zhou, Y. X.

Y. X. Zhou, X. Q. Shen, C. X. Du, B. L. Wu, and H. Y. Zhang, “1d, 2d and 3d coordination polymers of aromatic carboxylate TbIII: structure, thermolysis kinetics and fluorescence,” Eur. J. Inorg. Chem. 2008, 4280–4289 (2008).
[CrossRef]

Zhu, S. R.

J. Jia, M. Shao, T. T. Jia, S. R. Zhu, Y. M. Zhao, F. F. Xing, and M. X. Li, “Coordination polymers of biphenyl-2,4,2′,4′-tetracarboxylic acid—synthesis, structures and adsorption properties,” CrystEngComm. 12, 1548–1561 (2010).
[CrossRef]

Acta Crystallogr. Sect. C (1)

R. Koner and I. Goldberg, “The first coordination polymer of lanthanum(III) with a naphthalene -1,4,5,8-tetracarboxylic 1,8-anhydride derivative,” Acta Crystallogr. Sect. C 64, m264–m266 (2008).
[CrossRef]

Bioorg. Med. Chem. Lett. (1)

S. G. Gouin, M. Roger, N. Leygue, D. Deniaud, K. Julienne, E. Benoist, C. Picard, J. Kovensky, and C. Galaup, “Lanthanide(III) complexes of pyridine-tetraacetic acid-glycoconjugates: synthesis and luminescence studies of mono and divalent derivatives,” Bioorg. Med. Chem. Lett. 22, 2684–2688 (2012).
[CrossRef]

Chem. Eur. J. (1)

E. S. Andreiadis, R. Demadrille, D. Imbert, J. Pecaut, and M. Mazzanti, “Remarkable tuning of the coordination and photophysical properties of lanthanide ions in a series of tetrazole-based complexes,” Chem. Eur. J. 15, 9458–9476 (2009).
[CrossRef]

Chemistry (1)

C. Marchal, Y. Filinchuk, X. Y. Chen, D. Imbert, and M. Mazzanti, “Lanthanide-based coordination polymers assembled by a flexible multidentate linker: design, structure, photophysical properties, and dynamic solid-state behavior,” Chemistry 15, 5273–5288 (2009).
[CrossRef]

CrystEngComm. (2)

J. Jia, M. Shao, T. T. Jia, S. R. Zhu, Y. M. Zhao, F. F. Xing, and M. X. Li, “Coordination polymers of biphenyl-2,4,2′,4′-tetracarboxylic acid—synthesis, structures and adsorption properties,” CrystEngComm. 12, 1548–1561 (2010).
[CrossRef]

L. Ma, Y. C. Qiu, G. Peng, J. B. Cai, H. Deng, and M. Zeller, “Self-assembly of d–f coordination frameworks based on 1H-benzimidazole-5-carboxylic acid: synthesis, structure and luminescence,” CrystEngComm. 13, 3852–3861 (2011).
[CrossRef]

Dalton Trans. (1)

P. Mahata, K. V. Ramya, and S. Natarajan, “Synthesis, structure and optical properties of rare-earth benzene carboxylates,” Dalton Trans. 36, 4017–4026 (2007).
[CrossRef]

Eur. J. Inorg. Chem. (1)

Y. X. Zhou, X. Q. Shen, C. X. Du, B. L. Wu, and H. Y. Zhang, “1d, 2d and 3d coordination polymers of aromatic carboxylate TbIII: structure, thermolysis kinetics and fluorescence,” Eur. J. Inorg. Chem. 2008, 4280–4289 (2008).
[CrossRef]

Inorg. Chem. (1)

X. L. Wang, L. C. Li, and D. Z. Liao, “Slow magnetic relaxation in lanthanide complexes with chelating nitronyl nitroxide radical,” Inorg. Chem. 49, 4735–4737 (2010).
[CrossRef]

Inorg. Chem. Commun. (4)

B. Yan, C. Sheng, and L. Guo, “Lanthanide (Eu3+, Tb3+, Gd3+) hybrid system with functionalized diethylenetriamine pentaacetic acid: coordination bonding assembly, luminescence and MRI contrast agent property,” Inorg. Chem. Commun. 18, 43–46 (2012).
[CrossRef]

M. Xu, Y. C. Zhang, Z. H. Xu, and Z. Z. Zeng, “Crystal structure, biological studies of water-soluble rare earth metal complexes with an ofloxacin derivative,” Inorg. Chem. Commun. 384, 324–332 (2012).
[CrossRef]

H. G. Yan, H. H. Wang, P. He, J. X. Shi, and M. L. Gong, “An efficient bonding-type Eu- containing copolymer as red phosphor applied in LED,” Inorg. Chem. Commun. 14, 1065–1068 (2011).
[CrossRef]

X. Zhao, X. Y. Yu, T. L. Chen, Y. H. Luo, J. J. Yang, and H. Zhang, “A series of lanthanide compounds based on mixed aromatic carboxylate ligands: syntheses, crystal structures and luminescent properties,” Inorg. Chem. Commun. 20, 247–251 (2012).
[CrossRef]

J. Chem. Phys. (1)

S. I. Weissman, “Intramolecular energy transfer the fluorescence of complexes of europium,” J. Chem. Phys. 10, 214–217 (1942).
[CrossRef]

J. Lumin. (2)

L. M. Zhang, B. Li, S. M. Yue, M. T. Li, Z. R. Hong, and W. L. Li, “A terbium (III) complex with triphenylamine-functionalized ligand for organic electroluminescent device,” J. Lumin. 128, 620–624 (2008).
[CrossRef]

B. J. Gao, W. Zhang, Z. G. Zhang, and Q. J. Lei, “Preparation of polymer–rare earth complex using salicylic acid-containing polystyrene and its fluorescence emission property,” J. Lumin. 132, 2005–2011 (2012).
[CrossRef]

J. Photochem. Photobiol., A (1)

M. Hilder, M. Lezhnina, M. L. Cole, C. M. Forsyth, P. C. Junk, and U. H. Kynast, “Spectroscopic properties of lanthanoid benzene carboxylates in the solid state: part 2. polar substituted benzoates,” J. Photochem. Photobiol., A 217, 76–86 (2011).
[CrossRef]

J. Rare Earths (1)

M. Tabatabaee, M. A. Sharif, F. Vakili, and S. Saheli, “Hydrothermal synthesis and structural studies of a new coordination polymer of lanthanum(III) with benzene-1,2,4,5-tetracarboxylic acid and 4,4′-bipyridine,” J. Rare Earths 27, 356–361 (2009).
[CrossRef]

Opt. Mater. (1)

M. Pietraszkiewicz, S. Mal, and O. Pietraszkiewicz, “Novel, highly photoluminescent Eu(III) and Tb(III) tetrazolate-2-pyridine-1-oxide complexes,” Opt. Mater. 34, 1507–1512 (2012).
[CrossRef]

Spectrochim. Acta A (3)

T. Wu, J. Gao, J. Wang, S. Wang, Y. Bai, Y. Li, K. Li, and X. Zhang, “Synthesis, structural determination and spectroscopic analysis of a novel 2D terbium coordination network with ethyleneglycol-bis-(2-aminoethylether)-N,N,N′,N′-tetraacetic acid,” Spectrochim. Acta A 86, 1–7 (2012).
[CrossRef]

B. Yan, W. Wang, and Y. Song, “Photophysical properties of praseodymium complexes with aromatic carboxylic acids: double light conversion both in ultraviolet and visible region,” Spectrochim. Acta A 66, 1115–1121 (2007).
[CrossRef]

H. A. Azab, S. A. El-Korashy, Z. M. Anwar, B. H. Hussein, and G. M. Khairy, “Synthesis and fluorescence properties of Eu-anthracene-9-carboxylic acid towards N-acetyl amino acids and nucleotides in different solvents,” Spectrochim. Acta A 75, 21–27 (2010).
[CrossRef]

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Figures (7)

Fig. 1.
Fig. 1.

IR absorption spectra of BPDA (a), TbL2 (b), TbL (c), and Tb2L (d).

Fig. 2.
Fig. 2.

TG curves of complexes TbL2 (a), TbL (b), and Tb2L (c).

Fig. 3.
Fig. 3.

UV absorption spectra of complexes TbL2, TbL, and Tb2L.

Fig. 4.
Fig. 4.

Fluorescence excitation spectra of complexes TbL2, TbL, and Tb2L.

Fig. 5.
Fig. 5.

Fluorescence emission spectra of complexes TbL2, TbL and Tb2L.

Fig. 6.
Fig. 6.

CIE 1931 chromaticity coordinates of complexes TbL2 (a), TbL (b), and Tb2L (c).

Fig. 7.
Fig. 7.

Fluorescence decay curves of the transitions D45-F57 (544 nm) and D45-F37 (613 nm) for complexes a, TbL2; b, TbL; and c, Tb2L.

Tables (1)

Tables Icon

Table 1. Luminescence Lifetimes and Decay Parameters of Complexesa

Metrics